Degradation of trichloroethylene (TCE) by nanoscale zero-valent iron (nZVI) immobilized in alginate bead

Journal of Hazardous Materials

Volumn 176, Issue 1-3, 2010, Pages 1038-1043

  Kim, Hojeong ^a   Hong, Hye Jin ^b   Jung, Juri ^b   Kim, Seong Hye ^b   Yang, Ji Won ^b  

^a Korea Environment Institute (KEI)   (South Korea)

^b Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

Author keywords

Immobilization; Iron nanoparticle; Reductive dechlorination; Trichloroethylene; Zero valent iron

Indexed keywords

ALGINATE BEADS; AQUEOUS SOLUTIONS; BARIUM IONS; CHLORINATED SOLVENT; CORE SHELL STRUCTURE; ENVIRONMENTAL APPLICATIONS; FATE AND TRANSPORT; FIELD APPLICATION; GROUND WATER REMEDIATION; IRON NANOPARTICLE; IRON NANOPARTICLES; NANOSCALE ZERO-VALENT IRON; ORDER OF MAGNITUDE; PSEUDO-FIRST ORDER KINETICS; PSEUDO-FIRST-ORDER REACTION; REDUCTIVE DECHLORINATION; TEM (TRANSMISSION ELECTRON MICROSCOPY); ZERO-VALENT IRON;

ALGINATE; ANESTHETICS; BARIUM; DECHLORINATION; DOPING (ADDITIVES); GROUNDWATER; HYDROGEOLOGY; NANOPARTICLES; NANOSTRUCTURED MATERIALS; PALLADIUM; RATE CONSTANTS; SINGLE CRYSTALS; SOLUTIONS; SURFACE ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; TRICHLOROETHYLENE;

METAL RECOVERY;

ALGINIC ACID; BARIUM ION; FERRIC ION; IRON; PALLADIUM; TRICHLOROETHYLENE;

ALGINATE; BIODEGRADATION; DECHLORINATION; IMMOBILIZATION; IRON; MICROSTRUCTURE; OXIDATION; PARTICLE SIZE; REACTION KINETICS; SOLVENT; TRANSMISSION ELECTRON MICROSCOPY; TRICHLOROETHYLENE;

AQUEOUS SOLUTION; ARTICLE; CROSS LINKING; DEGRADATION KINETICS; IMMOBILIZATION; OXIDATION KINETICS; SURFACE PROPERTY; TRANSMISSION ELECTRON MICROSCOPY; WASTE COMPONENT REMOVAL;

ENVIRONMENTAL REMEDIATION; IRON; KINETICS; MICROSPHERES; NANOPARTICLES; PALLADIUM; TRICHLOROETHYLENE; WATER POLLUTANTS, CHEMICAL; WATER PURIFICATION;

KOBUS;

EID: 74449087115     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2009.11.145     Document Type: Article

References (31)

1. Tratnyek P.G., and Johnson R.L. Nanotechnologies for environmental cleanup. Nano Today 1 (2006) 44-48
2. Arnold W.A., and Roberts A.L. Pathways and kinetics of chlorinated ethylene and chlorinated acetylene reaction with Fe(0) particles. Environ. Sci. Technol. 34 (2000) 1794-1805
3. Zhang W. Nanoscale iron particles for environmental remediation: an overview. J. Nanopart. Res. 5 (2003) 323-332
4. Meyer D.E., Wood K., Bachas L.G., and Bhattacharyya D. Degradation of chlorinated organics by membrane-immobilized nanosized metals. Environ. Prog. 23 (2004) 232-242
5. Schäfer D., Köber R., and Dahmke A. Competing TCE and cis-DCE degradation kinetics by zero-valent iron: experimental results and numerical simulation. J. Contam. Hydrol. 65 (2003) 183-202
6. Liu Y.Q., Majetich S.A., Tilton R.D., Sholl D.S., and Lowry G.V. TCE dechlorination rates, pathways, and efficiency of nanoscale iron particles with different properties. Environ. Sci. Technol. 39 (2005) 1338-1345
7. Gotpagar J.K., Grulke E.A., and Bhattacharyya D. Reductive dehalogenation of trichloroethylene: kinetic models and experimental verification. J. Hazard. Mater. 62 (1998) 243-264
8. Xu J., and Bhattacharyya D. Fe/Pd nanoparticle immobilization in microfiltration membrane pores: synthesis, characterization, and application in the dechlorination of polychlorinated biphenyls. Ind. Eng. Chem. Res. 46 (2007) 2348-2359
9. Kim Y.H., and Carraway E.R. Reductive dechlorination of TCE by zero valent bimetals. Environ. Technol. 24 (2003) 69-75
10. Ponder S.M., Darab J.G., and Mallouk T.E. Remediation of Cr(VI) and Pb(II) aqueous solutions using supported, nanoscale zero-valent iron. Environ. Sci. Technol. 34 (2000) 2564-2569
11. Joo S.H., Feitz A.J., and Waite T.D. Oxidative degradation of the carbothioate herbicide, molinate, using nanoscale zero-valent iron. Environ. Sci. Technol. 38 (2004) 2242-2247
12. Choe S., Lee S.H., Chang Y.Y., Hwang K.Y., and Khim J. Rapid reductive destruction of hazardous organic compounds by nanoscale Fe-0. Chemosphere 42 (2001) 367-372
13. Kanel S.R., Manning B., Charlet L., and Choi H. Removal of arsenic(III) from groundwater by nanoscale zero-valent iron. Environ. Sci. Technol. 39 (2005) 1291-1298
14. UNEP, GEO Year BOOK 2007, UNEP, 2007.
15. USEPA, Nanotechnology for Site Remediation Fact Sheet, 2009.
16. Wu L.F., and Ritchie S.M.C. Removal of trichloroethylene from water by cellulose acetate supported bimetallic Ni/Fe nanoparticles. Chemosphere 63 (2006) 285-292
17. D. Bhattacharyya, X. Jian, D. Meyer, Y. Tee, L. Bachas, Membrane-immobilized metal nanoparticles for environmental applications ICOM2005, Seoul, Korea, 2005.
18. Ponder S.M., Darab J.G., Bucher J., Caulder D., Craig I., Davis L., Edelstein N., Lukens W., Nitsche H., Rao L.F., Shuh D.K., and Mallouk T.E. Surface chemistry and electrochemistry of supported zerovalent iron nanoparticles in the remediation of aqueous metal contaminants. Chem. Mater. 13 (2001) 479-486
19. Zhang P.F., Tao X., Li Z.H., and Bowman R.S. Enhanced perchloroethylene reduction in column systems using surfactant-modified zeolite/zero-valent iron pellets. Environ. Sci. Technol. 36 (2002) 3597-3603
20. Mackenzie K., Hildebrand H., and Kopinke F.D. Nano-Catalysts and Colloidal Suspensions of Carbon-Iron for Environmental Application (NSTI-Nanotech 2007), vol. 2 (2007) 639-642
21. Hoch L.B., Mack E.J., Hydutsky B.W., Hershman J.M., Skluzacek J.M., and Mallouk T.E. Carbothermal synthesis of carbon-supported nanoscale zero-valent iron particles for the remediation of hexavalent chromium. Environ. Sci. Technol. 42 (2008) 2600-2605
22. Huang Q., Shi X., Pinto R.A., Petersen E.J., and Weber W.J. Tunable synthesis and immobilization of zero-valent iron nanoparticles for environmental applications. Environ. Sci. Technol. 42 (2008) 8884-8889
23. Anisha G.S., and Prema P. Cell immobilization technique for the enhanced production of [alpha]-galactosidase by Streptomyces griseoloalbus. Bioresour. Technol. 99 (2008) 3325-3330
24. Bezbaruah A.N., Krajangpan S., Chisholm B.J., Khan E., and Elorza Bermudez J.J. Entrapment of iron nanoparticles in calcium alginate beads for groundwater remediation applications. J. Hazard. Mater. 166 (2009) 1339-1343
25. Zhu B.W., and Lim T.T. Catalytic reduction of chlorobenzenes with Pd/Fe nanoparticles: reactive sites, catalyst stability, particle aging, and regeneration,. Environ. Sci. Technol. 41 (2007) 7523-7529
26. Kanel S.R., Nepal D., Manning B., and Choi H. Transport of surface-modified iron nanoparticle in porous media and application to arsenic (III) remediation. J. Nanopart. Res. 9 (2007) 725-735
27. Xu J., and Bhattacharyya D. Membrane-based bimetallic nanoparticles for environmental remediation: synthesis and reactive properties. Environ. Prog. 24 (2005) 358-366
28. Schrick B., Blough J.L., Jones A.D., and Mallouk T.E. Hydrodechlorination of trichloroethylene to hydrocarbons using bimetallic nickel-iron nanoparticles. Chem. Mater. 14 (2002) 5140-5147
29. Tee Y.H., Grulke E., and Bhattacharyya D. Role of Ni/Fe nanoparticle composition on the degradation of trichloroethylene from water. Ind. Eng. Chem. Res. 44 (2005) 7062-7070
30. 2 evolution. Environ. Sci. Technol. 41 (2007) 7881-7887
31. Wang C.B., and Zhang W.X. Synthesizing nanoscale iron particles for rapid and complete dechlorination of TCE and PCBs. Environ. Sci. Technol. 31 (1997) 2154-2156