A kinetic model for glycerol chlorination in the presence of acetic acid catalyst

Korean Journal of Chemical Engineering

Volumn 27, Issue 1, 2010, Pages 66-72

  Luo, Zheng Hong ^a   You, Xiao Zi ^a   Li, Hua Rong ^a  

^a XIAMEN UNIVERSITY   (China)

Author keywords

1,3 Dichloro 2 propanol; Chlorination Kinetics; Glycerol; Mechanism Model

Indexed keywords

EID: 74249100397     PISSN: 02561115     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11814-009-0329-x     Document Type: Article

References (16)

1. H. L. Horsley, Encyclopedia of chemical technology, 3th ed., Wiley, Hoboken, NJ, 595 (1965).
2. L. Ma, J. W. Zhu, X. Q. Yuan and Q. Yue, Trans IChemE, Part A, Chem. Eng. Res. Des., 85, 1580 (2007).
3. S. Carrà, E. Santacesarla and M. Morbldlll, Ind. Eng. Chem. Process Des. Dev., 18, 424 (1979).
4. L. L. Wang, Y. M. Liu and W. Xie, J. Catal., 246, 205 (2007).
5. S. H. Lee, D. R. Park, H. Kim, J. Lee, J. C. Jung, S. Y. Woo, W. S. Song, M. S. Kwon and I. K. Song, Catal. Com., 9, 1920 (2008).
6. W. Xie, H. Peng and L. Chen, Appl. Catal. A-Gen., 300, 67 (2006).
7. C. S. Macleod, A. P. Harvey, A. F. Lee and K. Wilson, Chem. Eng. J., 135, 63 (2008).
8. P. Krafft, P. Gilbeau and D. Balthasart, Crude glycerol-based product, process for its purification and its use in the manufacture of dichloropropanol, PCT Patent WO/2007/144335 (2007).
9. P. Gilbeau and P. Krafft, Producing chlorinated organic compounds e. g. dichloropropanol involves using glycerol obtained from renewable raw materials, as a starting product, FR Patent FR2868419 (2005).
10. P. Krafft, P. Gilbeau, B. Gosselin and S. Claessens, Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel, PCT Patent WO2005/054167 A1 (2005).
11. P. Kubicek, P. Sladek and I. Buricova, Method of preparing dichloroproanols from glycerine, PCT Patent WO2005/021476 A1 (2005).
12. D. J. Schreck, W. J. Kruper, R. D. Varjian, M. E. Jones, R. M. Campbell, K. Kearns, B. D. Hook, J. R. Briggs and J. G. Hippler, Conversion of a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, PCT Patent WO2006/020234 A1 (2006).
13. P. Krafft, C. Franck, I. D. Andolenko and R. Veyrac, Process for the manufacture of dichloropropanol by chlorination of glycerol, PCT Patent WO/2007/054505 (2007).
14. Z. H. Luo, X. Z. You and H. R. Li, Ind. Eng. Chem. Res., 48, 446 (2009).
15. R. Tesser, E. Santacesaria, M. Di Serio, G. Di Nuzzi and V. Fiandra, Ind. Eng. Chem. Res., 46, 6456 (2007).
16. S. Carrà, E. Santacesarla and M. Morbldlll, Ind. Eng. Chem. Process Des. Dev., 18, 428 (1979).