A simple and efficient route to prepare inorganic hollow microspheres using polymer particles as template in supercritical fluids

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 355, Issue 1-3, 2010, Pages 45-52

  Chen, Zhimin ^a   Li, Shijiang ^b   Xue, Fengfeng ^a   Sun, Guannan ^a   Luo, Chengguo ^b   Chen, Jiafu ^a   Xu, Qun ^a  

^a ZHENGZHOU UNIVERSITY   (China)

^b Do Fluoride Chemicals Co Ltd   (China)

Author keywords

Hollow microspheres; Supercritical fluids; Template

Indexed keywords

CARBON DIOXIDE; EFFLUENT TREATMENT; POLYSTYRENES; SILICA; SINTERING; SUPERCRITICAL FLUID EXTRACTION; SUPERCRITICAL FLUIDS; TITANIUM; TITANIUM DIOXIDE; TRANSMISSION ELECTRON MICROSCOPY; TRANSPORT PROPERTIES;

COMPOSITE PARTICLES; CROSS-LINKED POLYSTYRENE; ELECTRONIC MICROSCOPES; FORMATION MECHANISM; HOLLOW MICROSPHERE; HOLLOW MICROSPHERES; HOLLOW PARTICLE; POLYMER PARTICLES; SEM; SILICA MICROSPHERES; SOL-GEL PROCEDURE; SUPERCRITICAL CARBON DIOXIDES; TEM; TETRAETHYL ORTHOSILICATES;

MICROSPHERES;

CARBON DIOXIDE; MICROSPHERE; POLYSTYRENE; SILICON DIOXIDE; TETRAETHOXYSILANE; TITANIUM DIOXIDE;

ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; CROSS LINKING; PRIORITY JOURNAL; SUPERCRITICAL FLUID; SYNTHESIS;

EID: 74149088418     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2009.11.030     Document Type: Article

References (33)

1. Caruso F. Nanoengineering of particle surfaces. Adv. Mater. 13 (2001) 11-22
2. Caruso F., Caruso R.A., and Möhwald H. Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science 282 (1998) 1111-1114
3. 2 by templating against crystalline arrays of polystyrene beads. Adv. Mater. 12 (2000) 206-209
4. Cheng X.J., Chen M., Wu L.M., and Gu G. Novel and facile method for the preparation of monodispersed titania hollow spheres. Langmuir 22 (2006) 3858-3863
5. Jiang C.L., Zhang W.Q., Zou G.F., Yu W.C., and Qian Y.T. Synthesis and characterization of ZnSe hollow nanospheres via a hydrothermal route. Nanotechnology 16 (2005) 551-554
6. Yeh Y.Q., Chen B.C., Lin H.P., and Tang C.Y. Synthesis of hollow silica spheres with mesostructured shell using cationic-anionic-neutral block copolymer ternary surfactants. Langmuir 22 (2006) 6-9
7. Chen Y.W., Kang E.T., Neoh K.G., and Reiner A. Preparation of hollow silica nanospheres by surface-initiated atom transfer radical polymerization on polymer latex templates. Adv. Funct. Mater. 15 (2005) 113-117
8. Cui T.Y., Zhang J.H., Wang J.Y., Cui F., Chen W., Xu F.B., Wang Z., Zhang K., and Yang B. CdS-nanoparticle/polymer composite shells grown on silica nanospheres by atom-transfer radical polymerization. Adv. Funct. Mater. 15 (2005) 481-486
9. Liang H.P., Zhang H.M., Hu J.S., Guo Y., Wan L.J., and Bai C.L. Pt hollow nanospheres: facile synthesis and enhanced electrocatalysts. Angew. Chem. Int. 43 (2004) 1540-1543
10. Wang Y.L., Cai L., and Xia Y.N. Monodisperse spherical colloids of Pb and their use as chemical templates to produce hollow particles. Adv. Mater. 17 (2005) 473-477
11. Zhang K., Zhang X.H., Chen H.T., Chen X., Zheng L.L., Zhang J.H., and Yang B. Hollow titania spheres with movable silica spheres inside. Langmuir 20 (2004) 11312-11314
12. Ding S.J., Zhang C.L., Yang M., Qu X.Z., Lu F.Y., and Yang Z.Z. Template synthesis of composite hollow spheres using sulfonated polystyrene hollow spheres. Polymer 47 (2006) 8360-8366
13. Wei Z.X., and Wan M.X. Hollow microspheres of polyaniline synthesized with an aniline emulsion template. Adv. Mater. 14 (2002) 1314-1317
14. Peng Q., Dong Y.J., and Li Y.D. ZnSe semiconductor hollow microspheres. Angew. Chem. Int. Ed. 42 (2003) 3027-3030
15. Yang H.G., and Zeng H.C. Creation of intestine-like interior space for metal-oxide nanostructures with a quasi-reverse emulsion. Angew. Chem. Int. Ed. 43 (2004) 5206-5209
16. Choi W.S., Park J.H., Koo H.Y., Kim J.Y., Cho B.K., and Kim D.Y. Grafting-from polymerization inside a polyelectrolyte hollow-capsule microreactor. Angew. Chem. Int. Ed. 44 (2005) 1096-1101
17. Douglas T., and Young M. Host-guest encapsulation of materials by assembled virus protein cages. Nature 393 (1998) 152-155
18. Douglas T., Strable E., Willits D., Aitouchen A., Libera M., and Young M. Protein engineering of a viral cage for constrained nanomaterials synthesis. Adv. Mater. 14 (2002) 415-418
19. Hotz J., and Meier W. Polymer particles by templating of vesicles. Adv. Mater. 10 (1998) 1387-1390
20. Hubert D.H., Jung M., Frederik P.M., Bomans P.H., Meuldijk J., and German A.L. Vesicle-directed growth of silica. Adv. Mater. 12 (2000) 1286-1290
21. Eckert C.A., Knutson B.L., and Debendetti P.G. Supercritical fluids as solvents for chemical and materials processing. Nature 383 (1996) 313-318
22. DeSimone J.M. Practical approaches to green solvents. Science 297 (2002) 799-803
23. Kazarian S.G., Vincent M.F., Bright F.V., Liotta C.L., and Eckert C.A. Specific intermolecular interaction of carbon dioxide with polymers. J. Am. Chem. Soc. 118 (1996) 1729-1736
24. Yates M.Z., Birnbaum E.R., and McCleskey T.M. Colored polymer microparticles through carbon dioxide-assisted dyeing. Langmuir 16 (2000) 4757-4760
25. Abramowitz H., Shah P.S., Green P.F., and Johnston K.P. Welding colloidal crystals with carbon dioxide. Macromolecules 37 (2004) 7316-7324
26. 2-aerogel inverse opals in supercritical carbon dioxide. Chem. Mater. 17 (2005) 6137-6145
27. 2 using 3D-latex array templates. Chem. Commun. (2005) 2618-2620
28. 2 in modified polystyrene 3D latex arrays. Langmuir 22 (2006) 8966-8974
29. Chen Z.M., Xue F.F., Chen J.F., and Xu Q. Transforming micron-sized cross-link PS microspheres from isotropy to anisotropy with the assistance of supercritical carbon dioxide and sonication. Colloid Surf. A 335 (2009) 16-22
30. 2/water systems. J. Mater. Chem. 16 (2006) 1751-1756
31. 2-in-water interface templating. Chem. Commun. 2 (2005) 210-212
32. 2O interface. J. Supercrit. Fluids. 42 (2007) 142-149
33. Sing K.S.W. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl. Chem. 57 (1985) 603-619