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Abbreviations: LAM = less activated monomer, MA = methyl acrylate, MAM = more activated monomer, NVP = ./V-vinylpyrrolidone, S = styrene, VAc = vinyl acetate, PMA = poly(methyl acrylate), PMMA = poly(methyl methacrylate), PNVP = poly(N-vinylpyrrolidone), PS = polystyrene, PVAc = poly(vinyl acetate), and RAFT = reversible addition-fragmentation chain transfer, PNVC = poly(N-vinyl carbazole).
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Abbreviations: LAM = less activated monomer, MA = methyl acrylate, MAM = more activated monomer, NVP = ./V-vinylpyrrolidone, S = styrene, VAc = vinyl acetate, PMA = poly(methyl acrylate), PMMA = poly(methyl methacrylate), PNVP = poly(N-vinylpyrrolidone), PS = polystyrene, PVAc = poly(vinyl acetate), and RAFT = reversible addition-fragmentation chain transfer, PNVC = poly(N-vinyl carbazole).
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74049147894
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It is extremely important when applying this strategy to prepare PSblock-polyLAM to ensure that the polystyrene macro-RAFT agent is free of residual styrene monomer; otherwise, the high reactivity of styrene will result in formation of a new macro-RAFT agent with a terminal styrene unit and an extended period of slow polymerization.
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It is extremely important when applying this strategy to prepare PSblock-polyLAM to ensure that the polystyrene macro-RAFT agent is free of residual styrene monomer; otherwise, the high reactivity of styrene will result in formation of a new macro-RAFT agent with a terminal styrene unit and an extended period of slow polymerization.
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The polystyrene aromatic ring chromophore has an absorption maximum at 262 nm. The thiocarbonylthio chromophore has an absorption maximum at 290 nm. Polystyrene does not absorb at 290 nm. Polyvinyl acetate is transparent at 262 and 290 nm.
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The polystyrene aromatic ring chromophore has an absorption maximum at 262 nm. The thiocarbonylthio chromophore has an absorption maximum at 290 nm. Polystyrene does not absorb at 290 nm. Polyvinyl acetate) is transparent at 262 and 290 nm.
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s = 0.77, rMA = 0.12.
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s = 0.77, rMA = 0.12.
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