Arsenicin A, A natural polyarsenical: Synthesis and crystal structure

Organometallics

Volumn 29, Issue 1, 2010, Pages 32-33

  Lu, Di ^a   David Rae, A ^a   Salem, Geoff ^a   Weir, Michelle L ^a   Willis, Anthony C ^a   Bruce Wild, S ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

ADAMANTANES; ARSENIC TRIOXIDE; METHYLENE GROUPS; OXYGEN ATOM; STEREOCENTERS; SYNTHESIS AND CRYSTAL STRUCTURE; TYPE STRUCTURES;

ARSENIC; OXYGEN;

CRYSTAL ATOMIC STRUCTURE;

EID: 73649106171     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900998q     Document Type: Article

References (11)

1. Mancini, I.; Guella, G.; Frostin, M.; Hnawia, E.; Laurent, D.; Debitus, C.; Pietra, F. Chem. Eur. J. 2006, 12, 8989.
2. Tahtinen, P.; Saielli, G.; Guella, G.; Mancini, I.; Bagno, A. Chem. Eur. J. 2008, 14, 10445.
3. (a) Evens, A. M.; Tallman, M. S.; Gartenhaus, R. B. Leuk. Res. 2004, 25, 891.
4. (b) Miller, W. H.Jr.; Schipper, H. M.; Lee, J. S.; Singer, J.; Waxman, S. Cancer Res. 2002, 62, 3893.
5. (c) Chen, H.; MacDonald, R. C.; Li, S.; Krett,N. L.; Rosen, S. T.; O'Halloran, T. V J. Am. Chem. Soc. 2006, 125, 13348.
6. Sommer, K. Z. Anorg. Allg. Chem. 1970, 377, 120.
7. 6 in THF. The pure tetraarsine was isolated as a colorless liquid following elution with dichloromethane-n-hexane from a silica plate with use of a Chromatotron.
8. Sommer, K. Z. Anorg. Allg. Chem. 1970, 377, 128.
9. 2) = 0.182. All of the crystals of this compound examined were twinned. The nature of the twinning was identified and the ratio of the two components refined.
10. Kopf, J.; von Deuten, K.; Klar, G. Inorg. Chim. Acta 1980, 55, 67.
11. Francesconi, K. A.; Keuhnelt, D. In Environmental Chemistry of Arsenic; Frankenberger, W. T., Jr., Ed.; Marcel Dekker: New York, 2002; Chapter 3, pp 51-116.