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Volumn 63, Issue 14, 1998, Pages 4732-4740

Synthesis of (±)-allocyathin B2 and (+)-erinacine A

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; CARBONYL DERIVATIVE; DITERPENE; PALLADIUM; XYLOSE;

EID: 7344254688     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9804700     Document Type: Article
Times cited : (46)

References (58)
  • 15
    • 0019813172 scopus 로고
    • For unsuccessful approaches to cyathins see: (a) Ayer, W. A.; Ward, D. E.; Browne, L. M.; Delbaere, L. T. J.; Hoyano, Y. Can. J. Chem. 1981, 59, 2665. (b) Ward, D. E. Can. J. Chem. 1987, 65, 2380. (c) Dahnke, K. R.; Paquette, L. A. J. Org. Chem. 1994, 59, 885.
    • (1981) Can. J. Chem. , vol.59 , pp. 2665
    • Ayer, W.A.1    Ward, D.E.2    Browne, L.M.3    Delbaere, L.T.J.4    Hoyano, Y.5
  • 16
    • 0000718903 scopus 로고
    • For unsuccessful approaches to cyathins see: (a) Ayer, W. A.; Ward, D. E.; Browne, L. M.; Delbaere, L. T. J.; Hoyano, Y. Can. J. Chem. 1981, 59, 2665. (b) Ward, D. E. Can. J. Chem. 1987, 65, 2380. (c) Dahnke, K. R.; Paquette, L. A. J. Org. Chem. 1994, 59, 885.
    • (1987) Can. J. Chem. , vol.65 , pp. 2380
    • Ward, D.E.1
  • 17
    • 0028353349 scopus 로고
    • For unsuccessful approaches to cyathins see: (a) Ayer, W. A.; Ward, D. E.; Browne, L. M.; Delbaere, L. T. J.; Hoyano, Y. Can. J. Chem. 1981, 59, 2665. (b) Ward, D. E. Can. J. Chem. 1987, 65, 2380. (c) Dahnke, K. R.; Paquette, L. A. J. Org. Chem. 1994, 59, 885.
    • (1994) J. Org. Chem. , vol.59 , pp. 885
    • Dahnke, K.R.1    Paquette, L.A.2
  • 42
    • 7344236283 scopus 로고    scopus 로고
    • note
    • 6ax. Molecular mechanics calculations indicate that 38 is rigid and that the pseudoequatorial α′ proton that is long-range coupled to the α proton with J = 1.0 Hz should be vicinally coupled to CHOSi with a small coupling constant (1.5 Hz), as is observed. In the diastereomer of 38, the pseudoequatorial α′ proton would be vicinally coupled to CHOSi with a large coupling constant.
  • 51
    • 7344219886 scopus 로고    scopus 로고
    • note
    • 27b the observed value for 17 is consistent with a 2,4-cycloheptadienone.
  • 53
    • 7344238540 scopus 로고    scopus 로고
    • note
    • 2, erinacine A, and erinacine A triacetate.
  • 57
    • 7344251227 scopus 로고    scopus 로고
    • All synthetic compounds are racemic, except for 4 and 42-44
    • All synthetic compounds are racemic, except for 4 and 42-44.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.