Kinetics of the hydration of ethylene oxide in the presence of heterogeneous catalyst

Industrial and Engineering Chemistry Research

Volumn 48, Issue 24, 2009, Pages 10840-10844

  Altiokka, Mehmet Riza ^a   Akyalçin, Sema ^a  

^a ANADOLU UNIVERSITY   (Turkey)

Author keywords

[No Author keywords available]

Indexed keywords

ABSOLUTE TEMPERATURES; ANION EXCHANGE RESINS; HETEROGENEOUS CATALYST; HETEROGENEOUSLY CATALYZED REACTIONS; HOMOGENEOUS MECHANISM; HYDRATION OF ETHYLENE; KINETIC DATA; RATE EXPRESSION; SERIES-PARALLEL; STYRENE-DIVINYLBENZENE; TEMPERATURE DEPENDENCIES; UNCATALYZED REACTIONS;

BATCH REACTORS; CATALYSIS; CATALYSTS; ETHYLENE; HYDRATION; INSECTICIDES; RESINS; STYRENE;

RATE CONSTANTS;

EID: 73349088702     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie901037w     Document Type: Article

References (21)

1. Kirk, R. E.; Othmer, D. F. In Encyclopedia of Chemical Technology; Seidel, A., Ed.; John Wiley and Sons: New York, 2005; pp 644-660.
2. Weissermel, K.; Arpe, H.-J. Industrial Organic Chemistry; Wiley-VCH: New York, 1993.
3. Othmer, D. F.; Thakar, M. S. Glycol Production-Hydration of Ethylene Oxide. Ind. Eng. Chem. 1958, 50, 1235.
4. Keen, B. T. Carbon Dioxide-Enhanced Monoalkylene Glycol Production. U.S. Patent 4,578,524, 1986.
5. Masuda, T.; Asona, K.; Hori, N.; Ando, S. Method for Preparing Ethylene Glycol and/or Propylene Glycol. U.S. Patent 4,937,393, 1990.
6. Kozlovsky, I. A.; Kovzlovsky, R. A.; Koustov, A. V.; Makarov, M. G.; Suchkov, J. P.; Shvets, V. F. Kinetics and Products Distribution of Selective Catalytic Hydration of Ethylene and Propylene Oxides in Concentrated Aqueous Solutions. Org. Process Res. Dev. 2002, 6, 660.
7. Van Hal, J. W.; Ledford, J. S.; Zhang, X. Investigation of Three Types of Catalysts for the Hydration of Ethylene Oxide (EO) to Monoethylene Glycol (MEG). Catal. Today 2007, 123, 310.
8. Reed, L. M.; Wenzel, L. A.; O'Hara, J. B. Catalytic Hydration of Ethylene Oxide: Applying Ion Exchange Resins as Catalysts. Ind. Eng. Chem. 1956, 48, 205.
9. Johnson, F. L.; Watts, L. W. Process for the Production of Alkylene Glycols. U.S. Patent 4,393,254, 1983.
10. Reman, W. G.; Van Kruchten, E. M. G. A. Process for the Preparation of Alkylene Glycols. U.S. Patent 5,488,184, 1996.
11. Shvets, V. F.; Kozlovskiy, R. A.; Kozlovskiy, I. A.; Makarov, M. G.; Suchkov, J. P.; Koustov, A. V. The Model of Catalytic Reactor of Ethylene Glycol Production. Org. Process Res. Dev. 2005, 9, 768.
12. Shvets, V. F.; Kozlovskiy, R. A.; Kozlovskiy, I. A.; Makarov, M. G.; Suchkov, J. P.; Koustov, A. V. The Cause and Quantitative Description of Catalyst Deactivation in the Ethylene Oxide Hydration Process. Chem. Eng. J. 2005, 107, 199.
13. Li, Y.; Yan, S.; Yue, B.; Yang, W.; Xie, Z.; Chen, Q.; He, H. Selective Catalytic Hydration of Ethylene Oxide over Niobium Oxide Supported on R-Alumina. Appl. Catal., A 2004, 272, 305.
14. Altiokka, M. R.; Citak, A. Kinetics Study of Esterification of Acetic Acid with Isobutanol in the Presence of Amberlite Catalyst. Appl. Catal., A 2003, 239, 141.
15. Van Kruchten, E. M. G. A.; Kunin, R.; Lemansaki, M. F. Catalyst Stabilising Additive in the Hydrolysis of Alkylene Oxides. WO Patent 0035841, 2000.
16. Skoog, D. A.; West, D. M.; Holler, F. J. Fundamentals of Analytical Chemistry; Saunders College: Orlando, FL, 1996.
17. Fogler, H. S. Elements of Chemical Reaction Engineering; Prentice-Hall: Englewood Cliffs, NJ, 1992.
18. Jenson, V. G.; Jeffreys, G. V. Mathematical Methods in Chemical Engineering; Academic Press: New York, 1977.
19. Mcclellan, P. P. Manufacture and Uses of Ethylene Oxide and Ethylene Glycol. Ind. Eng. Chem. 1950, 42, 2402.
20. Madon, R. J.; Boudart, M. Experimental Criterion for the Absence of Artifacts in the Measurement of Rates of Heterogeneous Catalytic Reactions. Ind. Eng. Chem. Fundam. 1982, 21, 438.
21. Levenspiel, O. Chemical Reaction Engineering; John Wiley and Sons: New York, 1999.