Isotope-sensitive degenerate [1,3]-hydrogen migration versus competitive enol-keto tautomerization

Chemistry - A European Journal

Volumn 15, Issue 44, 2009, Pages 11815-11819

  Zhang, Xinhao ^a   Zummack, Waltraud ^a   Schroder, Detlef ^b   Weinhold, Frank A ^c   Schwarz, Helmut ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b INSTITUTE OF ORGANIC CHEMISTRY AND BIOCHEMISTRY   (Czech Republic)

^c UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

Hydrogen migration; Isotope effects; Keto enol tautomerism; Nonergodic behavior; Reaction mechanisms

Indexed keywords

CATION-RADICALS; DISSOCIATIVE IONIZATION; ELECTRON IONIZATION; HYDROGEN MIGRATION; ISOTOPE EFFECT; ISOTOPOLOGUES; KETO-ENOL TAUTOMERISM; LABORATORY PROCEDURES; LEWIS STRUCTURE; NATURAL BOND ORBITAL; NATURAL RESONANCE; OUT-OF-PLANE; P-TYPE; RADICAL CATIONS; REACTION MECHANISM; TAUTOMERIZATIONS; TRANSITION PATHWAY; UNIMOLECULAR DISSOCIATION;

ACETONE; AIR PURIFICATION; CARRIER MOBILITY; CHROMATOGRAPHIC ANALYSIS; ELECTRON SPIN RESONANCE SPECTROSCOPY; GAS CHROMATOGRAPHY; HYDROGEN; ISOTOPES; PARTICLE DETECTORS; PHOTODISSOCIATION; POSITIVE IONS;

IONIZATION OF GASES;

EID: 73249151656     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902176     Document Type: Article

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