Non-equilibrium thermodynamics of the gas-liquid interface: Measurement of the Onsager heat of transport for ammonia at the surface of water

Journal of Non-Equilibrium Thermodynamics

Volumn 34, Issue 3, 2009, Pages 265-275

  Currie, Robert B ^a   Phillips, Leon F ^a  

^a UNIVERSITY OF CANTERBURY   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

AIR-SEA EXCHANGE; AVERAGE VALUES; CONFIDENCE LIMIT; FIELD MEASUREMENT; GAS-LIQUID INTERFACE; METAL SURFACES; NON EQUILIBRIUM THERMODYNAMICS; ONSAGER; ONSAGER HEAT OF TRANSPORT; THERMAL ACCOMMODATION COEFFICIENT;

AMMONIA; CHEMISORPTION; GLOBAL WARMING; GREENHOUSE GASES; LIQUIDS; MARTENSITIC STAINLESS STEEL; STAINLESS STEEL;

PHASE INTERFACES;

EID: 73249125205     PISSN: 03400204     EISSN: 14374358     Source Type: Journal    
DOI: 10.1515/JNETDY.2009.014     Document Type: Article

References (30)

1. Denbigh, K. G., Raumann, G., The thermo-osmosis of gases through a membrane. I. Theoretical, Proc. R. Soc. London, A210 (1952), 377-387.
2. Denbigh, K. G., Raumann, G., The thermo-osmosis of gases through a membrane. II. Experimental, Proc. R. Soc. London, A210 (1952), 518-533.
3. Spanner, D. C., The active transport of water under temperature gradients, Symp. Soc. Exper. Biol., 8 (1954), 76-93.
4. Kjelstrup, S., Bedeaux, D., Non-Equilibrium Thermodynamics of Heterogeneous Systems, World Scientific, Singapore, 2008.
5. Phillips, L. F., Surfing the nanowaves: Progress in understanding the gas-liquid interface, Acc. Chem. Res, 37 (2004), 982-988.
6. Pao, Y-P., Application of kinetic theory to the problem of evaporation and condensation, Phys. Fluids (1958-1988), 14 (1971), 306-312.
7. Fang, G., Ward C. A., Temperature measured close to the interface of an evaporating liquid, Phys. Rev. E, 59 (1999), 417-428.
8. Ward, C. A, Stanga, D, Interfacial conditions during evaporation or condensation of water, Phys. Rev. E, 64 (2001), 051509/1-051509/9.
9. Mills, C. T., Phillips, L. F, Distillation of a cool liquid onto a warmer surface, Chem. Phys. Lett, 372 (2003), 615-619.
10. Mills, C. T., Bones, D. L, Casavecchia, P., Phillips, L. F., Onsager heat of transport measured at the nheptanol liquid-vapour interface, J. Phys. Chem. B, 108 (2004), 2681-2685.
11. Phillips, L. F, Onsager heat of transport at the n-octane liquid-vapour interface: Effects of altering the size of the vapour-gap and of adding helium, Chem. Phys. Lett, 458 (2008), 388-390.
12. James, R. A., Phillips, L. F, Onsager heat of transport for water vapour at the surface of sulfuric acid, Chem. Phys. Lett, 407 (2005), 358-361.
13. James, R. A., Phillips, L. F, Onsager heat of transport for water vapour at the surface of glycerol, Chem. Phys. Lett, 425 (2006), 49-52.
14. Phillips, L. F, Surface concentrations and compound formation in aqueous sulphuric acid, Aust. J. Chem., 47 (1994) 91-99.
15. Pursell, C. J, Phillips, L. F., Onsager heat of transport for water vapour at the surface of water and ice: Thermal accommodation coefficients for water vapour on a stainlesssteel surface, Phys. Chem. Chem. Phys, 8 (2006), 4694-4699.
16. Biggs, G. A, Phillips, L. F, BET analysis of thermal accommodation coefficients obtained via measurements of the Onsager heat of transport, Chem. Phys. Lett, 452 (2008), 84-88.
17. Loyalka, S. K, Siewert, C. E., Thomas, J. R., Temperature-jump problem with arbitrary accommodation, Phys. Fluids, 21 (1978), 854-855.
18. Wexler, A, Greenspan, L., Vapor pressure equation for water in the range 0 to 100, J. Res. Natl. Bur. Stand, 75 (1971), 213-230.
19. Dasgupta, P. K., Dong, S., Solubility of ammonia in liquid water and generation of trace levels of standard gaseous ammonia, Atmos. Environ, 20 (1986), 565-570.
20. Phillips, L. F., Onsager heat of transport as a consequence of detailed balance at the gas-liquid interface, Chem. Phys. Lett, 396 (2004), 350-352.
21. Brunauer, S., Love, K. S., Keenan, R. G., Adsorption of nitrogen and the mechanism of ammonia decomposition over iron catalysts, J. Am. Chem. Soc, 64 (1942), 751-758.
22. Grunze, M., Ertl, G., UPS and thermal desorption studies on the interaction of ammonia with an iron (111) surface, Proc. Int. Vac. Congr., 7th, 2 (1977), 1137-1140.
23. Yoshida, K., Somorjai, G. A., The chemisorption of carbon monoxide, carbon dioxide, acetylene, ethylene, hydrogen, and ammonia on the clean iron (100) and (111) crystal surfaces, Surf. Sci, 75 (1978), 46-60.
24. Drechsler, M., Hoinkes, H., Kaarmann, H., Wilsch, H., Ertl, G., Weiss, M., Interaction of ammonia with iron (110): Identification of surface species by means of secondary ion mass spectroscopy (SIMS), Appl. Surf. Sci, 3 (1979), 217-228.
25. Weiss, M, Ertl, G., Nitschke, F, Adsorption and decomposition of ammonia on iron (110), Appl. Surf. Sci, 2 (1979), 614-635.
26. Yoshida, K, Adsorption of ammonia on iron single crystal surfaces; (110), (111) and stepped (111) surfaces, J. Res. Inst. Catalysis, 28 (1980), 15-30.
27. Benndorf, C, Madey, T. E., Johnson, A. L, Ammonia adsorption and dissociation on a stepped iron (s) (100) surface, Surf. Sci, 187 (1987), 434-444.
28. Ma, H, Berthier, Y, Marcus, P, AES, XPS, and TDS study of the adsorption and desorption of NH3 on ultrathin chromium oxide films formed on chromium single crystal surfaces, Appl. Surf. Sci, 153 (1999), 40-46.
29. Jäime, B, Haußecker, H, Air-water gas exchange, Ann. Rev. FluidMech, 30 (1998), 443-468.
30. Pawlikowskl, E. M, Newman, J., Prausnltz, J. M, Phase equilibriums for aqueous solutions of ammonia and carbon dioxide, Ind. Eng. Chem. Process Des. Dev, 21 (1982), 764-770.