Nonlocal chemical reactivity at organic - Metal interfaces

ACS Nano

Volumn 3, Issue 11, 2009, Pages 3684-3690

  Chen, Lan ^a   Li, Hui ^a   Wee, Andrew Thye Shen ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Chemical reactions; Electron transport; Interface; Scanning tunneling microscopy; Surface

Indexed keywords

AU(1 1 1 ); COPPER-HEXADECAFLUOROPHTHALOCYANINE; DIFFERENT SUBSTRATES; ELECTRON TRANSPORT; HOT-ELECTRON TRANSPORT; INTERFACE; NONLOCAL; ORGANIC-INORGANIC INTERFACE; ORGANIC-METAL INTERFACES; RESEARCH FIELDS; SCANNING TUNNELING MICROSCOPES; SUBSTRATE INTERFACE; SURFACE PHYSICS; THEORETICAL RESULT;

ELECTRON TRANSITIONS; ELECTRON TRANSPORT PROPERTIES; GRAFTING (CHEMICAL); HOT ELECTRONS; MONOLAYERS; SCANNING; SCANNING TUNNELING MICROSCOPY; SILVER; SUBSTRATES; SURFACE REACTIONS; WIND TUNNELS;

SYNTHESIS (CHEMICAL);

EID: 73249119953     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn900811t     Document Type: Article

References (32)

1. Zhu, X. Y. Surface Photochemistry. Annu. Rev. Phys. Chem. 1994, 45, 113-144.
2. Lindstrom, C. D.; Zhu, X. Y. Photoinduced Electron Transfer at Molecule-Metal Interface. Chem. Rev. 2006, 706, 4281-4300.
3. 2 Surfaces-Principles, Mechnisms, and Selected Results. Chem. Rev. 1995, 95, 735-758.
4. Ho, P. K. H.; Kim, J. S.; Burroughes, J. H.; Becker, H.; Li, S. F. Y.; Brown, T. M.; Cacialli, F.; Friend, R. H. Molecular-Scale Interface Engineering for Polymer Lighting-Emitting Diodes. Nature 2000, 404, 481-484.
5. Nitzan, A.; Ratner, M. A. Electron Transport in Molecular Wire Junctions. Science 2003, 300, 1384-1389.
6. Zhu, X. Y. Electronic Structure and Electron Dynamics at Molecule-Metal Interfaces: Implications for Molecule-Based Electronics. Surf. Sci. Rep. 2004, 56, 1-83.
7. Wang, L.; Chen, W.; Wee, A. T. S. Charge Transfer Across the Molecule/Metal Interface Using the Core Hole Clock Technique.Surf. Sci. Rep. 2008, 63, 465-486.
8. 4/Ag(111). Phys. Rev. Lett. 1991, 67, 2395-2398.
9. Ho, W. Single-Molecule Chemistry. J. Chem. Phys. 2002, 117, 11033-11061.
10. Komeda, T. Chemical Identification and Manipulation of Molecules by Vibrational Excitation via Tunneling Process with Scanning Tunneling Microscopy. Prog. Surf. Sci. 2005, 78, 41-85.
11. Alemani, M.; Peters, M. V.; Hecht, S.; Rieder, K.-H.; Moresco, F.; Grill, L. Electric Field-Induced Isomerization of Azoben-zene by STM. J. Am. Chem. Soc. 2006, 728, 14446-14447.
12. Maksymovych, P.; Dougherty, D. B.; Zhu, X. Y.; Yates, J. T. Nonlocal Dissociative Chemistry of Adsorbed Molecules Induced by Localized Electron Injection into Metal Surfaces. Phys. Rev. Lett. 2007, 99, 016101.
13. 60 Polymers Formed by Electron or Hole Injection from a Scanning Tunneling Microscope Tip. Phys. Rev. Lett. 2006, 97, 196101.
14. Maksymovych, P.; Sorescu, D. C.; Jordan, K. D.; Yates, J. T. Collective Reactive of Molecular Chains Self-Assembled on a Surface. Science 2008, 322, 1664-1667.
15. 16CuPc Thin Film on Ag(111). J. Phys. Chem. C 2008, 772, 14913-14918.
16. Lancu, V.; Deshpande, A.; Hla, S.-W. Manipulating Kondo Temperature via Single Molecule Switching. Nano Lett. 2006, 6, 820-823.
17. Zhao, A. D.; Li, Q. X.; Chen, L.; Xiang, H. J.; Wang, W. H.; Pan, S.; Wang, B.; Xiao, X. D.; Yang, J. L.; Hou, J. G.; et al. Controlling the Kondo Effect of an Adsorbed Magnetic Ion through Its Chemical Bonding. Science 2005, 309, 1542-1544.
18. Ghosh, A.; Gassman, P. G.; Almlof, J. Substituent Effects in Porphyrazines and Phthalocyanines. J. Am. Chem. Soc. 1994, 776, 1932-1940.
19. Komeda, T.; Kim, Y.; Fujita, Y.; Sainoo, Y.; Kawai, M. Local Chemical Reaction of Benzene on Cu(110) via STM-Induced Excitation. J. Chem. Phys. 2005, 720, 5347-5352.
20. Sloan, P. A.; Palmer, R. E. Two-Electron Dissociation of Single Molecules by Atomic Manipulation at Room Temperature. Nature 2005, 434, 367-371.
21. Hla, S. W.; Bartels, L.; Meyer, G.; Rieder, K. H. Inducing All Steps of a Chemical Reaction with the Scanning Tunneling Microscope Tip: Towards Single Molecule Engineering. Phys. Rev. Lett. 2000, 85, 2777-2780.
22. Palmer, R. E. Electron-Molecule Dynamics at Surfaces. Prog. Surf. Sci. 1992, 47, 51-108.
23. Liljeroth, P.; Repp, J.; Meyer, G. Current-Induced Hydrogen Tautomerization and Conductance Switching of Naphtha-locyanine Molecules. Science 2007, 377, 1203-1206.
24. 16CuPc on Cu(111) and Ag(111): An X-ray Standing Wave Study. Phys. Rev. B 2005, 77, 205425.
25. Bartels, L.; Meyer, G.; Rieder, K. H.; Velic, D.; Knoesel, E.; Hotzel, A.; Wolf, M.; Ertl, G. Dynamics of Electron-Induced Manipulation of Individual CO Molecules on Cu(111). Phys. Rev. Lett. 1998, 80, 2004-2007.
26. Chulkov, E. V.; Borisov, A. G.; Gauyacq, J. P.; Sanchez-Portal, D.; Silkin, V. M.; Zhukov, V. P.; Echenique, P. M. Electronic Excitations in Metals and at Metal surfaces. Chem. Rev. 2006, 706, 4160-4206.
27. Hulbert, S. L.; Johnson, P. D.; Stoffel, N. G.; Smith, N. V. Unoccupied Bulk and Surface States on Ag(111) Studied by Inverse Photoemission. Phys. Rev. B 1985, 32, 3451-3455.
28. Woodruff, D. P.; Royer, W. A.; Smith, N. V. Empty Surface States, Image States, and Band Edge on Au(111). Phys. Rev. B 1986, 34, 764-767.
29. 60 Molecular Chains. Adv. Mater. 2008, 20, 484-488.
30. Perdew, J. P.; Zunger, A. Self-interaction Correction to Density-Function Approximations for Many-Electron Systems. Phys. Rev. B 1981, 23, 5048-5079.
31. Kresse, G.; Hafner, J. Norm-Conserving and Ultrasoft Pseudopotentials for First-Law and Transition-Elements. J. Phys.: Condens. Matter 1994, 6, 8245-8257.
32. Kresse, G.; Furthmüller, J. Efficient Iterative Schemes for Ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set. Phys. Rev. B 1996, 54, 11169-11186.