Molecular composition of soluble fraction from depolymerized cornstalk powder in supercritical methanol and ethanol

Renewable Energy

Volumn 35, Issue 5, 2010, Pages 946-951

  Tang, Shi Rong ^a,b   Zong, Zhi Min ^a   Zhou, Lei ^a   Zhao, Wei ^a   Li, Xiao Bo ^a   Peng, Yao Li ^a   Xie, Rui Lun ^a   Chen, Xiao Fei ^c   Gu, Wen Tao ^c   Wei, Xian Yong ^a,c  

^a CHINA UNIVERSITY OF MINING AND TECHNOLOGY   (China)

^b XUZHOU INSTITUTE OF TECHNOLOGY   (China)

^c WUHAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Cornstalk; Depolymerization; FTIR analysis; GC MS analysis; Supercritical ethanol; Supercritical methanol

Indexed keywords

DIESTERS; DIETHYL PHTHALATE; DIFFERENT SOLVENTS; DIHYDROXYBENZENES; ETHYL ESTERS; FTIR; FTIR ANALYSIS; GC/MS ANALYSIS; METHOXYBENZENE; METHYL ESTERS; MOLECULAR COMPOSITIONS; OXYGEN-CONTAINING SPECIES; SOLUBLE FRACTION; SUPERCRITICAL ETHANOL; SUPERCRITICAL METHANOL;

CHROMATOGRAPHIC ANALYSIS; ESTERIFICATION; ESTERS; ETHANOL; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROCARBONS; KETONES; METHANOL; OXYGEN;

REACTION KINETICS;

ETHANOL; FTIR SPECTROSCOPY; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; METHANOL; MOLECULAR ANALYSIS; POLYMERIZATION; SUPERCRITICAL FLOW;

EID: 73249114927     PISSN: 09601481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.renene.2009.11.037     Document Type: Article

References (25)

1. Cui P.L., Yan Y.J., Chuang Z.W., and Hai T.H. Study on the distribution and quantity of biomass residues resource in China. Biomass Bioenergy 27 2 (2004) 111-117
2. Antal M.J., Mok W.S., Roy J.C., Raissi A.T., and Anderson D.G. Pyrolytic sources of hydrocarbons from biomass. J Anal Appl Pyrol 8 (1985) 291-303
3. Matsumura Y., Nonaka H., Yokura H., Tsutsumi A., and Yoshida K. Co-liquefaction of coal and cellulose in supercritical water. Fuel 78 9 (1999) 1049-1056
4. Demirbas A. Biomass resource facilities and biomass conversion processing for fuels and chemicals. Energy Convers Manage 42 11 (2001) 1357-1378
5. Wang C., Du Z., Pan J., Li J., and Yang Z. Direct conversion of biomass to bio-petroleum at low temperature. J Anal Appl Pyrol 78 2 (2007) 438-444
6. Demirbas A. Progress and recent trends in biofuels. Prog Energy Combust Sci 33 1 (2007) 1-18
7. Wang J., Wang G., Zhang M., Chen M., Li D., Min F., et al. A comparative study of thermolysis characteristics and kinetics of seaweeds and fir wood. Process Biochem 41 8 (2006) 1883-1886
8. Demirbas M.F., and Balat M. Recent advances on the production and utilization trends of bio-fuels: a global perspective. Energy Convers Manage 47 15-16 (2006) 2371-2381
9. Bhattacharya S.C., Abdul S.P., Runqing H., Somashekar H.I., Racelis D.A., Rathnasiri P.G., et al. An assessment of the potential for non-plantation biomass resources in selected Asian countries for 2010. Biomass Bioenergy 29 3 (2005) 153-166
10. Qian Y., Zuo C., Tan J., and He J. Structural analysis of bio-oils from sub- and supercritical water liquefaction of woody biomass. Energy 32 3 (2007) 196-202
11. Song C., Hu H., Zhu S., Wang G., and Chen G. Nonisothermal catalytic liquefaction of corn stalk in subcritical and supercritical water. Energy Fuels 18 1 (2004) 90-96
12. Xu C., and Etcheverry T. Hydro-liquefaction of woody biomass in sub- and super-critical ethanol with iron-based catalysts. Fuel 87 3 (2008) 335-345
13. 4. Energy Fuels, in press, doi:10.1021/ef900535y.
14. Zhao W, Xu WJ, Lu XJ, Sheng C, Zhong ST, Zong ZM, et al. Preparation and property measurement of liquid fuel from supercritical ethanolysis of wheat stalk. Energy Fuels, in press, doi:10.1021/ef900521k.
15. http://www.grainmarket.com.cn/ReadNews.asp?NewsID=6332
16. Ji L.Z. Bio-oil from fast pyrolysis of rice husk: yields and related properties and improvement of the pyrolysis system. J Anal Appl Pyrol 80 1 (2007) 30-35
17. Hu S., Jess A., and Xu M. Kinetic study of Chinese biomass slow pyrolysis: comparison of different kinetic models. Fuel 86 17-18 (2007) 2778-2788
18. Zhang S., Yan Y., Li T., and Ren Z. Upgrading of liquid fuel from the pyrolysis of biomass. Bioresour Technol 96 5 (2005) 545-550
19. Cui P.L., Chuang Z.W., Yan Y.J., and Hai T.H. Chemical elemental characteristics of biomass fuels in China. Biomass Bioenergy 27 2 (2004) 119-130
20. Wang C., Pan J., Li J., and Yang Z. Comparative studies of products produced from four different biomass samples via deoxy-liquefaction. Bioresource Technol 99 8 (2008) 2778-2786
21. Zhao W., Zong Z.M., Lin J., Song Y.M., Guo X.F., Yao Z.S., et al. Dewaxing from stalks with petroleum ether by different methods. Energy Fuels 21 2 (2007) 1165-1168
22. Kershaw J.R. Comments on the role of the solvent in supercritical fluid extraction of coal. Fuel 76 5 (1997) 453-454
23. Wahyudiono M.S., and Motonobu G. Recovery of phenolic compounds through the decomposition of lignin in near and supercritical water. Chem Eng Process 47 9-10 (2008) 1609-1619
24. Wang M., Xu C.B., and Leitch M. Liquefaction of cornstalk in hot-compressed phenol-water medium to phenolic feedstock for the synthesis of phenol-formaldehyde resin. Bioresource Technol 100 7 (2009) 2305-2307
25. Liu Z.G., and Zhang F.S. Effects of various solvents on the liquefaction of biomass to produce fuels and chemical feedstocks. Energy Convers Manage 49 12 (2008) 3498-3504