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Single crystal diffraction data were recorded on a Bruker Apex II CCD diffractometer at 173(2) K employing Mo Kα radiation (λ, 0.71073 Å, graphite monochromator, Crystal data: molecular formula, C 2H15N6O9PtS2; molecular weight, 526.41 g/mol; crystal system, monoclinic; space group, P2 1/c (No. 14, a, 7.7441(3) Å, b, 19.2289(6) Å, c, 9.5902(3) Å, β, 91.6590(10)°, V, 1427.48(8)Å3, Z, 4, p, 2.454g/cm3 (calculated, μ, 10.17 mm-1, F(000, 1008; crystal size, 0.32 × 0.29 × 0.19 mm. Data collection: 2.12 ≤ θ ≤ 40.25°; index range, 14 ≤ h ≤ 14, 34 ≤ k ≤ 32, 17 ≤, ≤ 17. Observed reflections: 73967, unique reflections, 8962; observed reflections with I > 2σI, 8317; R int, 0.0354. Mod
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The X-ray structure of MS was experimentally not obtained because the conversion efficiency of 20% or 26% for the two compounds 1 and 2 is not sufficient to obtain quantitative data as was illustrated in some previous publications see ref 35, Moreover, it is expected to be rather difficult to detect a change in NO coordination besides the heavy Pt central atom. Given all the spectroscopic and numerical evidence, we could at best obtain some more qualitative information about the MS in these Pt-NO compounds. We would rather search a molecule with higher photoconversion efficiency in order to provide an accurate structure determination of MS
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The X-ray structure of MS was experimentally not obtained because the conversion efficiency of 20% or 26% for the two compounds 1 and 2 is not sufficient to obtain quantitative data as was illustrated in some previous publications (see ref 35). Moreover, it is expected to be rather difficult to detect a change in NO coordination besides the heavy Pt central atom. Given all the spectroscopic and numerical evidence, we could at best obtain some more qualitative information about the MS in these Pt-NO compounds. We would rather search a molecule with higher photoconversion efficiency in order to provide an accurate structure determination of MS.
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