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Volumn 113, Issue 47, 2009, Pages 13418-13427

Dipole moment of water in highly vibrationally excited states: Analysis of photofragment quantum-beat spectroscopy measurements using a local-mode hamiltonian

Author keywords

[No Author keywords available]

Indexed keywords

ANHARMONIC OSCILLATORS; BOND-STRETCHING; COMPLEX INTERACTION; DIFFERENT TIME SCALE; DIPOLE MOMENT SURFACES; EQUIVALENT BONDS; EXPERIMENTAL VALUES; INERTIAL FRAMES; OH STRETCHING VIBRATIONS; PHOTOFRAGMENTS; QUANTUM BEAT SPECTROSCOPY; SIMPLE MODEL; SPECTROSCOPY MEASUREMENTS; VIBRATIONAL MOTIONS; VIBRATIONAL STATE; VIBRATIONALLY EXCITED; VIBRATIONALLY EXCITED STATE;

EID: 72949109618     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp904035g     Document Type: Article
Times cited : (2)

References (42)
  • 2
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    • (2000) Chemistry of Atmospheres
    • Wayne, R.P.1
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    • (1996) Science , vol.273 , pp. 779
    • Arking, A.1
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    • 0041460518 scopus 로고
    • Scoles, G., Ed.; Oxford University Press: London Chapter 2
    • Muenter, J. S. In Atomic and Molecular Beam Methods; Vol.II; Scoles, G., Ed.; Oxford University Press: London: 1992; Vol.II, Chapter 2, pp 15-57.
    • (1992) In Atomic and Molecular Beam Methods; Vol.II , vol.2 , pp. 15-57
    • Muenter, J.S.1
  • 26
    • 72949096024 scopus 로고    scopus 로고
    • Another commonly used labeling scheme for the vibrational states of water is based on the normal mode notation (1-2-3). The correlation between local mode and normal mode notation for the states we studied is given here for completeness: |4,0-→ T (301); |4,0-|2→ T (321); |5,0-→ T (401); |8,0+→ T (800)
    • Another commonly used labeling scheme for the vibrational states of water is based on the normal mode notation (1-2-3). The correlation between local mode and normal mode notation for the states we studied is given here for completeness: |4,0-→ T (301); |4,0-|2→ T (321); |5,0-→ T (401); |8,0+→ T (800).
  • 35
    • 0000711186 scopus 로고
    • Pickett, H. M. J. Mol. Spectrosc. 1991, 148, 371-377. http://spec.jpl.nasa.gov/ftp/pub/calpgm/.
    • (1991) J. Mol. Spectrosc. , vol.148 , pp. 371-377
    • Pickett, H.M.1
  • 39
    • 72949093697 scopus 로고    scopus 로고
    • Alternatively, the relevant rotational constants can be extrapolated from the accurately known constants of the ground-and first excited-states. This gives fairly good results for Gxz/2: respectively 1.28, 1.28, 1.59, and 2.55 for |40-, |40-2, |50-, and |80+. The results for {A, B, C} are less satisfactory: respectively, {23.90, 13.91, 8.65}, {31.60, 14.23, 8.35}, {22.90, 13.75, 8.50}, and {19.92, 13.29, 8.03}
    • Alternatively, the relevant rotational constants can be extrapolated from the accurately known constants of the ground-and first excited-states. This gives fairly good results for Gxz/2: respectively 1.28, 1.28, 1.59, and 2.55 for |40-, |40-2, |50-, and |80+. The results for {A, B, C} are less satisfactory: respectively, {23.90, 13.91, 8.65}, {31.60, 14.23, 8.35}, {22.90, 13.75, 8.50}, and {19.92, 13.29, 8.03}.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.