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Volumn 9, Issue 11, 2009, Pages 4592-4594

A nanosized uranyl camphorate cage and its use as a building unit in a metal - organic framework

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EID: 72949095838     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg900851s     Document Type: Article
Times cited : (43)

References (35)
  • 22
    • 72949123192 scopus 로고    scopus 로고
    • Synthesis of 1, 1R, 3S, -Camphoric acid (40 mg, 0.20 mmol, UO 2(NO3)2-6H2O (100 mg, 0.20 mmol, 1,4-diazabicyclo[2.2.2]-octane (DABCO, 22 mg, 0.20 mmol, and demineralized water (2 mL) were placed in a 15 mL tightly closed glass vessel and heated at 180 °C under autogenous pressure, yielding yellow crystals of complex 1 within three days (61 mg, 77% based on the acid, Anal. Caled for C 120H200O76U8: C, 30.26; H, 4.23. Found: C, 30.28; H, 5.29, Synthesis of 2, 1R, 3S, )-Camphoric acid (20 mg, 0.10 mmol, UO2(NO3)2-6H2O (50 mg, 0.10 mmol, Ba-(CH3COO)2 (26 mg, 0.10 mmol, and demineralized water (3 mL) were placed in a 15 mL tightly closed glass vessel and heated at 180 °C under autogenous pressure, yielding yellow crystals of complex 2 in low yield within three days
    • 2 (26 mg, 0.10 mmol), and demineralized water (3 mL) were placed in a 15 mL tightly closed glass vessel and heated at 180 °C under autogenous pressure, yielding yellow crystals of complex 2 in low yield within three days.
  • 23
    • 72949105294 scopus 로고    scopus 로고
    • Crystallographic data were collected at 100(2) K (1) or 150(2) K (2) on a Nonius Kappa-CCD area-detector diffractometer17 and processed with HKL2000.18 Absorption effects were corrected with SCALEPACK. 18 The structures were solved by direct methods and refined by full-matrix least-squares on F2 with SHELXTL.19 All non-hydrogen atoms were refined with anisotropic displacement parameters. The hydrogen atoms bound to oxygen atoms were not found and the carbon-bound hydrogen atoms were introduced at calculated positions. The drawings were done with ORTEP-3/ POV-Ray20 and Balls & Sticks.21 Crystal data for 1: C120H200O76U8, M, 4763.04, tetragonal, space group I4, a, b, 17.9223(6, c, 33.2705(19) Å3, V, 10686.8(8) Å3 Z, 2. Refinement of 470 parameters on 9497 independent reflections out of 74327 measured reflections Rint
    • -3.
  • 31
    • 0004281430 scopus 로고    scopus 로고
    • Nonius BV: Delft, The Netherlands
    • Hooft, R. W. W. COLLECT; Nonius BV: Delft, The Netherlands, 1998.
    • (1998) COLLECT
    • Hooft, R.W.W.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.