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Volumn 48, Issue 23, 2009, Pages 10895-10897

A New 2D hybrid indate-germanate based on the linkages of Ge 4O10F2clusters and {In2O 6} dimers

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EID: 72949093847     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic901894m     Document Type: Article
Times cited : (10)

References (48)
  • 3
    • 0037142065 scopus 로고    scopus 로고
    • (c) Davis, M. E. Nature 2002, 417, 813.
    • (2002) Nature , vol.417 , pp. 813
    • Davis, M.E.1
  • 36
    • 72949108780 scopus 로고    scopus 로고
    • In a typical synthesis of 1, a mixture of In2O3 (0.103 g) and GeO2 (0.093 g) was dispersed to a stirring solution of H2O (2.0 mL) and dap (2.0 mL, Then HF (0.1 mL) was added, and the stirring was continued for 11 h at room temperature. The final mixture (pH 12.5) was heated in a Teflon-lined stainless steel autoclave at 180 °C for 15 days under autogenous pressure, and was then cooled to room temperature. The crystals were washed with distilled water and then dried in air. The yield was about 52, based on GeO2, Anal. Caled for 1: C, 7.63; H, 2.99; N, 5.94. Found: C, 7.84; H, 3.06; N, 5.97. IR (KBr pellet, cm-1, 3534 (m, 3436 (m, 3345 (m, 3268 (m, 2963 (w, 2873 (w, 1629 (s, 1584 (s, 1532 (s, 1468 (m, 1403 (w, 1273 (w, 1202 (w, 1150 (w, 1066 (m, 1014 (m, 878 (s, 826 (s, 781 (s, 742 (s, 587 (m, 522 (m, 419 m
    • -1): 3534 (m), 3436 (m), 3345 (m), 3268 (m), 2963 (w), 2873 (w), 1629 (s), 1584 (s), 1532 (s), 1468 (m), 1403 (w), 1273 (w), 1202 (w), 1150 (w), 1066 (m), 1014 (m), 878 (s), 826 (s), 781 (s), 742 (s), 587 (m), 522 (m), 419 (m).
  • 38
    • 72949107879 scopus 로고    scopus 로고
    • Crystal data for 1: Mr, 469.20, triclinio, P1, a, 7.0315(14) Å, b, 7.5416(15) Å, c= 11.232(2) Å, α= 100.46(3)°, β=93.65(3)°, γ=91.06(3)°, V= 584.26(19) Å3, Z=2, Dc=2.667 g cm -3, μ, 7.104 mm-1, F(000)=448, GOF= 1.050, a total of 3820 reflections were collected, 2080 of which were unique (Rint, 0.0237, R1 (wR2, 0.0292 (0.0663) for 161 parameters and 1796 reflections (I > 2σI, CCDC: 735647
    • 2) = 0.0292 (0.0663) for 161 parameters and 1796 reflections (I > 2σ(I)). CCDC: 735647.


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