On the formation and decomposition of the melonate ion in cyanate and thiocyanate melts and the crystal structure of potassium melonate, K 3[C6N7(NCN)3]

European Journal of Inorganic Chemistry

Volumn , Issue 33, 2009, Pages 4972-4981

  Sattler, Andreas ^a   Schnick, Wolfgang ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Nitrogen heterocycles; Reactions mechanisms; Structure elucidation; Thermal analysis

Indexed keywords

CHEMICAL REACTIONS; CRYSTAL STRUCTURE; IONS; NITROGEN; POTASSIUM; SINGLE CRYSTALS;

CRYSTALS STRUCTURES; DECOMPOSITION REACTION; HIGH-TEMPERATURE REACTION; NA+ IONS; NITROGEN HETEROCYCLES; PROLONGED REACTION; REACTION MECHANISM; SALT MELT; SELECTIVE DECOMPOSITION; STRUCTURE ELUCIDATION;

THERMOANALYSIS;

EID: 72949086650     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200900585     Document Type: Article

References (42)

1. L. Gmelin, Ann. Pharm. 1835, 15, 252-264.
2. 6] was used, as in old (early to mid 19th century) literature only the term ''Blutlaugensalz'' is used, which does not specify the oxidation state of iron, whereas newer literature gives oxidation states but is not consistent in interpretation.
3. a) J. Liebig, Ann. Chem. Pharm. 1844, 50, 337-361;
4. b) J. Liebig, Ann. Chem. Pharm. 1847, 61, 262-264;
5. c) J. Liebig, Ann. Chem. Pharm. 1855, 95, 257-282.
6. B. V. Lotsch, M. Döblinger, J. Sehnert, L. Seyfarth, J. Senker, O. Oeckler, W. Schnick, Chem. Eur. J. 2007, 13, 4969-4980.
7. J. Klason, J. Prakt. Chem. 1886, 33, 285-289.
8. B. Jürgens, Doctoral Thesis, University of Munich (LMU), 2004.
9. T. Komatsu, T. Nakamura, J. Mater. Chem. 2001, 11, 474-478.
10. a) B. Jürgens, W. Milius, P. Morys, W. Schnick, Z. Anorg. Allg. Chem. 1998, 624, 91-97;
11. b) B. Jürgens, E. Irran, J. Schneider, W. Schnick, Inorg. Chem. 2000, 39, 665-670;
12. c) E. Irran, B. Jürgens, W. Schnick, Chem. Eur. J. 2001, 7, 5372-5381.
13. B. V. Lotsch, W. Schnick, Chem. Mater. 2006, 18, 1891-1900.
14. a) E. Kroke, M. Schwarz, E. Horvath-Bordon, P. Kroll, B. Noll, A. D. Norman, New J. Chem. 2002, 26, 508-512;
15. b) T. Komatsu, J. Mater. Chem. 2001, 11, 802-805.
16. [11]W. L. Burdick, J. Am. Chem. Soc, 1925, 47, 1485-1490.
17. a) S. G. Fedoruk, A. I. Finkel'shtein, N. V. Spiridonova, Zh. Obshch. Khim. 1972, 42, 419-420;
18. b) S. G. Fedoruk, A. I. Finkel'shtein, N. V. Spiridonova, Trudy po Khimii i Khimicheskoi Tekhnologii 1975, 106-109.
19. E. Horvath-Bordon, E. Kroke, I. Svoboda, H. Fuess, R. Riedel, New J. Chem. 2005, 29, 693-699.
20. a) S. J. Makowski, W. Schnick,Z. Anorg. Allg. Chem. DOI:10.1002/zaac200900232;
21. b) S. J. Makowski, D. Gunzelmann, J. Senker, W. Schnick, Z. Anorg. Allg. Chem., DOI:10.1002/zaac200900231.
22. C. Clauss, J. Wagler, M. Schwarz, A. Schwarzer, E. Kroke, Z. Anorg. Allg. Chem., DOI:10.1002/zaac200900326.
23. L. Pauling, J. H. Sturdivant, Proc. Natl. Acad. Sci. USA 1937, 23, 615-620.
24. C. E. Redemann, H. J. Lucas, J. Am. Chem. Soc. 1939, 61, 3420-3424.
25. D. R. Lide (Ed.), Handbook of Chemistry and Physics, 88th ed., The Chemical Rubber Co., Cleveland, Ohio, 2008, pp. 4-82 (KOCN), pp. 4-83 (KSCN), pp. 4-89 (NaOCN), pp. 4-91 (NaSCN).
26. Sicherheitsdatenblatt, Kaliumcyanat zur Synthese, Merk Schuchard OHG, Hohenbrunn, 2005, p. 3.
27. L. Gmelin, Gmelins Handbuch der anorganischen Chemie Natrium, 8th ed., Verlag Chemie GmbH, Weinheim, 1967, pp. 382-1386 (NaOCN), pp.1387-1397 (NaSCN).
28. L. Gmelin, Gmelins Handbuch der anorganischen Chemie Kalium, 8th ed., Verlag Chemie GmbH, Weinheim, 1937, pp. 890-894 (KOCN) pp. 894-913 (KSCN).
29. CCDC-732128 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data.-request/cif.
30. B. Jürgens, W. Milius, P. Morys, W. Schnick, Z. Anorg. Allg. Chem. 1998, 624, 91-97.
31. S. Grimme, Angew. Chem. 2008, 120, 3478-3483;
32. Angew. Chem. Int. Ed, 2008, 47, 3430-3734.
33. D. R. Miller, D. C. Swenson, E. G. Gillan, J. Am. Chem. Soc. 2004, 126, 5372-5373.
34. S. Tragl, H.-J. Meyer, Z. Anorg. Allg. Chem. 2005, 631, 2300-2302.
35. J. Liebig, Ann. Pharm 1834, 10, 1-47.
36. E. C. Franklin, J. Am. Chem. Soc. 1922, 44, 486-509.
37. W. Madelung, E. Kern, Justus Liebigs Ann. Chem. 1922, 427, 1-26.
38. Win XPOW, version 2.12, STOE & Cie GmbH, Darmstadt, 2005.
39. Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307-326.
40. G. M. Sheldrick, Acta Crystallogr., Sect. A 2008, 64, 112-122.
41. D. D. Perrin, W. L. F. Armarego in Purification of Laboratory Chemicals, 3rd ed., Pergamon Press, Oxford, 1992, p. 337 (KOCN), p. 346 (NaOCN).
42. Percentage data given for yields is calculated under the assumption that Equations (8) and (9) are applicable. Values are suspect to uncertainty, as this cannot be confirmed at the moment.