Enhanced catalytic activity and unexpected products from the oxidation of cyclohexene by organic nanoparticles of 5,10,15,20-tetrakis-(2,3,4,5,6- pentafluorophenyl)porphyrinatoiron(III) in water by using O2

Chemistry - A European Journal

Volumn 15, Issue 44, 2009, Pages 12133-12140

  Smeureanu, Gabriela ^b   Aggarwal, Amit ^b   Soll, Clifford E ^b   Arijeloye, Julius ^b   Malave, Erik ^b   Drain, Charles Michael ^a,b  

^a ROCKEFELLER UNIVERSITY   (United States)

^b CITY UNIVERSITY OF NEW YORK   (United States)

Author keywords

Alkenes; Catalytic oxidation; Nanoparticles; Oxygen; Porphyrinoids

Indexed keywords

ALKENES; ALLYLIC PRODUCT; AXIAL LIGAND; CATALYTIC TURNOVER; CLOSE PROXIMITY; CYCLOHEXENES; DIOXYGENS; ENHANCED CATALYTIC ACTIVITY; HOST-GUESTS; IRON PORPHYRIN; METALLOPORPHYRINS; ORGANIC NANOPARTICLES; OXIDATIVE DEGRADATION; OXIDATIVE MECHANISM; OXYGEN SOURCES; PENTAFLUOROPHENYL; PORPHYRINOIDS; REACTION CONDITIONS; REACTION SOLVENTS; SOLVENT METHOD; TETRAKIS; TURNOVER NUMBER;

CATALYSIS; CATALYST ACTIVITY; DEGRADATION; NANOPARTICLES; OLEFINS; OXYGEN; PORPHYRINS;

CATALYTIC OXIDATION;

CYCLOHEXENE; CYCLOHEXENE DERIVATIVE; FERRIC ION; ISOTOPE; METALLOPORPHYRIN; NANOPARTICLE; OXYGEN; TETRAKIS(PENTAFLUOROPHENYL)PORPHYRINATO IRON(III) CHLORIDE; WATER;

ARTICLE; CATALYSIS; CHEMISTRY; KINETICS; OXIDATION REDUCTION REACTION;

CATALYSIS; CYCLOHEXENES; FERRIC COMPOUNDS; ISOTOPES; KINETICS; METALLOPORPHYRINS; NANOPARTICLES; OXIDATION-REDUCTION; OXYGEN; WATER;

EID: 72949084909     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200901086     Document Type: Article

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