Preparation of Pt/NiO-C electrocatalyst and heat-treatment effect on its electrocatalytic performance for methanol oxidation

International Journal of Hydrogen Energy

Volumn 35, Issue 1, 2010, Pages 313-320

  Kim, Dong Baek ^a   Chun, Hee Joon ^a   Lee, Yoon Kyung ^a   Kwon, Heock Hoi ^b   Lee, Ho In ^a  

^a Seoul National University   (South Korea)

^b Soongsil University   (South Korea)

Author keywords

Direct methanol fuel cell; Methanol oxidation, Heat treatment; NiO; Pt catalyst

Indexed keywords

4F-ELECTRONS; CARBON SUPPORT; CATALYTIC EFFECTS; ELECTROCATALYTIC PERFORMANCE; ELECTROCHEMICAL ACTIVE SURFACE AREAS; ELECTROCHEMICAL ACTIVITIES; HEAT-TREATMENT EFFECTS; METHANOL OXIDATION; POLYOL METHODS; PT CATALYST; PT CATALYSTS; PT PARTICLE; VULCAN XC72;

AGGLOMERATION; BINDING ENERGY; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTRONIC STRUCTURE; FUEL CELLS; METHANOL; METHANOL FUELS; NICKEL; OXIDATION; OXYGEN; PLATINUM; PLATINUM ALLOYS; TEMPERATURE PROGRAMMED DESORPTION; X RAY PHOTOELECTRON SPECTROSCOPY;

CATALYST SUPPORTS;

EID: 72649094469     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2009.10.037     Document Type: Article

References (29)

1. Hamnett A. Mechanism and electrocatalysis in the direct methanol fuel cell. Catal Today 38 (1997) 445-457
2. McGrath K.M., Surya Prakash G.K., and Olah G.A. Direct methanol fuel cells. J Ind Eng Chem 10 (2004) 1063-1080
3. Wasmus S., and Kuver A. Methanol oxidation and direct methanol fuel cells: a selective review. J Electroanal Chem 461 (1999) 14-31
4. Antolini E., Salgado J.R.C., and Gonzalez E.R. The stability of Pt-M (M = first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells: a literature review and tests on a Pt-Co catalyst. J Power Sources 160 (2006) 957-968
5. Costamagna P., and Srinivasan S. Quantum jumps in the PEMFC science and technology from the 1960s to the year 2000: part II. Engineering, technology development and application aspects. J Power Sources 102 (2001) 253-269
6. Park K.-W., and Sung Y.-E. Design of nanostructured electrocatalysts for direct methanol fuel cells. J Ind Eng Chem 12 (2006) 165-174
7. Choi J.-S., Chung W.S., Ha H.Y., Lim T.-H., Oh I.-H., Hong S.-A., et al. Nano-structured Pt-Cr anode catalyst over carbon support for direct methanol fuel cell. J Power Sources 156 (2006) 466-471
8. Kim C., Kwon H.-H., Song I.K., Sung Y.-E., Chung W.S., and Lee H.-I. Preparation of PtRu nanoparticles on various carbon supports using surfactants and their catalytic activities for methanol electro-oxidation. J Power Sources 171 (2007) 404-411
9. Lim D.-H., Lu L., Kim D.B., Choi D.-H., Park D.-R., and Lee H.-I. Binary-surfactant (Brij 35 + Tween 20) assisted preparation of highly dispersed Pt nanoparticles on carbon. J Nanopart Res 10 (2008) 1215-1220
10. Lim D.-H., Choi D.-H., Lee W.-D., and Lee H.-I. A new synthesis of a highly dispersed and CO tolerant PtSn/C electrocatalyst for low-temperature fuel cell; its electrocatalytic activity and long term durability. Appl Catal B Environ 89 (2009) 484-493
11. Papageorgopoulos D.C., Keijzer M., and de Bruijn F.A. The inclusion of Mo, Nb and Ta in Pt and PtRu carbon supported electrocatalysts in the quest for improved CO tolerant PEMFC anodes. Electrochim Acta 48 (2002) 197-204
12. Zhao J., Chen W., and Zheng Y. Effect of ceria on carbon supported platinum catalysts for methanol electrooxidation. Mater Chem Phys 113 (2009) 591-595
13. Wang Y., Fachini E.R., Cruz G., Zhu Y., Ishikawa Y., Colucci J.A., et al. Effect of surface composition of electrochemically codeposited platinum/molybdenum oxide on methanol oxidation. J Electrochem Soc 148 (2001) C222-C226
14. 2-supported bimetallic catalysts for methanol oxidation in acidic media. Electrochem Commun 8 (2006) 1439-1444
15. 3OH oxidation reaction. J Appl Electrochem 34 (2004) 427-438
16. Min Y.L., Chen Y.C., Zhao Y.G., and Chen C. Simple approach to synthesis Pt/NiO flower microspheres and their electrocatalytic properties. Mater Lett 62 (2008) 4503-4505
17. 2-Pt/CNT catalysts for methanol electro-oxidation. Electrochim Acta 53 (2008) 3708-3713
18. Bönnemann H., Braun G., Brijoux W., Brinkmann R., Schulze Tilling A., Seevogel K., et al. Nanoscale colloidal metals and alloys stabilized by solvents and surfactants preparation and use as catalyst precursors. J Org Chem 520 (1996) 143-162
19. Chan K.-Y., Ding J., Ren J., Cheng S., and Tsang K.Y. Supported mixed metal nanoparticles as electrocatalysts in low temperature fuel cells. J Mater Chem 14 (2004) 505-516
20. Liu Z., Lee J.Y., Han M., Chen W., and Gan L.M. Synthesis and characterization of PtRu/C catalysts from microemulsions and emulsions. J Mater Chem 12 (2002) 2453-2458
21. Zhou Z., Wang S., Zhou W., Jiang L., Wang G., Sun G., et al. Preparation of highly active Pt/C cathode electrocatalysts for DMFCs by an improved aqueous impregnation method. Phys Chem Chem Phys 5 (2003) 5485-5488
22. Guo J., Sun G., Sun S., Yan S., Yang W., Qi J., et al. Polyol-synthesized PtRu/C and PtRu black for direct methanol fuel cells. J Power Sources 168 (2007) 299-306
23. Li X., Qiu X., Yuan H., Chen L., and Zhu W. Size-effect on the activity of anodic catalysts in alcohol and CO electrooxidation. J Power Sources 184 (2008) 353-360
24. Yu W., Tu W., and Liu H. Synthesis of nanoscale platinum colloids by microwave dielectric heating. Langmuir 15 (1999) 6-9
25. Bock C., Paquet C., Couillard M., Botton G.A., and MacDougall B.R. Size-selected synthesis of PtRu nano-catalysts: reaction and size control mechanism. J Am Chem Soc 126 (2004) 8028-8037
26. Pozio A., De Francesco M., Cemmi A., Cardellini F., and Giorgi L. Comparison of high surface Pt/C catalysts by cyclic voltammetry. J Power Sources 105 (2002) 13-19
27. Manoharan R., and Goodenough J.B. Methanol oxidation in acid on ordered NiTi. J Mater Chem 2 (1992) 875-887
28. Park K.-W., Choi J.-H., Kwon B.-K., Lee S.-A., Sung Y.-E., Ha H.-Y., et al. Chemical and electronic effects of Ni in Pt/Ni and Pt/Ru/Ni alloy nanoparticles in methanol electrooxidation. J Phys Chem B 106 (2002) 1869-1877
29. Zhou J.-H., Sui Z.-J., Zhu J., Li P., Chen D., Dai Y.-C., et al. Characterization of surface oxygen complexes on carbon nanofibers by TPD, XPS and FT-IR. Carbon 45 (2007) 785-796