Evaluation of the polymer-solvent interaction parameter χ for the system cured polybutadiene rubber and toluene

Polymer Testing

Volumn 29, Issue 1, 2010, Pages 119-126

  Marzocca, A J ^a   Rodriguez Garraza A L ^a   Mansilla, M A ^a  

^a UNIVERSIDAD DE BUENOS AIRES   (Argentina)

Author keywords

Crosslinking; Flory Huggins interaction parameter; Polybutadiene rubber; Swelling; Toluene

Indexed keywords

CROSS-LINK DENSITIES; DEGREE OF SWELLING; FLORY-HUGGINS INTERACTION PARAMETER; NETWORK STRUCTURES; POLYBUTADIENE RUBBER; POLYBUTADIENE RUBBERS; POLYMER VOLUME FRACTION; POLYMER-SOLVENT INTERACTIONS; ROOM TEMPERATURE; SWELLING BEHAVIOUR; SWELLING MEASUREMENTS; TUBE MODEL; UNIAXIAL STRESS;

CURING; INDUSTRIAL APPLICATIONS; POLYBUTADIENES; RUBBER; RUBBER APPLICATIONS; SOLVENTS; SULFUR; SWELLING; TITRATION; TOLUENE;

ORGANIC SOLVENTS;

EID: 72449166885     PISSN: 01429418     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymertesting.2009.09.013     Document Type: Article

References (40)

1. Kuzma L.J. In: Morton M. (Ed). Rubber Technology (1987), Van Nostrand Reinhold, New York 235
2. Flory P.J., and Rehner J. Statistical mechanics of cross-linked polymer networks I. Rubberlike elasticity. J. Chem. Phys. 11 (1943) 512
3. Flory P.J., and Rehner J. Statistical mechanics of cross-linked polymer networks II. Swelling. J. Chem. Phys. 11 (1943) 521
4. Bahar I., Erbil H.Y., Baysal B.M., and Erman B. Determination of polymer-solvent interaction parameter from swelling of networks. The system poly(2-hydroxyethyl methacrylate)-diethylene glycol. Macromolecules 20 (1987) 1353
5. Bahar I., and Erman B. Osmotic compressibility and mechanical moduli of swollen polymeric networks. Macromolecules 20 (1987) 1696
6. Horta A., and Pastoriza M.A. The interaction parameter of crosslinked networks and star polymers. Eur. Polym. J. 41 (2005) 2793
7. McKenna G.B., Flynn K.M., and Chen Y. Mechanical and swelling of crosslinked natural rubber: consequences of the Flory-Rehner hypothesis. Polym. Commun. 29 (1988) 272
8. Mc.Kenna G.B., Flynn K.M., and Chen Y. Swelling in crosslinked natural rubber: experimental evidence of the crosslink density dependence of χ. Polymer 31 (1990) 1937
9. Hergenrother W.L., and Hilton A.S. Use of χ as a function of volume fraction of rubber to determine crosslink density by swelling. Rubber Chem. Technol. 76 (2003) 832
10. Marzocca A.J. Evaluation of the polymer-solvent interaction parameter χ for the system cured styrene butadiene rubber and toluene. Eur. Polym. J. 43 (2007) 2682
11. Hergenrother W.L. Characterization of networks from the peroxide cure of polybutadiene. J. Appl. Polym. Sci. 16 (1972) 2611
12. 129Xe chemical shift. Macromolecules 40 (2007) 5787
13. Guo F., Andreasen J.W., Vigild M.E., and Ndoni S. Influence of 1,2-PB matrix cross-linking on structure and properties of selectively etched 1,2-PB- b-PDMS block copolymers. Macromolecules 40 (2007) 3669
14. Saeki S., Holste J.C., and Bonner D.C. Vapor-liquid equilibria for polybutadiene and polyisoprene solutions. J. Polym. Sci. Polym. Phys. 20 (1982) 793
15. Brotzman R.W., and Flory P.J. Elastic behavior of cis-1,4-polybutadiene. Macromolecules 20 (1987) 351
16. Jessup R.S. Thermodynamic properties of the systems polybutadiene - benzene and polyisobutene - benzene. J. Res. Natl. Bur. Stand. 60 (1958) 47
17. Gregg E.C., and Katrenick S.E. Chemical structure in cis-1,4-polybutadiene vulcanizates. Model compound approach. Rubber Chem. Technol. 43 (1970) 549
18. Krauss G. Quantitative characterization of polybutadiene networks. J. Appl. Polym. Sci. 7 (1963) 1257
19. Short J.N., Thornton V., and Krauss G. Effect of the cis-trans ratio on the physical properties of 1,4 polybutadienes. Rubber Chem. Technol. 30 (1957) 1118
20. Gavrilov V.M., and Shvarts A.G. Dependence of the polymer-solvent interaction parameter of vulcanizates based on cis-1,4-poly(butadiene) on the type and concentration of vulcanizing agent. Rubber Chem. Technol. 47 (1974) 303
21. Heinrich G., Straube E., and Helmis G. Rubber elasticity of polymer networks: theories. Adv. Polym. Sci. 85 (1988) 33
22. Matzen D., and Straube E. Mechanical properties of SBR-networks: I. Determination of crosslink densities by stress-strain measurements. Colloid Polym. Sci. 270 (1992) 1
23. Heinrich G., and Vilgis T.A. Contribution of entanglements to the mechanical properties of carbon black filled polymer networks. Macromolecules 26 (1993) 1109
24. Marzocca A.J. Estimation by mechanical analysis of the molecular parameters of SBR vulcanizates at different cure conditions. J. Appl. Polym. Sci. 58 (1995) 1839
25. Marzocca A.J., Cerveny S., and Raimondo R.B. Analysis of variation of molecular parameters of NR during vulcanization in the frame of conformational tube model. J. Appl. Polym. Sci. 66 (1997) 1085
26. Cerveny S., and Marzocca A.J. Analysis of variation of molecular parameters of natural rubber during vulcanization in conformational tube model. II influence of sulfur/accelerator ratio. J. Appl. Polym. Sci. 74 (1999) 2747
27. Marzocca A.J., Cerveny S., and Mendez J.M. Some considerations concerning the dynamic mechanical properties of cured styrene-butadiene rubber/polybutadiene blends. Polym. Int. 49 (2000) 216
28. Marzocca A.J., and Goyanes S. An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress-strain behavior of SBR. J. Appl. Polym. Sci. 91 (2004) 2601
29. Kaliske M., and Heinrich G. An extended tube-model for rubber elasticity: statistical-mechanical theory and finite element implementation. Rubber Chem. Technol. 72 (1999) 602
30. Wu S.J. Chain structure and entanglement. J. Polym. Sci. B Polym. Phys. 27 (1989) 723
31. Ferry J.D. Viscoelastic Properties of Polymers (1980), John Wiley & Sons, New York p. 267
32. Valentine R.H., Ferry J.D., Homma T., and Ninomiya K. Viscoelastic properties of polybutadienes - linear and lightly crosslinked near the gel point. J. Polym. Sci. Part-2: Polym. Phys. 6 (1968) 479
33. Aharoni S.M. Correlations between chaín parameters and the plateau modulus of polymers. Macromolecules 19 (1986) 426
34. Seber G.A.F., and Wild C.J. Nonlinear Regression (2003), John Wiley & Sons Inc, Hoboken, NJ
35. In: Lide D.R. (Ed). CRC Handbook of Chemistry and Physics (1997), CRC Press, New York 3-55
36. Scott R.L., and Magat M. The thermodynamics of high-polymer solutions: I. The free energy of mixing of solvents and polymers of heterogeneous distribution. J. Chem. Phys. 13 (1945) 172
37. In: Brandrup J., and Immergut R.H. (Eds). Polymer Handbook. second ed (1975), J. Wiley & Sons, New York IV-341-IV-354
38. Small P.A. Some factors affecting the solubility of polymers. J. Appl. Chem. 3 (1953) 71
39. Sheehan C.J., and Bisio L. Polymer/solvent interaction parameters. Rubber Chem. Technol. 39 (1966) 149
40. Queslel J.P., and Mark J.E. Structure of randomly cross-linked networks. A theoretical relationship between the molecular weight between crosslinks and the cycle rank, and its comparison with experiment. J. Chem. Phys. 82 (1985) 3449-3452