Proton charge and adsorption of humic acid and phosphate on goethite

Soil Science Society of America Journal

Volumn 73, Issue 6, 2009, Pages 2013-2020

  Shuai, Xiufu ^a,b   Zinati, Gladis ^a  

^a RUTGERS UNIVERSITY   (United States)

^b UNIVERSITY OF HAWAII   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRICAL DOUBLE LAYERS; ELECTROSTATIC INTERACTIONS; HIGH PH; HUMIC ACID; INITIAL CONCENTRATION; POINT OF ZERO CHARGE; POTENTIOMETRIC TITRATION METHODS; SMALL REDUCTION; TERNARY MIXTURES;

ADSORPTION; BINARY MIXTURES; ELECTRIC PROPERTIES; HYDROXYLATION; IONIC STRENGTH; LOADING; ORGANIC ACIDS; PROTONS; TITRATION;

BIOLOGICAL MATERIALS;

ADSORPTION; GOETHITE; HUMIC ACID; PH; PHOSPHATE;

EID: 72449151248     PISSN: 03615995     EISSN: None     Source Type: Journal    
DOI: 10.2136/sssaj2009.0119     Document Type: Article

References (41)

1. Antelo, J., M. Avena, S. Fiol, R. López, and F. Arce. 2005. Effects of pH and ionic strength on the adsorption of phosphare and arsenate at the goethite-water interface. J. Colloid Interface Sci. 285:476-486. (Pubitemid 40544665)
2. Antelo, J., F. Arce, M. Avena, S. Fiol, R. López, and F. Maclas. 2007. Adsorption of a soil humic acid at the surface of goethite and its competitive interaction with phosphate. Geoderma 138:12-19. (Pubitemid 46227396)
3. Avena, MJ, and L.K. Koopal. 1998. Desorption of humic acids from an iron oxide surface. Environ. ScL TechnoL 32:2572-2577. (Pubitemid 28420285)
4. Bowden, J.W., S. Nagarajah, NJ. Barrow, A.M. Posner, and J.P. Quirk. 1980a. Describing the adsorption of phosphate, citrate and selenite on a variable-charge mineral surface. Aust J. Soil Res. 18:49-60.
5. Bowden, J.W, A.M. Posner, and J.P. Quirk. 1980b. Adsorption and charging phenomena in variable charge soils, p. 147-165. In B.K.G Theng (ed.) Soils with variable charge. Soil Bureau, Department of Scientific and Industrial Research, Lower Hurt, New Zealand.
6. Davies, C.W. 1962. Ion association. Butterworths, London.
7. Davis, J.A., R.O. James, and J.O. Leckie. 1978. Surface ionization and complexation at the oxide/water interface. I. Computation of electrical double layer properties in simple electrolytes. J. Colloid Interface Sci. 63:480-499.
8. Dzombak, D.A., and F.M.M. Morel. 1990. Surface complexation modeling: hydrous ferric oxide. John Wiley & Sons, New York.
9. Geelhoed, J.S., T. Hiemstra, and W.H. van Riemsdijk. 1998. Competitive interaction between phosphate and citrate on goethite. Environ. Sci. TechnoL 32:2119-2123.
10. Goldberg, S., and G. Sposito. 1985. On the mechanism of specific phosphate adsorption by hydroxylated mineral surfaces: A review. Commun. Soil Sci. Plant Anal. 16:801-821.
11. Gu, B., J. Schmitt, Z. Chen, L Liang, and J.F. McCarthy. 1994. Adsorption and desorption of natural organic matter on iron oxide: Mechanisms and models. Environ. Sci. Technol. 28:38-46.
12. Hayes, K.F., G. Redden, W. Ela, and J.O. Leckie. 1991. Surface complexation models: An evaluation of model parameter estimation using FITEQL and oxide mineral titration data. J. Colloid Interface Sci. 142:448-469.
13. Hiemstra, T., and W.H. van Riemsdijk. 1996. A surface structural approach to ion adsotption: The charge distribution (CD) model. J. Colloid Interface Sci. 179:488-508. (Pubitemid 26188477)
14. Hiemstra, T., W.H. Van Riemsdijk, and G.H. Bolt 1989. Multisite proton adsotption modeling at the solid/solution interface of (hydr)oxides: A new approach: I. Model description and evaluation of intrinsic reaction constants. J. Colloid Interface Sci. 133:91-104.
15. 3-J. Colloid Interface Sci. 55:281-288.
16. 3. J. Colloid Interface Sci. 22:231-259.
17. Joo, J.C., C.D. Shackelford, and K.F. Reardon. 2008. Association of humic acid with metal (hydr)oxide-coated sands at solid-water inrerfaces. J. Colloid Interface Sci. 317:424-433.
18. Kinniburgh, D.G., W.H. van Riemsdijk, LK. Koopal, M. Borkovec, M.F. Benedetti, and M.J. Avena. 1999. Ion binding to natural organic mattet: Competition, heterogeneity, stoichiometry and thermodynamic consistency. Colloids Surf. A Physicochem. Eng. Asp. 151:147-166.
19. Klapper, H. 1991. Control of eutrophication in inland waters. Ellis Horwood, Chichester.
20. Koretsky, C. 2000. The significance of surface complexation reactions in hydrologic systems: A geochemist's perspective. J. Hydrol. 230:127-171.
21. Li, W., S. Zhang, and X.Q. Shan. 2007. Surface modification of goethite by phosphate for enhancement of Cu and Cd adsorption. Colloids Surf. A Physicochem. Eng. Asp. 293:13-19.
22. Lindsay, W.L. 1979. Chemical equilibria in soils. John Wiley & Sons, New York.
23. Manning, B.A., and S. Goldberg. 1996. Modeling competitive adsorption of arsenate with phosphate and molybdate on oxide minerals. Soil Sci. Soc. Am. J. 60:121-131.
24. Milne, C.J., D.G. Kinniburgh, and E. Tipping. 2001. Generic NICA-Donnan model parameters for proton binding by humic substances. Environ. Sci. Technol. 35:2049-2059.
25. Milne, C.J., D.G. Kinniburgh, J.C.M. Dewit, W.H. Vanriemsdijk, and L.K. Koopal. 1995. Analysis of proton binding by a peat humic-acid using a simple electrostatic model. Geochim. Cosmochim. Acta 59:1101-1112.
26. Murphy, J., and J.P. Riley. 1962. A modified single solution method for the determination of phosphate in natural waters. Anal. Chim. Acta 27:31-36.
27. Parker, J.C., L.W. Zelazny. S. Sampath, and W.G. Harris. 1979. A critical evaluation of the extension of zero point of charge (ZPC) theory to soil systems. Soil Sci. Soc. Am. J. 43:668-674.
28. Rahnemaie, R., T. Hiemstta, and W.H. van Riemsdijk. 2007. Geometty, charge distribution, and surface speciation of phosphate on goethite. Langmuir 23:3680-3689. (Pubitemid 46581893)
29. Saito, T., L.K. Koopal, W.H. van Riemsdijk, S. Nagasaki, and S. Tanaka. 2004. Adsorption of humic acid on goethite: Isotherms, charge adjustments, and potential profiles. Langmuir 20:689-700.
30. Santos, E.B.H, V.I. Esteves, J.P.C. Rodrigues, and A.C. Duarte. 1999. Humic substances' proton-binding equilibria: Assessment of errors and limitations of Potentiometric data. Anal. Chim. Acta 392:333-341.
31. Sibanda, H.M, and S.D. Young. 1986. Competitive adsotption of humus acids and phosphate on goethite, gibbsite and two tropical soils. Eur. J. Soil Sci. 37:197-204.
32. Sposito, G. 1981. The operational definition of the zero point of charge in soils. Soil Sci. Soc. Am. J. 45:292-297.
33. Stevenson, F.J. 1994. Humus chemistry: Genesis, composition, reactions. 2nd ed. John Wiley & Sons, New York.
34. Stumm, W., C.P. Huang, and S.R. Jenkins. 1970. Specific chemical interactions affecting the stability of dispersed systems. Croat Chem. Acta 42:223-244.
35. Tipping, E. 1998. Humic ion-binding model VI: An improved description of the interactions of protons and metal ions with humic substances. Aquat. Geochem. 4:3-48.
36. Uehara, G., and G.P. Gillman. 1981. The mineralogy, chemistry, and physics of tropical soils with variable charge clays. Westview Press, Boulder, CO.
37. Venema, P., T. Hiemstra, and W.H. van Riemsdijk. 1996. Multisite adsorption of cadmium on goethite. J. Colloid Interface Sci. 183:515-527.
38. Weng, L., W.H. van Riemsdijk, and T. Hiemstta. 2007. Adsorption of humic acids onto goethite: Effects of molar mass, pH and ionic strength. J. Colloid Interface Sci. 314:107-118. (Pubitemid 47187431)
39. Weng, L., W.H. van Riemsdijk, and T. Hiemstra. 2008. Humic nanoparticles at the oxide-water interface: Interactions with phosphate ion adsorption. Environ. Sci. Technol. 42:8747-8752.
40. Weng, L., W.H. van Riemsdijk, L.K. Koopal, and T. Hiemstra. 2006. Adsorption of humic substances on goethite: Comparison between humic acids and fulvic acids. Environ. Sci. Technol. 40:7494-7500.
41. Yates, D.E., S. Levine, and T.W. Healy. 1974. Site-binding model of the electrical double layer at the oxide/water interface. J. Chem. Soc. Faraday Trans. 1. 70:1807-1818.