Solvent extraction of zirconium(IV) from acidic chloride solutions using the thiosubstituted organophosphorus acids Cyanex 301 and 302

Journal of Chemical Technology and Biotechnology

Volumn 79, Issue 11, 2004, Pages 1301-1307

  Reddy, B Ramachandra ^a   Kumar, J Rajesh ^a,b   Reddy, A Varada ^b  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

^b SRI VENKATESWARA UNIVERSITY   (India)

Author keywords

Associated metals; Cyanex 301; Cyanex 302; HCl; Zirconium

Indexed keywords

ION EXCHANGE; ORGANIC ACIDS; STRIPPING (REMOVAL); ZIRCONIUM;

METAL COMPLEXES; METAL TRANSFER; MIXED EXTRACTANTS;

SOLVENT EXTRACTION;

CHLORIDE; METAL DERIVATIVE; ORGANOPHOSPHORUS COMPOUND; PROTON; ZIRCONIUM DERIVATIVE;

EXTRACTION PROCESS;

ACIDITY; ANALYTIC METHOD; AQUEOUS SOLUTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL PROCEDURES; COLORIMETRY; COMPLEX FORMATION; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; EXTRACTION; STATISTICAL ANALYSIS; STATISTICAL SIGNIFICANCE; TEMPERATURE DEPENDENCE;

SIGANUS;

EID: 7244258810     PISSN: 02682575     EISSN: None     Source Type: Journal    
DOI: 10.1002/jctb.1129     Document Type: Article

References (27)

1. Agrawal YK and Sudhakar S, Extraction, separation and preconcentration of zirconium. Sep and Puri Tech 27:111-119 (2002).
2. Sole KC and Hiskey BJ, Solvent extraction of copper by Cyanex 272 , Cyanex 302 and Cyanex 301. Hydrometallurgy 37:129-147 (1995).
3. Pearson RG, Hard and soft acids and bases. J Am Chem Soc 85:3533-3539 (1963).
4. Cytec Industries Inc, Cyanex 301 and Cyanex 302 Technical Brochures. West Paterson, New Jersey (1996).
5. Algucil FJ, Cobo A and Caravaca C, Study of the extraction of zinc (II) in aqueous chloride media by Cyanex 302. Hydrometallurgy 31:163-174 (1992).
6. Facon S, Cote G and Bauer D, Solvent extraction of antimony(III), bismuth(III), lead(II) and tin(IV) with bis(2,4,4-trimethylpentyl)-phosphinodithionic acid (Cyanex 301). Solvent Extr Ion Exch 9:717-734 (1991).
7. Avil Rodriguez M, Cote G and Bauer D, Recovery of indium(III) from mixed hydrochloric acid - sulfuric acid media by solvent extraction with Cyanex 301. Solvent Extr Ion Exch 10:811-827 (1992).
8. Levitt AE and Freund H, Solvent extraction of zirconium with tributylphosphate. J Am Chem Soc 78:1545-1549 (1956).
9. Alcock K, Bedford FC, Hardwick WH and McKay HAC, Tri-n butylphosphate as an extracting solvent for inorganic nitrates-I. J Inorg Nucl Chem 4:100-105 (1957).
10. Siekierski S, Extraction from solutions of perchloric acid by tributylphosphate - I. J Inorg Nucl Chem 12:129-135 (1959).
11. Egorov GF, Fomin VV, Frolov YuG and Yagodin GA, Solvates of zirconium and hafnium nitrates with tributylphosphate (TBP). Zh Neorg Khim 5:1044-1050 (1960).
12. Korovin SS, Lebedeva EN, Renzik AM, Komissarova LN and Kuznetsova GP, Extraction of zirconium and hafnium with tributylphosphate. Khim I Khim Tekhnol 5:231-235 (1962).
13. Golub AM and Sergunkin VN, Extraction of zirconium and hafnium thiocynate complexes with cyclohexane and tributylphosphate. Zh Prikil Khim 43:1203-1209 (1970).
14. Umezawa H and Hara R, Studies on the extraction of zirconium with organophosphorus compounds. Anal Chim Acta 25:360-365 (1961).
15. Tedesco PH, De Rumi VB and Gonzalez Quintana JA, Extraction of tetravalent metals with di-(2-ethylhexyl) phosphoric acid - II. J Inorg Nucl Chem 29:1307-1375 (1967).
16. Korovin SS, Reznik AM, Lebedeva EN and Apraksin IA, Reaction of zirconium and hafnium with neutral organophosphorus extracting agents, in Org Reagenty Anal Khim Tsirkoniya, ed by Ermakov AN. Izd. Nauka, Moscow, pp 63-103 (1970).
17. Yagodin GA and Tarasov VV, Rate of zirconium extraction from nitrate media by bis(2-ethylhexyl)phosphate. Radiokhimiya 12 664-666 (1970).
18. Biswas RK and Hayat MA, Solvent extraction of zirconium (IV) from chloride media by D2EHPA in kerosene. Hydrometallurgy 63 149-158 (2002).
19. Mishra PK, Chakravortty V. Dash KC, Das NR and Bhattacharyya SN, The extraction of Zr(IV) from HCl by mixture of Aliquat 336 and Alamine 336 with TBP. J Radioanal Nucl Chem 134:259-264 (1989).
20. Mcisaac DL and Baker JD, Extraction of zirconium from nitric acid by dihexyl-N,N-diethyl carbamoyl methyl phosphonate. Solv Extr Ion Exch 1:27-41 (1983).
21. Sun J, Wang C, Li D and Ye D, Extraction separation of Zr(IV) from Th(IV), Ti(IV), Fe(III) with isopropylphosphonic acid mono-(1-hexyl-4-ethyl)-octyl ester and its mechanism. Fenxi Huaxue 23:998-1002 (1995).
22. Brewer KN, Herbst RS, Todd TA and Christian JD, Zirconium extraction into octyl (phenyl)-N-N diisobutylcarbomylmethyl-phosphine oxide and tributyl phosphate. Solv Extr Ion Exch 119:1047-1066 (1998).
23. Marczenko Z, Spectrophotometric Determination of Elements John Wiley & Sons, New York, pp 555, 609 (1976).
24. Mohanty SR and Reddy AS, Solvent extraction of uranium from hydrochloric acid solutions by sulphoxides and their mixtures. J Inorg Nucl Chem 37:1791-1795 (1975).
25. Cote G, Martin JV, Bauer D and Mottot Y, Physico-chemical properties of Cyanex 301, in Proceedings of the International Solvent Extraction Conference, ISEC 2002, South Africa Vol 1 p 291-298 (2002 ).
26. Jensen MP and Bond AH, Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301 and Cyanex 302. Radiochim Acta 80 205-209 (2002)
27. Menoyo B, Elizalde MP and Almela A, Determination of the degradation compounds formed by the oxidation of thiophosphinic acids and phosphine sulfides with nitric acid. Analytical Sciences 18 799-804 (2002).