Liberation of pnicogen chains from Cu2P1.8As 1.2I2: Synthesis and characterization of a new allotrope of P-As

Inorganic Chemistry

Volumn 43, Issue 22, 2004, Pages 6902-6904

  Jayasekera, Buddhimathie ^a   Somaskandan, Kanchana ^a   Brock, Stephanie L ^a  

^a WAYNE STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PHOSPHORUS; POLYMER;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; OPTICS; SCANNING ELECTRON MICROSCOPY; SYNTHESIS; TRANSMISSION ELECTRON MICROSCOPY;

EID: 7244257612     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0490223     Document Type: Article

References (19)

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3. Up to 5% As can be incorporated into Hittorf's phosphorus: Hönle, W.; von Schnering, H. G. Chem. Rev. 1988, 88, 242-269.
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9. Jayasekera, B.; Brock, S. L.; Lo, A. Y. H.; Schurko, R. W.; Nazri, G. A. Chem. Eur. J., submitted.
10. Jayasekera, B.; Brock, S. L. Mater. Res. Soc. Symp. Proc. 2003, 755, DD6.12.1-6.12.6.
11. SEM/EDS data were acquired on a Hitachi S-2400 scanning electron microscope with an associated EDAX unit. Samples were placed on adhesive carbon tabs on A1 stubs for the measurement.
12. X-ray powder diffraction was conducted using a Rigaku D-Max RU 200B with rotating anode operating at 40 kV, 100 mA (Cu Kα). Samples were dusted onto double sticky tape.
13. 4 as a 100% reflectance sample. The reflectance data were converted to absorption data for optical band gap determination.131b
14. (b) Wendlandt, W. W.; Hecht, H. G. Reflectance Spectroscopy; Interscience Publishers: New York, 1966.
15. 2 or 1 was ultrasonically dispersed in acetone and deposited onto copper grids coated with amorphous carbon.
16. Viculis, L. M.; Mack, J. J.; Kaner, R. B. Science 2003, 299, 1361-1361.
17. Grandmann, M., Appl. Phys. Lett. 2003, 83, 2444-2446.
18. P/As measured, 55/45; calculated, 60/40 (value ± 10%, ICP-MS, RTI labs, Livonia, MI). C, H, N each <1% of the sample by mass (combustion analysis, Prevalere, Whitesboro, NY).
19. Pfitzner, A.; Bräu, M. F.; Zweck, J.; Branklaus, G.; Eckert, H. Angew. Chem. 2004, 43, 4228-4231.