Systematic reduction of complex tropospheric chemical mechanisms, part II: Lumping using a time-scale based approach

Atmospheric Chemistry and Physics

Volumn 4, Issue 7, 2004, Pages 2057-2081

  Whitehouse, L E ^a   Tomlin, A S ^a   Pilling, M J ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 7244247145     PISSN: 16807316     EISSN: None     Source Type: Journal    
DOI: 10.5194/acp-4-2057-2004     Document Type: Article

References (18)

1. Campbell, S. L. and Meyer, C. D.: Generalized Inverses of Linear Transformations, Pitman, London, 1979.
2. Fish, D. J.: The automatic generation of reduced mechanisms for tropospheric chemistry modelling, Atm. Env., 34, 1563-1574, 2000.
3. Gery, M. W., Whitten, G. Z.and Killus, J. P., and Dodge, M. C.: A photochemical kinetics mechanism for urban and regional scale computer modelling, J. Geophys. Res., 94 D10, 12 925-12 956, 1989.
4. Hough, A. M.: An intercomparison of mechanisms for the production of photochemical oxidants, J. Geophys. Res., 93, 3789-3812, 1988.
5. Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric degradation of volatile organic compounds :A protocol for mechanism development, Atm. Env., 31, 81-104, 1997.
6. Jenkin, M. E., Saunders, S. M., Derwent, R. G., and Pilling, M. J.: Development of a reduced speciated VOC degradation mechanism for use in ozone models, Atm. Env., 36, 4725-4734, 2002.
7. Leone, J. A. and Seinfeld, J. H.: Comparative analysis of chemical reaction mechanisms for photochemical smog, Atm. Env., 10, 437-464, 1985.
8. Li, G. and Rabitz, H.: A general analysis of exact lumping in chemical kinetics, Chem. Eng. Sci., 14, 1413-1430, 1989.
9. Li, G. and Rabitz, H.: A general analysis of approximate lumping in chemical kinetics, Chem. Eng. Sci., 45, 977-1002, 1990.
10. Makar, P. A. and Polavarapu, S. M.: Analytic solutions for gas-phase chemical mechanism compression, Atm. Env., 31, 1025-1039, 1997.
11. Makar, P. A., Stockwell, W. R., and Li, S. M.: Gas-phase mechanism compression strategies: treatment of reactions, Atm. Env., 30, 831-842, 1996.
12. Middleton, P., Stockwell, W. R., and Carter, W. P. L.: Aggregation of volatile organic compound emissions for regional modelling, Atm. Env., 6, 1107-1133, 1990.
13. Pilling, M. J., Saunders, S., Carslaw, N., Pascoe, S., Jenkin, M., and Derwent, D.: Master Chemical Mechanism, http://www.chem. leeds.ac.uk/Atmospheric/MCM/mcmproj.html, 1999.
14. Stockwell, W. R., Middleton, P., Chang, J. S., and Tang, X. Y.: The second generation regional acid deposition model mechanism for regional air-quality modelling, J. Geophys. Res., 95, 16 343-16 367, 1990.
15. Tomlin, A. S., Turányi, T., and Pilling, M. J.: Autoignition and low temperature combustion of hydrocarbons, chap. Mathematical tools for construction, investigation and reduction of combustion mechanisms, Elesvier, Amsterdam., 1998.
16. Wang, S. W., Georgopoulos, P. G., Li, G., and Rabitz, H.: Condensing complex atmospheric chemistry mechanisms - I. The direct constrained approximate lumping (DCAL) method applied to alkane photochemistry, Env. Sci. Tech., 32, 2018-2024, 1998.
17. Wei, J. and Kuo, J. C.: A lumping analysis in monomolecular reaction systems, Ind. Eng. Chem. Fundam., 8, 114-133, 1969.
18. Whitehouse, L. E., Tomlin, A. S., and Pilling, M. J.: Systematic reduction of complex tropospheric chemical mechanisms, Part I: sensitivity and time-scale analyses, Atmos. Chem. Phys., 4, 2025-2056, 2004, SRef-DI: 1680-7324/acp/2004-4-2025.