Heterogeneous cobalt-saponite catalyst for liquid phase air oxidation of p-Cresol

Industrial and Engineering Chemistry Research

Volumn 48, Issue 21, 2009, Pages 9426-9427

  Kshirsagar, Vikas S ^a   Garade, Ajit C ^a   Patil, Kashinath R ^b   Jha, Ratnesh K ^c   Rode, Chandrashekhar V ^a  

^a Chemical Engineering and Process Development Division   (India)

^b Centre for Materials Characterization Division   (India)

^c NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AIR OXIDATION; CO LOADING; DIVALENT COBALT IONS; EFFICIENT CATALYSTS; FIRST-ORDER DEPENDENCE; INERT ATMOSPHERES; LATTICE OXYGEN; LIQUID PHASE; LIQUID-PHASE OXIDATION; MARS-VAN KREVELEN; P-CRESOL; PARTIAL PRESSURE OF OXYGEN; RATE OF REACTION; REACTION PARAMETERS; XPS;

CATALYSIS; CATALYSTS; CLAY MINERALS; COBALT; LIQUIDS; OXIDATION; OXYGEN; PRESSURE EFFECTS;

SOLUTIONS;

EID: 72349100445     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie801941e     Document Type: Article

References (27)

1. Akhmedov, V. M.; Al-khowaiter, S. H. Recent advances and future aspects in the low-temperature conversion of saturated hydrocarbon. Catal. Rev. Sci. Eng. 2002, 44, 455-498.
2. Labinger, J. A.; Bercaw, E. Understanding and exploiting C-H bond activation. Nature (London) 2002, 417, 507-514.
3. Punniyamurthy, T.; Velusamy, S.; Iqbal, J. Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen. Chem. Rev. 2005, 105, 2329-2363.
4. Sheldon, R. A. I. Catalytic Oxidation: Principles and Applications; Sheldon R. A.; van Santen, R. A., Eds.; World Scientific: Singapore, 1995; p 177.
5. Makwana, V. D.; Son, Y. C.; Howell, A. R.; Suib, S. L. The role of lattice oxygen in selective benzyl alcohol oxidation using OMS-2 catalyst: A kinetic and isotope-labeling study. J. Catal. 2002, 210, 46-52.
6. Sittig, M. Chemical Technology Review: Pharmaceutical Manufacturing Encyclopedia; Noyes Data Corporation: NJ, 1997. Vol. 124, pp 626-28.
7. Clonts, K. E.; McKetta, R. A. Cresols and Cresylic Acids. Kirk- Othmer Encyclopedia of Chemical Technology; 3rd ed.; Wiley-InterScience: New York, 1978; vol. 3, pp 212-225.
8. Burdock, G. A. Encyclopedia of Food and Colour Additives; CRC Press: New York, 1997; Vol. 3, pp 371-376; 2891-2904.
9. Torii, S.; Tanaka, H.; Siroi, T.; Akada, M. Regiospecific electroacetoxylation of 4-methylphenyl acetate to form 4-acetoxybenzyl acetate: A significant procedure for vanillin synthesis involving novel etherification methods of aryl bromides. J. Org. Chem. 1979, 44, 3305-3310.
10. Rode, C. V.; Sonar, M. V.; Nadgeri, J. M.; Chaudhari, R. V. Selective synthesis of p-hydroxybenzaldehyde by liquid-phase catalytic oxidation of p-cresol. Org. Proc. Res. Dev. 2004, 8, 873-878.
11. Rode, C. V.; Kshirsagar, V. S.; Nadgeri, J. M.; Patil, K. R. Cobaltsalen intercalated Montmorrilonite catalyst for air oxidation of p-cresol under mild conditions. Ind. Eng. Chem. Res. 2007, 46, 8413-8419.
12. 4 Catalyst with tunable selectivity for liquid phase air oxidation of p-cresol. Chem. Lett. 2008, 37, 310-311.
13. Wang, F.; Yang, G.; Zhang, W.; Wu, W.; Xu, J. Copper and manganese: Two concordant partners in the catalytic oxidation of p-cresol to p-hydroxybenzaldehyde. Chem. Commun. 2003, 1172-1173.
14. Mitchell, Kirk-Othmer Encyclopedia of Chemical Technology, 4th ed.; Wiley-InterScience: New York, 1998; Vol. 13, pp 1030-1042.
15. Yumin, L.; Shetian, L.; Kaizheng, Z.; Xingkai, Y.; Yue, W. Catalysis of hydrotalcite-like compounds in liquid phase oxidation: (II) Oxidation of p-cresol to p-hydroxybenzaldehyde. Appl. Catal. A 1998, 169, 127-135.
16. Kshirsagar, V. S.; Garade, A. C.; Patil, K. R.; Shirai, M.; Rode, C. V. Liquid phase oxidation of p-cresol over cobalt saponite. Top. Catal. DOI: 10.1007/s11244-009-9199-z.
17. Pinnavaia, T. J. Intercalated clay catalysts. Science 1983, 220, 365- 378.
18. Kshirsagar, V. S.; Nadgeri, J. M.; Tayade, P. R.; Rode, C. V. Reaction kinetics of liquid phase air oxidation of p-cresol to p-hydroxybenzaldehyde. Appl. Catal. A 2008, 339, 28-35.
19. Kawai, S.; Yao, Y. Z. Saponite catalysts with systematically varied mg/ni ratio: synthesis, characetrization and catalysis. Microporous Mesoporous Mater. 1999, 33, 49-59.
20. Weckhuysen, B. M.; Verberckmoes, A. A.; Uytterhoeven, M. G.; Mabbs, F. E.; Collison, D.; De Boer, E.; Schoonheydt, R. A. Electron spin resonance of high-spin cobalt in microporous crystalline cobalt-containing aluminophosphates. J.Phys. Chem. B 2000, 104, 37-42.
21. Jamas, J.; Machej, T.; Gurgul, J.; Socha, R. P.; Che, M.; Dzwigaj, S. Effect of Co content on the catalytic activity of CoSiBEA zeolite in the selective catalytic reduction of NO with ethanol: Nature of the cobalt species. Appl. Catal. B 2007, 75, 239-248.
22. Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pioretti, R. A.; Rouquerol, J.; Siemieniewska, T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl. Chem. 1985, 57, 603-619.
23. Barton, T. J.; Bull, L. M.; Klemperer, W. G.; Loy, D. A.; McEnaney, B.; Misono, M.; Monson, P. A.; Pez, G.; Scherer, G. W.; Vartuli, J. C.; Yaghi, O. M. Tailored porous materials. Chem. Mater. 1999, 2633-2656.
24. Moulder, J. F.; Syicle, W. F.; Sobol, P. E.; Bomben, K. D. I. Handbook of X-Ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data; Chastain, J., Ed.; Perkin-Elmer: Eden Prairie, MN, 1992; p 82.
25. 2O decomposition. Appl. Catal. B 1998, 18, 223- 231.
26. Fierro, G.; Eberhardt, M. A.; Houalla, M.; Hercules, D. M.; Hall, W. K. Redox chemistry of CoZSM-5 zeolite. J. Phys. Chem. 1996, 100, 8468-8477.
27. Doornkamp, C.; Ponec, V. The universal character of Mars and van Krevelen Mechanism. J. Mol. Catal. A 2000, 162, 19-32.