A new multi-cobalt-substituted C-shaped polyoxotungstogermanate, [((CoOH2)Co2GeW9O34)2(GeW6O26)]20-

Inorganic Chemistry Communications

Volumn 13, Issue 1, 2010, Pages 98-100

  Ruizhan, Tong ^a   Chen, Lili ^a   Liu, Ying ^a   Liu, Bin ^a   Xue, Ganglin ^a   Hu, Huaiming ^a   Fu, Feng ^b   Wang, Jiwu ^b  

^a BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

^b YAN'AN UNIVERSITY   (China)

Author keywords

Cobalt; Germanium; Polyoxometalates; Sandwich type; Structure elucidation

Indexed keywords

EID: 72249122980     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.10.027     Document Type: Article

References (44)

1. Pope M.T. Heteropoly and Isopoly Oxometalates (1983), Springer-Verlag, Berlin
2. Pope M.T., and Müller A. Angew. Chem., Int. Ed. Engl. 30 (1991) 34
3. In: Pope M.T., and Müller A. (Eds). Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (1994), Kluwer Academic Publishers, Dordrecht, The Netherlands
4. Hill C.L. Polyoxometalates. Chem. Rev (1998), American Chemical Society, Washington, DC
5. Pope M.T., and Müller A. Polyoxometalate Chemistry: From Topology Via Self-Assembly to Applications (2001), Kluwer, Dordrecht, The Netherlands
6. In: Pope M.T. (Ed). Polyoxometalate Chemistry for Nano-Composite Design (2002), Kluwer, Dordrecht, The Netherlands
7. Mialane P., Dolbecq A., Marrot J., Rivière E., and Sécheresse F. Eur. J. Inorg. Chem. 11 (2005) 1771
8. Howell R.C., Perez F.G., Jain S., Horrocks W.D., Rheingold J.A.L., and Francesconi L.C. Angew. Chem., Int. Ed. 40 (2001) 4031
9. Reinoso S., Vitoria P., Felices L.S., Lezama L., and Gutiérrez-Zorrilla J. Eur. J. Inorg. Chem. 11 (2005) 1538
10. Zheng S.T., Zhang J., and Yang G.Y. Inorg. Chem. 44 (2005) 2426
11. Bassil B.S., Dickman M.H., and Kortz U. Inorg. Chem. 45 (2006) 2394
12. Bi L.H., and Kortz U. Inorg. Chem. 43 (2004) 7961
13. Bassil B.S., Nellutla S., Kortz U., Stowe A.C., van Tol J., Dalal N.S., Keita B., and Nadjo L. Inorg. Chem. 44 (2005) 2659
14. Pope M.T., and Mu{combining double acute accent}ller A. Angew. Chem., Int. Ed. 30 (1991) 34
15. Ruther T., Hultgren V.M., Timko B.P., Bond A.M., Jackson W.R., and Wedd A.G. J. Am. Chem. Soc. 125 (2003) 10133
16. Pan C.L., Xu J.Q., Li D.H., and Chu D.Q. Eur. J. Inorg. Chem. 8 (2003) 1514
17. Representative examples include the following and references therein:. Zhang X., Anderson T.M., Chen Q., and Hill C.L. Inorg. Chem. 40 (2001) 418
18. Ruhlmann L., Canny J., Contant R., and Thouvenot R. Inorg. Chem. 41 (2002) 3811
19. Laronze N., Marrot J., and Hervé G. Inorg. Chem. 42 (2003) 5857
20. Bi L.H., and Kortz U. Inorg. Chem. 43 (2004) 7961
21. Bi L.-H., Reicke M., Kortz U., Keita B., Nadjo L., and Clark R.J. Inorg. Chem. 43 (2004) 3915
22. Kortz U., Nellutla S., Stowe A.C., Dalal N.S., Rauwald U., Danquah W., and Ravot D. Inorg. Chem. 43 (2004) 2308
23. Kortz U., Nellutla S., Stowe A.C., Dalal N.S., van Tol J., and Bassil B.S. Inorg. Chem. 43 (2004) 144
24. Keita B., Mbomekalle I.M., Nadjo L., Anderson T.M., and Hill C.L. Inorg. Chem. 43 (2004) 3257
25. Ritorto M.D., Anderson T.M., Neiwert W.A., and Hill C.L. Inorg. Chem. 43 (2004) 44
26. Limanski E.M., Drewes D., and Krebs B. Z. Anorg. Allg. Chem. 630 (2004) 523
27. Bi L.H., Kortz U., Nellutla S., Stowe A.C., van Tol J., Dalal N.S., Keita B., and Nadjo L. Inorg. Chem. 44 (2005) 896
28. Zhang Z., Li Y., Wang E., Wang X., Qin C., and An H. Inorg. Chem. 45 (2006) 4313
29. Yamase T., Fukaya K., Nojiri H., and Ohshima Y. Inorg. Chem. 45 (2006) 7698
30. Zhao J.W., Zhang J., Zheng S.T., and Yang G.Y. Inorg. Chem. 46 (2007) 10944
31. Zheng S.-T., Yuan D.-Q., Zhang J., and Yang G.-Y. Inorg. Chem. 46 (2007) 4569
32. Liu Y., Liu B., Xue G., Hu H., Fu F., and Wang J. Dalton Trans. 33 (2007) 3634
33. Piedra-Garza L.F., Dickman M.H., Moldovan O., Breunig H.J., and Kortz U. Inorg. Chem. 48 (2009) 411
34. P Wang J., Ma P.T., Shen Y., and Niu J.Y. Cryst. Growth Des. 7 (2007) 603
35. Borras-Almenar J.J., Clemente-Juan J.M., Clemente-Leon M., Coronado E., Galan- Mascaros J.R., and Gomez-Garcia C.J. In: Pope M.T., and Müller A. (Eds). Polyoxometalate Chemistry: From Topology Via Self-Assembly to Applications (2001), Kluwer, Dordrecht, The Netherlands 231
36. Clemente-Juan J.M., Coronado E., Forment-Aliaga A., Galan-Mascaros J.R., Gimenez- Saiz C., and Gomez-Garcia C.J. Inorg. Chem. 43 (2004) 2689
37. Mbomekalle I.M., Keita B., Nierlich M., Kortz U., Berthet P., and Nadjo L. Inorg. Chem. 42 (2003) 5143
38. Ritorto M.D., Anderson T.M., Neiwert W.A., and Hill C.L. Inorg. Chem. 43 (2004) 44
39. Li B., Zhao J.-W., Zheng S.-T., and Yang G.-Y. Inorg. Chem. Commun. 12 (2009) 69
40. -1.
41. 2 = 0.993.
42. 2 by full matrix least-squares using the shelxtl-97 program package. Heavy atoms (Ge, W, Co and Na) were refined with anisotropic displacement parameters. Oxygen atoms were refined isotropically. Hydrogen atoms were not included. As usual for polyoxometalates, the crystal shows partly disorder in the range of counter ions and water molecules, accordingly, the exact formula was determined by elemental analyses. Further details of the crystal structure investigation can be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository number CSD 420866.
43. Zheng S.-T., Zhang J., and Yang G.-Y. Angew. Chem., Int. Ed. 120 (2008) 3973
44. Mbomekalle I.M., Keita B., Nadjo L., Neiwert W.A., Zhang L., Hardcastle K.I., Hill C.L., and Anderson T.M. Eur. J. Inorg. Chem. (2003) 3924