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Volumn 13, Issue 1, 2010, Pages 116-118

The first example of extended structure constructed from Knoth-type sandwich POMs and coordination fragments

Author keywords

Hydrothermal synthesis; Knoth type; Polyoxometalate; POMs in extended structure; Sandwich polyoxoanions

Indexed keywords


EID: 72249114927     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.10.034     Document Type: Article
Times cited : (5)

References (47)
  • 42
    • 72249102694 scopus 로고    scopus 로고
    • note
    • 2+).
  • 43
    • 72249115027 scopus 로고    scopus 로고
    • note
    • 3, Z = 2. A black block single crystal of 1 was glued on to a glass fiber. The data were collected on a Bruker Apex II CCD diffractometer with Mo Kα radiation (λ = 0.71073 Å) at 23 K in the range of 0.82° < θ < 26.05°. A empirical absorption correction was applied. A total of 25,016 (17,455 unique, R(int) = 0.0264) reflections were measured (-11 ≤ h ≤ 16, -16 ≤ k ≤ 16, -31 ≤ l ≤ 26). Structure solution and refinement based on 1090 parameters gave R1 (wR2) = 0.0409 (0.0993). The positions of the hydrogen atoms attached to lattice water molecules were not located. It should be noted that positions of W19, W20 and W21 are disorderedly occupied by W19, Cu5, W20, Cu6 and W21, Cu7 with occupency factors of 0.5, respectively. CCDC number: 739059.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.