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Volumn , Issue 19, 2009, Pages 3151-3154

Rhodium-Catalyzed cross-coupling of arylboronic acids using vinyl acetate as the electrophilic partner

Author keywords

Catalysis; Cross coupling; Rhodium; Vinyl acetate

Indexed keywords

ARYLBORONIC ACID; BORONIC ACID DERIVATIVE; ELECTROPHILE; PALLADIUM; RHODIUM; UNCLASSIFIED DRUG; VINYL ACETATE;

EID: 72049089020     PISSN: 09365214     EISSN: 14372096     Source Type: Journal    
DOI: 10.1055/s-0029-1218283     Document Type: Article
Times cited : (30)

References (53)
  • 1
    • 0003397781 scopus 로고    scopus 로고
    • 2nd ed.de Meijere, A.; Diederich, F., Eds.; Wiley-VCH: Weinheim
    • (a) Metal-Catalyzed Cross-Coupling Reactions, 2nd ed., Vol.1-2; de Meijere, A.; Diederich, F., Eds.; Wiley-VCH: Weinheim, 2004.
    • (2004) Metal-Catalyzed Cross-Coupling Reactions , vol.1 , pp. 2
  • 32
    • 57749117273 scopus 로고    scopus 로고
    • For Ni-catalyzed ArOMs couplings, see
    • (e) Zhang, L.; Qing, J.; Yang, P.; Wu, J. Org. Lett. 2008, 10, 4971. For Ni-catalyzed ArOMs couplings, see:
    • (2008) Org. Lett. , vol.10 , pp. 4971
    • Zhang, L.1    Qing, J.2    Yang, P.3    Wu, J.4
  • 40
    • 15944416407 scopus 로고    scopus 로고
    • To our knowledge, there is no literature report on cross-coupling of vinyl acetate before. Only oxidative coupling and 2-phenylpyridine C-H activation/coupling were reported, see: (a) Amatare, M.; Gosmini, C.; Périchon, J. Eur. J. Org. Chem. 2005, 989.
    • (2005) Eur. J. Org. Chem. , vol.989
    • Amatare, M.1    Gosmini, C.2    Périchon, J.3
  • 49
    • 56849114012 scopus 로고    scopus 로고
    • We have attempted to use MW reactor instead of conventional heating to perform this reaction. Under the same reaction conditions except MW heating at 130°C for 1 h, only 25% yield of p-tert-butylstyrene was obtained. For our recent reference on rhodium catalysis under MW conditions, see: Lee, H. W.; Lee, L. N.; Chan, A. S. C.; Kwong, F. Y. Eur. J. Org. Chem. 2008, 3403.
    • (2008) Eur. J. Org. Chem. , pp. 3403
    • Lee, H.W.1    Lee, L.N.2    Chan, A.S.C.3    Kwong, F.Y.4
  • 50
    • 72049120480 scopus 로고    scopus 로고
    • We tried to lower the loading of vinyl acetate to 2 equiv (with respected to arylboronic acid). However, the product yield dropped significantly
    • We tried to lower the loading of vinyl acetate to 2 equiv (with respected to arylboronic acid). However, the product yield dropped significantly.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.