Improvement of performance of palladium-based catalyst for small methanol reformer

Chemical Engineering Science

Volumn 65, Issue 1, 2010, Pages 201-207

  Kawamura, Yoshihiro ^a   Yahata, Takashi ^a   Igarashi, Akira ^b  

^a CASIO   (Japan)

^b KOGAKUIN UNIVERSITY   (Japan)

Author keywords

Catalysis; Catalyst deactivation; Fuel; Methanol reforming; Palladium based catalyst; Reaction engineering

Indexed keywords

BET SURFACE AREA; CATALYTIC ACTIVITY; CO-PRECIPITATED; DISTILLED WATER; LONG LASTING; METAL SALT; METHANOL REFORMER; METHANOL REFORMING; MIXED SOLUTION; REACTION ENGINEERING; THERMAL DURABILITY; ZNO;

CATALYSIS; CATALYST DEACTIVATION; CATALYST POISONING; DIFFUSERS (OPTICAL); DURABILITY; ELECTROCHEMICAL SENSORS; METHANOL; PALLADIUM; PRECIPITATION (CHEMICAL); REFORMING REACTIONS; SALTS; ZINC OXIDE;

CATALYST ACTIVITY;

EID: 71849101416     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.07.021     Document Type: Article

References (28)

1. 3. Journal of Catalysis 219 (2003) 389-403
2. Agrell J., Germani G., Järås S.G., and Boutonnet M. Production of hydrogen by partial oxidation of methanol over ZnO-supported palladium catalysts prepared by microemulsion technique. Applied Catalysis A: General 242 (2003) 233-245
3. Busca G., Costantino U., Marmottini F., Montanari T., Patrono P., Pinzari F., and Ramis G. Methanol steam reforming over ex-hydrotalcite Cu-Zn-Al catalysts. Applied Catalysis A: General 310 (2006) 70-78
4. Cubeiro M.L., and Fierro J.L.G. Partial oxidation of methanol over supported palladium catalysts. Applied Catalysis A: General 168 (1998) 307-322
5. Ehrfeld W., Hessel V., and Löwe H. Microreactors (2000), Wiley-VCH, Weinheim, Germany
6. Fukuhara C., Kamata Y., and Igarashi A. Catalytic performance of plate-type Pd/Zn-based catalysts for steam reforming of methanol, prepared by electroless plating. Applied Catalysis A: General 330 (2007) 108-116
7. Iwasa N., Kudo S., Takahashi H., Masuda S., and Takezawa N. Highly selective supported Pd catalysts for steam reforming of methanol. Catalysis Letters 19 (1993) 211-216
8. Iwasa N., Masuda S., Ogawa N., and Takezawa N. Steam reforming of methanol over Pd/ZnO: effect of the formation of PdZn alloys upon the reaction. Applied Catalysis A: General 125 (1995) 145-157
9. Iwasa N., Ogawa N., Masuda S., and Takezawa N. Selective PdZn alloy formation in the reduction of Pd/ZnO catalysts. Bulletin of the Chemical Society of Japan 71 (1998) 1451-1455
10. Iwasa N., Mayanagi T., Ogawa N., Sakata K., and Takezawa N. New catalytic functions of Pd-Zn, Pd-Ga, Pd-In, Pt-Zn, Pt-Ga and Pt-In alloys in the conversions of methanol. Catalysis Letters 54 (1998) 119-123
11. 3 catalyst for a micro methanol reformer. Journal of Power Sources 150 (2005) 20-26
12. Kawamura Y., Ogura N., Yahata T., Yamamoto K., Terazaki T., Yamamoto T., and Igarashi A. Multi-layered microreactor system with methanol reformer for small PEMFC. Journal of Chemical Engineering of Japan 38 (2005) 854-858
13. Kawamura Y., Ogura N., Yamamoto T., and Igarashi A. A miniaturized methanol reformer with Si-based microreactor for a small PEMFC. Chemical Engineering Science 61 (2006) 1092-1101
14. Kolb G., Hessel V., Cominos V., Pennemann H., Schürer J., Zapf R., and Löwe H. Microstructured fuel processors for fuel-cell applications. Journal of Materials Engineering and Performance 15 (2006) 389-393
15. Kniep B.L., Girgsdies F., and Ressler T. Effect of precipitate aging on the microstructural characteristics of Cu/ZnO catalysts for methanol steam reforming. Journal of Catalysis 236 (2005) 34-44
16. Kwon O.J., Hwang S.M., Ahn J.G., and Kim J.J. Silicon-based miniaturized-reformer for portable fuel cell applications. Journal of Power Sources 156 (2006) 253-259
17. Lenarda M., Storaro L., Frattini R., Casagrande M., Marchiori M., Capannelli G., Uliana C., Ferrari F., and Ganzerla R. Oxidative methanol steam reforming (OSRM) on a PdZnAl hydrotalcite derived catalyst. Catalysis Communications 8 (2007) 467-470
18. Liu S., Takahashi K., and Ayabe M. Hydrogen production by oxidative methanol reforming on Pd/ZnO catalyst: effects of Pd loading. Catalysis Today 87 (2003) 247-253
19. 2 over nonreduced Zr-containing CuO/ZnO catalysts. Journal of Catalysis 223 (2004) 340-351
20. 3 catalyst for low-temperature dehydrogenation of isobutane. Applied Catalysis A: General 258 (2004) 153-158
21. Park H.G., Malen J.A., Piggott III W.T., Morse J.D., Greif R., Grigoropoulos C.P., Havstad M.A., and Upadhye R. Methanol steam reformer on a silicon wafer. Journal of Microelectromechanical Systems 15 (2006) 976-985
22. Pavio, J., 2003. Performance and design of a reformed hydrogen fuel cell system. In: Abstracts of the 2003 Fuel Cell Seminar, Miami Beach, FL, pp. 973-976.
23. Pfeifer P., Schubert K., Liauw M.A., and Emig G. PdZn catalysts prepared by washcoating microstructured reactors. Applied Catalysis A: General 270 (2004) 165-175
24. 3 catalysts prepared by homogeneous precipitation method in steam reforming of methanol. Applied Catalysis A: General 263 (2004) 249-253
25. Shirai, T., Iida, H., Igarashi, A., 2005. Preparation of high surface area Pt/ZnO catalyst for low-temperature dehydrogenation of isobutane. PACIFICHEM 2005, Honolulu, HI, #0277.
26. Tanaka S., Chang K.S., Min K.B., Satoh D., Yoshida K., and Esashi M. MEMS-based components of a miniature fuel cell/fuel reformer system. Chemical Engineering Journal 101 (2004) 143-149
27. Terazaki T., Nomura M., Takeyama K., Nakamura O., and Yamamoto T. Development of multi-layered microreactor with methanol reformer for small PEMFC. Journal of Power Sources 145 (2005) 691-696
28. 3 hydrotalcite-derived catalysts. Journal of Catalysis 228 (2004) 56-65