Separation of ethylene/ethane mixtures by adsorption on small-pored titanosilicate molecular sieves

Chemical Engineering Science

Volumn 65, Issue 2, 2010, Pages 807-811

  Anson, A ^a   Lin, C C H ^a   Kuznicki, T M ^a   Kuznicki, S M ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

Adsorption; Gases; Ion exchange; Selectivity; Separations; Zeolites

Indexed keywords

ADSORPTIVE SEPARATION; CHROMATOGRAPHIC SELECTIVITY; CONTACT TIME; DISTILLATION METHOD; IDEAL ADSORBED SOLUTION THEORY; KEY FACTORS; KINETIC SEPARATION; MOLECULAR SIEVING; PHASE GAS; SELECTIVITY; STERIC EFFECT; TITANOSILICATES;

ATMOSPHERIC TEMPERATURE; BARIUM; CHROMATOGRAPHIC ANALYSIS; DISTILLATION; ETHANE; ETHYLENE; GAS ADSORPTION; GASES; ION EXCHANGE; ION EXCHANGERS; IONS; ISOTHERMS; MOLECULAR SIEVES; SIEVES; SILICATE MINERALS; STRONTIUM; ZEOLITES; ZINC;

GAS CHROMATOGRAPHY;

EID: 71849092815     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.09.033     Document Type: Article

References (17)

1. Al-Baghli N.A., and Loughlin K.F. Binary and ternary adsorption of methane, ethane, and ethylene on titanosilicate ETS-10 zeolite. Journal of Chemical and Engineering Data 51 (2006) 248-254
2. Auvil, S.R., Schork, J.M., Srinivasan, R., 1993. Air separation by pressure swing adsorption with a high capacity carbon molecular sieve. US Patent 5,240,474.
3. Choudary N.V., Kumar P., Bhat T.S.G., Cho S.H., Han S.S., and Kim J.N. Adsorption of light hydrocarbon gases on alkene-selective adsorbent. Industrial and Engineering Chemistry Research 41 (2002) 2728-2734
4. Danner R.P., and Choi E.C.F. Mixture adsorption equilibria of ethane and ethylene on 13X molecular sieves. Industrial and Engineering Chemistry Fundamentals 17 4 (1978) 248-253
5. Kuznicki, S.M., 1990. Preparation of small-pored crystalline titanium molecular sieve zeolites. US Patent 4,938,939.
6. Kuznicki, S.M., 1991. Large-pored crystalline titanium molecular sieve zeolites. US Patent No. 5,011,591.
7. Kuznicki, S.M., Bell, V.A., Petrovic, I., Blosser, P.W., 1999. Separation of nitrogen from mixtures thereof with methane utilizing barium exchanged ETS-4. US Patent 5,989,316.
8. Kuznicki, S.M., Bell, V.A., Petrovic, I., Desai, B.T., 2000. Small-pored crystalline titanium molecular sieve zeolites and their use in gas separation processes. US Patent 6,068,682.
9. Kuznicki S.M., Bell V.A., Nair S., Hillhouse H.W., Jacubinas R.M., Braunbarth C.M., Toby B.H., and Tsapatsis M. A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules. Nature 412 (2001) 720-723
10. Kuznicki, S.M., Bell, V.A., 2003. Olefin separations employing CTS molecular sieves. US Patent 6,517,611 B1.
11. Kuznicki, S.M., Sawada, J.A., Rode, E.J., Lin, C.C.H., 2008. Silicate materials, method for their manufacture, and the method for using such silicate materials for adsorptive fluid separations. International Patent WO 2008/002463.
12. Myers A.L., and Prausnitz J.M. Thermodynamics of mixed-gas adsorption. A.I.Ch.E. Journal 11 1 (1965) 121
13. Ruthven D.M., Farooq S., and Knaebel K.S. Pressure Swing Adsorption (1994), Wiley, New York
14. Sircar S., and Myers A.L. Handbook of Zeolite Science and Technology (Gas Separation by Zeolites) (2003), Marcel Dekker Inc., New York
15. Valenzuela D.P., and Myers A.L. Adsorption Equilibrium Data Handbook (1989), Prentice-Hall, Englewood Cliffs, NJ
16. Van Miltenburg A., Zhu W., Kapteijn F., and Moulijn J.A. Adsorptive separation of light olefin/paraffin mixtures. Chemical Engineering Research and Design 84 A5 (2006) 350-354
17. Yang R.T. Adsorbents: Fundamentals and Applications (2003), Wiley, New York