Preparation, characterization and thermolysis of nitrate and perchlorate salts of 2,4,6-trimethylaniline

Journal of Hazardous Materials

Volumn 173, Issue 1-3, 2010, Pages 173-180

  Kapoor, Inder Pal Singh ^a   Kapoor, Manisha ^a   Singh, Gurdip ^a   Singh, Udai P ^b   Goel, Nidhi ^b  

^a D D U GORAKHPUR UNIVERSITY   (India)

^b INDIAN INSTITUTE OF TECHNOLOGY ROORKEE   (India)

Author keywords

Explosion; Ignition; Nitrate; Perchlorate; Thermolysis

Indexed keywords

CONDENSED PHASE; HIGHER TEMPERATURES; ISO-CONVERSIONAL METHOD; MODEL FITTING; PERCHLORATE; PERCHLORATE SALT; THERMAL DECOMPOSITIONS;

ACTIVATION ENERGY; AMINES; EXPLOSIONS; ORGANIC COMPOUNDS; PHOTORESISTS; PROTON TRANSFER; PYROLYSIS; REACTION KINETICS; SALTS; THERMOLYSIS; X RAY CRYSTALLOGRAPHY;

NITRATES;

2,4,6 TRIMETHYLANILINIUM NITRATE; 2,4,6 TRIMETHYLANILINIUM PERCHLORATE; AMINE; AMMONIUM DERIVATIVE; NITRIC ACID; PERCHLORATE; UNCLASSIFIED DRUG;

ACTIVATION ENERGY; GRAVIMETRY; NITRATE; NITRIC ACID; OXIDATION; PERCHLORATE; REACTION KINETICS; REDUCTION; THERMAL DECOMPOSITION;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION KINETICS; CONTROLLED STUDY; CRYSTAL STRUCTURE; DECOMPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; GRAVIMETRY; HEAT TREATMENT; LYSIS; OXIDATION; PROTON TRANSPORT; REDUCTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ANILINE COMPOUNDS; CHROMATOGRAPHY, THIN LAYER; CRYSTALLIZATION; CRYSTALLOGRAPHY, X-RAY; HOT TEMPERATURE; INDICATORS AND REAGENTS; MODELS, MOLECULAR; NITRATES; PERCHLORIC ACID; SILICON DIOXIDE; THERMOGRAVIMETRY;

EID: 71749119717     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2009.08.058     Document Type: Article

References (26)

1. Singh G., Singh C.P., and Felix P. Recent Researches on Thermolysis of Energetic Materials (2008), Nova Publication Inc, New York
2. Singh G., and Pandey D.K. Studies on energetic compounds part 30: kinetics and mechanism of thermolysis of bis (diethylenetriamine) metal (II) nitrate complexes. J. Therm. Anal. Calorim. 76 (2004) 507-519
3. Kummer J.T. Thermal decomposition of ammonium nitrate. J. Am. Chem. Soc. 69 (1947) 2559-2562
4. 4 a review. J. Hazard. Mater. A 79 (2000) 1-18
5. - salt. J. Cryst. Spect. Res. 21 (1991) 167-171
6. Erdey L., and Gal S. Thermoanalytical investigations of high temperature fusion reactions. Talanta 10 (1963) 23-36
7. Erdey L., Gal S., and Liptay G. Thermoanalytical properties of analytical grade reagents: ammonium salts. Talanta 11 (1964) 913-940
8. Kapoor I.P.S., Srivastava P., and Singh G. Preparation, characterization & thermolysis of phenylenediammonium dinitrate salts. J Hazard. Mater. 150 (2008) 687-694
9. Kapoor I.P.S., Srivastava P., Singh G., Singh U.P., and Fröhlich R. Preparation, crystal structure and thermolysis of diperchlorate salts. J. Phys. Chem. A 112 4 (2008) 652-659
10. Singh G., Kapoor I.P.S., and Jacob S. Studies on energetic compounds- Part 19: Preparation and thermolysis of N-Methylanilinium and N,N- dimethylanilinium nitrate and perchlorates. J. Sci. Ind. Res. 59 (2000) 575-582
11. Singh G., Baranwal B.P., Kapoor I.P.S., Kumar D., Singh C.P., and Fröhlich R. Preparation, X-ray crystallography, and thermal decomposition of some transition metal nitrate complexes with hexamethylenetetramine. J. Therm. Anal. Calorim. 91 (2008) 971-976
12. Singh G., Baranwal B.P., Kapoor I.P.S., Kumar D., and Fröhlich R. Preparation, X-ray crystallography and thermal decomposition of some transition metal perchlorate complexes of hexamethylenetetramine. J. Phys. Chem. A 111 (2007) 12972-12976
13. Singh G., and Pandey D.K. Studies on energetic compounds, Part 40: kinetics of thermal decomposition of bis (propylenediamine) metal perchlorate complexes. J. Therm. Anal. Calorim. 82 (2005) 253-260
14. Singh G., Kapoor I.P.S., Singh J., and Kaur J. Role of proton transfer reaction in the thermolysis of alkyl and arylammonium salts. Ind. J. Chem. 39 B (2000) 1-9
15. Sheldric G.M. Phase annealing in SHELX-90: direct methods for larger structures. Acta Crystallogr. A 46 (1990) 467-473
16. Sheldric G.M. SHELXTL- NT, Version 6.12, Reference Manual (2000), University of Gottingen, Germany
17. Klaus B. DIAMOND, Version 1.2 c (1999), University of Bonn, Bonn, Germany
18. Allen F.H. The Cambridge structural database: a quarter of a million crystal structures and rising. Acta Crystallogr. B 58 (2000) 380-388
19. Singh G., and Singh R.R. Indigenously fabricated apparatus for thermogravimetric analysis. Res. Ind. 23 (1978) 92-93
20. Freeman E.S., and Gorden S. The application of the absolute rate theory of the nitrate- magnesium, sodium nitrate- magnesium. J. Phys. Chem. 60 (1956) 867-871
21. Henkins H., and McGill R. Rates of explosive decomposition of explosives experimental and theoretical kinetics study as a function of temperature. Ind. Eng. Chem. 44 (1952) 1391-1394
22. Brown M.E., Dollimore D., and Galaway A.K. Reactions in the Solid State. Comprehensive Chemical Kinetics 22 (1960), Elsevier, Amsterdam, The Netherlands pp.1-340
23. Vyazokin S., Dranca I., Fan X., and Advincula R. Kinetics of the thermal and thermo-oxidative degradation of polystyrene-clay nanocomposite. Macromol. Rapid Commun. 25 (2005) 498-503
24. Oyumi Y., and Brill T.B. Thermal decomposition of energetic materials, 25: shifting of the dominant decomposition site by backbone substitution of alkylammonium nitrate salts. J. Phys. Chem. 91 (1987) 3657-3661
25. Nambiar P.R., Vernekar Pai V.P., and Jain R.S. Thermal decomposition of methyl ammonium perchlorate. J. Therm. Anal. 7 (1975) 587-592
26. Russell T.P., and Brill T.B. Thermal decomposition of energetic materials. 39. Fast thermolysis patterns of poly (methyl), poly (ethyl), and primary alkylammonium mononitrate salts. Propellant Explos. Pyrotech. 1 (1990) 66-72