Effect of Mn2+ ions on the electrodeposition of zinc from acidic sulphate solutions

Hydrometallurgy

Volumn 99, Issue 3-4, 2009, Pages 249-254

  Zhang, Qi Bo ^a   Hua, Yixin ^a  

^a KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Crystal orientation; Deposit morphology; Kinetic parameters; Manganese; Potentiodynamic polarization; Zinc electrodeposition

Indexed keywords

CONCENTRATION RANGES; CRYSTALLOGRAPHIC ORIENTATIONS; DEPOSIT MORPHOLOGY; DEPOSIT QUALITY; EFFECT OF MN; KINETICS ANALYSIS; ON CURRENTS; OXIDIZED PRODUCTS; OXYGEN EVOLUTION REACTION; SULPHATE SOLUTIONS; ZINC ELECTRODEPOSITION;

CATHODIC POLARIZATION; DEPOSITS; ELECTRODEPOSITION; IONS; KINETIC PARAMETERS; MANGANESE; MANGANESE COMPOUNDS; MORPHOLOGY; OXYGEN; POTENTIODYNAMIC POLARIZATION; SINGLE CRYSTALS; ZINC;

CRYSTAL ORIENTATION;

EID: 71749110131     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2009.09.002     Document Type: Article

References (28)

1. Ault A.R., and Frazer E.J. Effects of certain impurities on zinc electrowinning in high-purity synthetic solutions. J. Appl. Electrochem. 18 (1988) 583-589
2. Cachet C., Rerolle C., and Wiart R. Kinetics of Pb and Pb-Ag anodes for zinc electrowinning-II. Oxygen evolution at high polarization. Electrochim. Acta 41 (1996) 83-90
3. 2+ ions on the kinetics of lead anodes for zinc electrowinning. J. Appl. Electrochem. 29 (1999) 811-818
4. Fosnacht D.R., and O'Keefe T.J. Evaluation of zinc sulphate electrolytes containing certain impurities and additives by cyclic voltammetry. J. Appl. Electrochem. 10 (1980) 495-504
5. Fosnacht D.R., and O'Keefe T.J. Effects of certain impurities and their interactions on zinc electrowinning. Met. Trans. 14B (1983) 645-655
6. Ivanov I., and Stefanov Y. Electroextraction of zinc from sulphate electrolytes containing antimony ions and hydroxyethylated-butyne-2-diol-1, 4: Part 3. The influence of manganese ions and a divided cell. Hydrometallurgy 64 (2002) 181-186
7. Kiryakov G.Z., Baynietova F.K., and Vakhidov R.S. Role of manganese in the electrolytic deposition of zinc. Tr. Inst. Khim. Akad. Nauk. S.S.R. 3 (1958) 72-81
8. Maja M., and Spinelli P. Detection of metallic impurities in acid zinc plating baths. J. Electrochem. Soc. 118 (1971) 1538-1540
9. Maja M., Penazzi N., Fratesi R., and Roventi G. Zinc electrocrystallization from impurity-containing sulfate baths. J. Electrochem. Soc. 129 (1982) 2695-2700
10. MacKinnon D.J. The effect of copper on zinc electrowinning from industrial acid sulphate electrolyte. J. Appl. Electrochem. 15 (1985) 953-960
11. MacKinnon D.J. The effects of foaming agents and their interaction with antimony, manganese and magnesium on zinc electrowinning from synthetic acid sulphate electrolyte. Hydrometallurgy. 35 (1994) 11-26
12. MacKinnon D.J., and Brannen J.M. Zinc deposit structures obtained from high purity synthetic and industrial acid sulphate electrolytes with and without antimony and glue additions. J. Appl. Electrochem. 7 (1977) 451-459
13. MacKinnon D.J., and Brannen J.M. Effect of manganese, magnesium, sodium and potassium sulphates on zinc electrowinning from synthetic acid sulphate electrolytes. Hydrometallurgy. 27 (1991) 99-111
14. MacKinnon D.J., Brannen J.M., and Fenn P.L. Characterization of impurity effects in zinc electrowinning from industrial acid sulphate electrolyte. J. Appl. Electrochem. 17 (1987) 1129-1143
15. MacKinnon D.J., and Fenn P.L. The effect of germanium on zinc electrowinning from industrial acid sulphate electrolyte. J. Appl. Electrochem. 14 (1984) 467-474
16. MacKinnon D.J., and Fenn P.L. The effect of tin on zinc electrowinning from industrial acid sulphate electrolyte. J. Appl. Electrochem. 14 (1984) 701-707
17. MacKinnon D.J., Morrison R.M., and Brannen J.M. The effects of nickel and cobalt and their interaction with antimony on zinc electrowinning from industrial acid sulphate electrolyte. J. Appl. Electrochem. 16 (1986) 53-61
18. Mohanty U.S., Tripathy B.C., Singh P., and Das S.C. Effect of pyridine and its derivatives on the electrodeposition of nickel from aqueous sulfate solutions. Part II: Polarization behaviour. J. Appl. Electrochem. 31 (2001) 969-972
19. Muresan L., Maurin G., Oniciu L., and Gaga D. Influence of metallic impurities on zinc electrowinning from sulphate electrolyte. Hydrometallurgy 43 (1996) 345-354
20. 4 layers at low polarization. Electrochim. Acta 40 (1995) 939-948
21. Robinson D.J., and O'Keefe T.J. On the effects of antimony and glue on zinc electro-crystallization behaviour. J. Appl. Electrochem. 6 (1976) 1-7
22. Saba A.E., and Elsberry A.E. Continuous electrowinning of zinc. Hydrometallurgy 54 (2000) 91-106
23. Stefanov Y., and Vane I. The influence of nickel ions and triethylbenzyl-ammonium chloride on the electrowinning of zinc from sulphate electrolytes containing manganese ions. Hydrometallurgy 64 (2002) 193-203
24. Stender V.V., and Pecherskaya A.G. Influence of impurities in the electrodeposition of zinc from sulfate solutions. Zhurnal. Prikladnoi. Khimii. (Sankt-Peterburg, Russian Federation) 23 9 (1950) 920-935
25. Tswuoka T. Behaviour of manganese in the electrodeposition of zinc. Nippon Kogyo. Kaishi. 76 (1960) 311-318
26. Vakhidov R.S., and Kiryakov G.Z. Role of manganese during the electrodeposition of zinc. Izv. Vissh. Ucheb. Zaved. Khim. Technol. 2 (1959) 238-243
27. Wark I.W. The electrodeposition of zinc from acidified zinc sulphate solution. J. Appl. Electrochem. 9 (1979) 721-730
28. 4 on zinc electrodeposition from acidic sulfate electrolyte. J. Appl. Electrochem. 39 (2009) 261-267