Kinetics and product distribution of end of life tyres (ELTs) pyrolysis: A novel approach in polyisoprene and SBR thermal cracking

Journal of Hazardous Materials

Volumn 172, Issue 2-3, 2009, Pages 1690-1694

  Al Salem, S M ^a   Lettieri, P ^a   Baeyens, J ^b  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

^b UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

ELTs; Hazardous waste; Kinetics; Pyrolysis; Thermogravimetry

Indexed keywords

A-THERMAL; CONVERSION TIME; DYNAMIC THERMOGRAVIMETRY; ELTS; END OF LIVES; GLOBAL PRODUCTS; HAZARDOUS WASTE; HAZARDOUS WASTES; KINETIC RATE CONSTANTS; LANDFILLING; OPEN SPACE; PRODUCT DISTRIBUTIONS; PYROLYSIS PROCESS; SECONDARY-SIDE; SOIL AND WATER; THERMAL CRACKING; THERMAL DEGRADATIONS; THERMOCHEMICAL TREATMENTS; THERMOGRAVIMETRY;

ENERGY CONVERSION; HAZARDOUS MATERIALS; OPTICAL TELESCOPES; RATE CONSTANTS; THERMOGRAVIMETRIC ANALYSIS; WASTE DISPOSAL; WATER RESOURCES;

CRACKING (CHEMICAL);

ISOPRENE; POLYISOPRENE; UNCLASSIFIED DRUG;

HAZARDOUS WASTE; KINETICS; POLYMERIZATION; PYROLYSIS; THERMOGRAVIMETRY; WASTE DISPOSAL; WASTE TREATMENT;

ARTICLE; DEPOLYMERIZATION; END OF LIFE TYRES PYROLYSIS; HAZARDOUS WASTE; INDUSTRIAL WASTE; PREDICTION; PRODUCT RECOVERY; PYROLYSIS; REGRESSION ANALYSIS; RUBBER INDUSTRY; THERMOGRAVIMETRY; WASTE MANAGEMENT;

CONSERVATION OF NATURAL RESOURCES; HEMITERPENES; HOT TEMPERATURE; INCINERATION; KINETICS; LATEX; THERMOGRAVIMETRY; WASTE MANAGEMENT;

EID: 71749097782     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2009.07.127     Document Type: Article

References (18)

1. Galvagno S., Casu S., Casabianca T., Calabrese A., and Cornacchia G. Pyrolysis process for the treatment of scrap tyres: preliminary experimental results. Waste Manage. 22 (2002) 917-923
2. Roy C., Chaala A., and Darmstad H. The vacuum pyrolysis of used tires: end-uses for oil and carbon black products. J. Anal. Appl. Pyrolysis 51 (1999) 201-221
3. Conesa J.A., Fullana A., and Font R. Tire pyrolysis: evolution of volatile and semivolatile compounds. Energy Fuels 14 (2000) 409-418
4. Berrueco C., Esperanza E., Mastral F.J., Ceamanos J., and Garcia-Bacaicoa P. Pyrolysis of waste tyres in an atmospheric static-bed batch reactor: Analysis of the gases obtained. J. Anal. Appl. Pyrolysis 74 (2005) 245-253
5. Cunliffe A.M., and Williams P.T. Composition of oils derived from the batch pyrolysis of tyres. J. Anal. Appl. Pyrolysis 44 (1998) 131-152
6. Cunliffe A.M., and Williams P.T. Influence of process conditions on the rate of activation of chars derived from pyrolysis of used tires. Energy Fuels 13 (1999) 166-175
7. Silva L.F.O., Moreno T., and Querol X. An introductory TEM study of Fe-nanominerals within coal fly ash. Sci. Total Environ. 407 (2009) 4972-4974
8. Senneca O., Salatino P., and Chirone R. An introductory TEM study of Fe-nanominerals within coal fly ash. Fuel 780 (1999) 1575-1581
9. Williams P.T., Besler S., and Taylor D.T. The pyrolysis of scrap automotive tyres: the influence of temperature and heating rate on product composition. Fuel 69 (1990) 1474-1482
10. Bouvier J.M., Charbel F., and Gelus M. Gas-solid pyrolysis of tire wastes-kinetics and material balances of batch pyrolysis of used tires. Resour. Conserv. 15 (1987) 205-214
11. Lucchesi A., and Maschio G. Semi-active carbon and aromatics produced by pyrolysis of scrap tires. Conserv. Recycl. 6 (1983) 85-90
12. Al-Salem S.M., Lettieri P., and Baeyens J. Thermal pyrolysis of high density polyethylene (HDPE). Proceedings 9th European Gasification Conference: Clean Energy and chemicals. Düsseldorf, Germany, 23-25 March (2009)
13. Khan A.R., Mathew J., Al-Shayji K., and Sari M. Copolyesteramides: synthesis and kinetic analysis. Euro. Polym. J. 38 (2002) 1013-1023
14. Khan A.R., Al-Roomi Y.M., Mathew J., and Sari M. Kinetic evaluation of an oligomeric amidation reaction. J. App. Polym. Sci. 82 (2001) 2534-2543
15. McCaffrey W.C., Kamal M.R., and Cooper D.G. Tertiary recycling of polyethylene: Mechanism of liquid production from polyethylene by thermolysis/reactive distillation. Poly. Degrad. Stab. 62 (1998) 513-521
16. Wu S., Su M., and Baeyens J. The fluidized bed pyrolysis of shredded tyres: the influence of carbon particles, humidity, and temperature on the hydrodynamics. Powder Technol. 93 (1997) 283-290
17. Grieco E., Bernardi M., and Baldi G. Styrene-butadiene rubber pyrolysis: products, kinetics, modelling. J. Anal. Appl. Pyrolysis 82 (2008) 304-311
18. Oh S.C., Jun H.C., and Kim H.T. Thermogravimetric evaluation for pyrolysis kinetics of styrene-butadiene rubber. J. Chem. Eng. Jpn. 36 (2003) 1016-1022