La0.8Sr0.2Ni0.4Fe0.6O 3?Ce0.8Gd0.2O2?δ nanocomposite as mixed ionic?electronic conducting material for SOFC cathode and oxygen permeable membranes: Synthesis and properties

Composite Interfaces

Volumn 16, Issue 4, 2009, Pages 407-431

  Sadykov, Vladislav ^a,b   Kharlamova, Tamara ^a   Batuev, Lubsan ^a   Muzykantov, Vitalii ^a   Mezentseva, Nathalia ^a   Krieger, Tamara ^a   Alikina, Galina ^a   Lukashevich, Anton ^a   Rogov, Vladimir ^a   Zaikovskii, Vladimir ^a   Ishchenko, Arcady ^a   Salanov, Aleksei ^a   Boronin, Andrei ^a   Koscheev, Sergei ^a   Pavlova, Svetlana ^a   Uvarov, Nikolai ^c   Smirnova, Alevtina ^d   Vasylyev, Oleksandr ^e  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

^c INSTITUTE OF SOLID STATE CHEMISTRY AND MECHANOCHEMISTRY   (Russian Federation)

^d UNIVERSITY OF CONNECTICUT   (United States)

^e FRANTSEVICH INSTITUTE FOR PROBLEMS OF MATERIALS SCIENCE   (Ukraine)

Author keywords

Characterization; Perovskite fluorite nanocomposite; SOFC; Synthesis; Transport properties

Indexed keywords

AMBIPOLAR TRANSPORT; CATHODE LAYERS; CONDUCTING MATERIALS; CONDUCTING NANOCOMPOSITES; FUNCTIONALLY GRADED; IMPEDANCE SPECTROSCOPY; OXYGEN ISOTOPE EXCHANGE; OXYGEN MOBILITY; POSITIVE EFFECTS; REAL STRUCTURE; SOFC; SURFACE COMPOSITIONS; SYNTHESIS; TEM; XPS; XRD;

CERIUM; CERIUM COMPOUNDS; COMPLEXATION; CRYSTAL GROWTH; FLUORSPAR; GADOLINIUM; IONIZATION OF LIQUIDS; ISOTOPES; LANTHANUM; NANOCOMPOSITES; NANOCRYSTALLINE POWDERS; OXIDE MINERALS; OXYGEN; PEROVSKITE; PHASE INTERFACES; SINTERING; SOLID OXIDE FUEL CELLS (SOFC); SURFACE ACTIVE AGENTS; TRANSPORT PROPERTIES; WATER ANALYSIS;

OXYGEN PERMEABLE MEMBRANES;

EID: 71649109334     PISSN: 09276440     EISSN: 15685543     Source Type: Journal    
DOI: 10.1163/156855409X450855     Document Type: Conference Paper

References (49)

1. K. C.Wincewicz and J. S. Cooper, Taxonomies of SOFC material and manufacturing alternatives, J. Power Sources 140, 280-296 (2005).
2. U. Balachandran, J. T. Dusek, R. E.Mieville, R. B. Poeppel, M. S. Kleefisch, S. Pei, T. P. Kobylinski, C. A. Udovich and A. C. Bose, Dense ceramic membranes for partial oxidation of methane to syngas, Appl. Catal. A 133, 19-29 (1995).
3. A. Petric, P. Huang and F. Tietz, Evaluation of La-Sr-Co-Fe-O perovskites for solid oxide fuel cells and gas separation membranes, Solid State Ionics 135, 719-725 (2000).
4. H. Ullmann, N. Trofimenko, F. Tietz, D. Stöver and A. Ahmad-Khanlou, Correlation between thermal expansion and oxide ion transport in mixed conducting perovskite-type oxides for SOFC cathodes, Solid State Ionics 138, 79-90 (2000).
5. E. P. Murray, M. J. Sever and S. A. Barnett, Electrochemical performance of (La, Sr)(Co, Fe)O3- (Ce, Gd)O2 composite cathodes, Solid State Ionics 148, 27-34 (2002).
6. B. Ma and U. Balachandran, Phase stability of SrFeCo0.5 in reducing environment, Mater. Res. Bull. 33, 223-236 (1998).
7. P. V. Hendriksen, P. H. Larsen, M. Mogensen, F.W. Poulsen and K.Wiik, Prospects and problems of dense oxygen permeable membranes, Catal. Today 56, 283-295 (2000).
8. S. McIntosh, J. F. Vente, W. G. Haije, D. H. A. Blank and H. J. M. Bouwmeester, Phase stability and oxygen non-stoichiometry of SrCo0.8Fe0.2O3-́ measured by in situ neutron diffraction, Solid State Ionics 177, 833-842 (2006).
9. H. L. Lein, K. Wiik and T. Grande, Kinetic demixing and decomposition of oxygen permeable membranes, Solid State Ionics 177, 1587-1590 (2006).
10. V. Dusastre and J. A. Kilner, Optimisation of composite cathodes for intermediate temperature SOFC applications, Solid State Ionics 126, 163-174 (1999).
11. E. P. Murray and S. A. Barnett, (La, Sr)MnO3-(Ce, Gd)O2-x composite cathodes for solid oxide fuel cells, Solid State Ionics 143, 265-273 (2001).
12. F. M. Figueiredo, J. R. Frade and F. M. B. Marques, Performance of composite LaCoO3-La2(Zr, Y)2O7 cathodes, Solid State Ionics 135, 463-467 (2000).
13. Y. Matsuzaki and I. Yasuda, Electrochemical properties of reduced-temperature SOFCs with mixed ionic-electronic conductors in electrodes and/or interlayers, Solid State Ionics 152-153, 463-468 (2002).
14. W. G. Wang and M. Mogensen, High-performance lanthanum-ferrite-based cathode for SOFC, Solid State Ionics 176, 457-462 (2005).
15. N. Oishi, Y. Yoo and I. Davidson, La0.6Sr0.4Co0.2Fe0.8O3-Ce0.8Sm0.2O2- ́ composite cathode for operation below 600́C, Electrochem. Soc. Proc. 07, 1645-1651 (2005).
16. V. V. Kharton, A. V. Kovalevsky, A. P. Biskup, A. L. Shaula, F. M. Figueiredo, E. N. Naumovich and F. M. B. Marques, Oxygen transport in Ce0.8Gd0.2O2-́-based composite membranes, Solid State Ionics 160, 247-258 (2003).
17. U. Nigge, H.-D.Wiemhöfer, E.W. J. Römer, H. J.M. Bouwmeester and T. R. Schulte, Composites of Ce0.8Gd0.2O1.9 and Gd0.7Ca0.3CoO3+́ as oxygen permeable membranes for exhaust gas sensors, Solid State Ionics 146, 163-174 (2002).
18. V. V. Zyryanov, N. F. Uvarov, V. A. Sadykov, Y. V. Frolova, G. M. Alikina, A. I. Lukashevich, M. I. Ivanovskaya, J. M. Criado and S. Neophytides, Mechanosynthesis of complex oxides and preparation of mixed conducting nanocomposites for catalytic membrane reactors, Catal. Today 104, 114-119 (2005).
19. Yu. V. Frolova-Borchert, V. A. Sadykov, G. M. Alikina, A. I. Lukashevich, E. M. Moroz, D. I. Kochubey, V. V. Kriventsov, V. I. Zaikovskii, V. V. Zyryanov and N. F. Uvarov, Nanocomposites comprised of doped cerium dioxide and lanthanum manganite for syngas production, Solid State Ionics 177, 2533-2538 (2006).
20. V. A. Sadykov, Yu. V. Borchert, G. M. Alikina, A. I. Lukashevich, N. V. Mezentseva, V. S. Muzykantov, E. M. Moroz, V. A. Rogov, V. I. Zaikovskii, D. A. Zyuzin, N. F. Uvarov, A. V. Ishchenko, V. V. Zyryanov and A. Smirnova, Synthesis and properties of nanocomposites with mixed ionic-electronic conductivity on the basis of oxide phases with perovskite and fluorite structures, Glass Phys. Chem. 33, 320-334 (2007).
21. V. V. Kharton, A. P. Viskup, E. N. Naumovich and V. N. Tikhonovich, Oxygen permeability of LaFe1-xNixO3-́ solid solutions, Mater. Res. Bull. 34, 1311-1317 (1999).
22. M. Bevilacqua, T. Montini, C. Tavagnacco, G. Vicario, P. Fornasiero and M. Graziani, Influence of synthesis route on morphology and electrical properties of LaNi0.6Fe0.4O3, Solid State Ionics 177, 2957-2965 (2006).
23. R. Chiba, F. Yoshimura and Y. Sakurai, Properties of La1-y SryNi1-xFexO3 as a cathode material for a low-temperature operating SOFC, Solid State Ionics 152-153, 575-582 (2002).
24. K. Świerczek, J. Marzec, D. Páubiak, W. Zajác and J. Molenda, LFN and LSCFN perovskites- structure and transport properties, Solid State Ionics 177, 1811-1817 (2006).
25. S. J. Skinner and J. A. Kilner, Oxygen diffusion and surface exchange in La2-x SrxNiO4+́ , Solid State Ionics 135, 709-712 (2000).
26. L. Mogni, F. Prado, A. Caneiro and A. Manthiram, High temperature properties of the n = 2 Ruddlesden-Popper phases (La, Sr)3(Fe, Ni)2O7-́ , Solid State Ionics 177, 1807-1810 (2006).
27. S. Miyoshi, T. Furuno, H. Matsumoto and T. Ishihara, Conductivity and oxygen permeability of a novel oxide, Pr2Ni0.8-xCu0.2FexO4 and its application to partial oxidation of CH4, Solid State Ionics 177, 2269-2273 (2006).
28. V. Vashook, J. Zosel, T.-L. Wen and U. Guth, Transport properties of the Pr2-x SrxNiO4́́ ceramics with x = 0.3 and 0.6, Solid State Ionics 177, 1827-1830 (2006).
29. A. Hagiwara, N. Hobara, K. Takizawa, K. Sato, H. Abe and M. Naito, Microstructure control of SOFC cathodes using the self-organizing behavior of LSM/ScSZ composite powder material prepared by spray pyrolysis, Solid State Ionics 178, 1123-1134 (2007).
30. M. P. Pechini, Method of preparing lead and alkaline earth titanates and niobates and coating method using the same to form a capacitor, U.S. Patent 3,330,697 (1967).
31. T. Kharlamova, S. Pavlova, V. Sadykov, T. Krieger, N. Mezentseva, V. Muzykantov, G. Alikina, A. Boronin, V. Zaikovskii, A. Ishchenko, V. Rogov, N. Uvarov, J. Frade and Chr. Argirusis, Perovskite and composite materials for intermediate temperatures solid oxide fuel cells, Mater. Res. Soc. Sympos. Proc. 1056, HH03-64.1-6 (2008).
32. V. A. Sadykov, Yu. V. Frolova, G. M. Alikina, A. I. Lukashevich, V. S. Muzykantov, V. A. Rogov, E. M. Moroz, D. A. Zyuzin, V. P. Ivanov, H. Borchert, E. A. Paukshtis, V. I. Bukhtiyarov, V. V. Kaichev, S. Neophytides, E. Kemnitz and K. Scheurell, Mobility and reactivity of lattice oxygen in Gd-doped ceria promoted by Pt, React. Kinet. Catal. Lett. 85, 367-374 (2005). (Pubitemid 41118850)
33. H. Borchert, Yu. Borchert, V. V. Kaichev, I. P. Prosvirin, G. M. Alikina, A. I. Lukashevich, V. I. Zaikovskii, E. M. Moroz, E. A. Paukshtis, V. I. Bukhtiyarov and V. A. Sadykov, Nanostructured Gd-doped ceria promoted by Pt or Pd: investigation of the electronic and surface structures and relations to chemical properties, J. Phys. Chem. 109, 20077-20086 (2005).
34. D. Briggs and M. P. Seah, Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy. Wiley, New York, NY, USA (1983).
35. J. F. Moulder, W. F. Stickle and P. E. Sobol, Handbook of X-ray Photoelectron Spectroscopy. Perkin-Elmer Corporation, Physical Electronics Division, Eden Prairie Minnesota, USA (1992).
36. V. A. Sadykov, N. N. Bulgakov, V. S. Muzykantov, T. G. Kuznetsova, G. M. Alikina, A. I. Lukashevich, Yu. V. Potapova, V. A. Rogov, E. B. Burgina, V. I. Zaikovskii, E. M. Moroz, G. S. Litvak, I. S. Yakovleva, L. A. Isupova, V. V. Zyryanov, E. Kemnitz and S. Neophytides, Mobility and reactivity of the surface and lattice oxygen of some complex oxides with per(r)vskite structure, in: Mixed Ionic Electronic Conducting Perovskites for Advanced Energy System, N. Orlovskaya and N. Browning (Eds), pp. 49-70. Kluwer Academic Publishers, Boston (2004).
37. H. Falcón, A. E. Goéta, G. Punte and R. E. Carbonio, Crystal structure refinement and stability of LaFexNi1-xO3 solid solutions, J. Solid State Chem. 133, 379-385 (1997).
38. R. D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides, Acta Cryst. A 32, 751-767 (1976).
39. A. Mineshige, J. Abe, M. Kobune, Y. Uchimoto and T. Yazawa, Oxygen nonstoichiometry, mixed valency and mixed conduction in (La, Sr)(Co, Fe)O3-́ , Solid State Ionics 177, 1803-1806 (2006).
40. I. Kosacki, T. Suzuki, V. Petrovskii and H. U. Anderson, Electrical conductivity of nanocrystalline ceria and zirconia thin films, Solid State Ionics 136-137, 1225-1233 (2000).
41. M. Mori, Y. Hiei, T. Yamamoto and H. Itoh, Lanthanum alkaline-earth manganites as a cathode material in high-temperature solid oxide fuel cells, J. Electrochem. Soc. 146, 4041-4047 (1999).
42. S. P. Yoona, J. Hana, S.W. Nama, T.-H. Lima, I.-H. Oha, S.-A. Honga, Y.-S. Yoob and H. C. Limb, Performance of anode-supported solid oxide fuel cell with La0.85Sr0.15MnO3 cathode modified by sol-gel coating technique, J. Power Sources 106, 160-166 (2002).
43. V. V. Kharton, A. V. Kovalevsky, A. P. Biskup, F. M. Figueiredo, A. A. Yaremchenko, E. N. Naumovich and F. M. B. Marques, Oxygen permeability of Ce0.8Gd0.2O2-́-La0.7Sr0.3MnO3 composite membranes, J. Electrochem. Soc. 147, 2814-2821 (2000).
44. J. A. M. Van Roosmalen, E. H. P. Cordfunke and R. B. Helmholdt, The defect chemistry of LaMnO3́́ , 2. Structural aspects of LaMnO3+́ , J. Solid State Chem. 110, 100-105 (1994).
45. H. Provendier, C. Petit, C. Estourń, S. Libs and A. Kiennemann, Stabilisation of active nickel catalysts in partial oxidation of methane to synthesis gas by iron addition, Appl. Catal. A 180, 163-173 (1999).
46. X. Xu, Ch. Xia, G. Xiao and D. Peng, Fabrication and performance of functionally graded cathodes for IT-SOFCs based on doped ceria electrolytes, Solid State Ionics 176, 1513-1520 (2005).
47. Y. Huang, J. M. Vohs and R. J. Gorte, Novel cathodes prepared by impregnation procedures, Electrochem. Soc. Proc. 07, 1735-1744 (2005). (Pubitemid 43176345)
48. Zh.Wang, M. Cheng, Y. Dong, M. Zhang and H. Zhang, Investigation of LSM1.1-ScSZ composite cathodes for anode-supported solid oxide fuel cells, Solid State Ionics 176, 2555-2561 (2005).
49. Y. J. Leng, S. H. Chan, K. A. Khor and S. P. Jiang, Performance evaluation of anode-supported solid oxide fuel cells with thin film YSZ electrolyte, Intl J. Hydrogen Energy 29, 1025-1033 (2004).