PVDF-based nanocomposite solid polymer electrolytes; The effect of affinity between PVDF and filler on ionic conductivity

Composite Interfaces

Volumn 16, Issue 4, 2009, Pages 347-358

  Lee, Yu Jin ^a   Jeong, Soo Kyeong ^a   Jo, Nam Ju ^a  

^a Pusan National University   (South Korea)

Author keywords

Filler effect; Ionic conductivity; Modified organoclay; Nanocomposite solid polymer electrolyte (nspe); Poly(vinylidene fluoride) (PVDF)

Indexed keywords

AC-IMPEDANCE; CLOISITE; FILLER EFFECT; FILLER EFFECTS; ION CONDUCTION; NANOCOMPOSITE SOLIDS; ORGANOCLAY CONTENT; ORGANOCLAY NANOCOMPOSITES; POLYVINYLIDENE FLUORIDES; ROOM TEMPERATURE; SILICATE LAYERS; STRUCTURAL CHANGE; XRD , TEM;

CONDUCTING POLYMERS; FILLERS; IONIC CONDUCTIVITY; IONS; NANOCOMPOSITES; ORGANOCLAY; POLYELECTROLYTES; POLYMERS; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); SOLID ELECTROLYTES;

IONIC CONDUCTION IN SOLIDS;

EID: 71649104880     PISSN: 09276440     EISSN: 15685543     Source Type: Journal    
DOI: 10.1163/156855409X450909     Document Type: Conference Paper

References (19)

1. M. Gauthier, A. Belanger, B. Kaper, G. Vasort and M. Armand, Polymer Electrolyte Reviews, Vol.2, p. 285. Elsevier, London, UK (1989).
2. F. M. Gray, Solid Polymer Electrolytes: Fundamentals and Technological Applications, p. 1. VCH Publishers, New York, USA (1991).
3. G. A. Nazri, Lithium Batteries: Science and Technology, p. 509. Kluwer Academic Publishers, New York, USA (2004).
4. J. Won, K. M. Lee, Y. S. Kang, S. K. Chang, C. K. Kim and C. K. Kim, Anion complexation by calyx[4]pyrrole in solid polymer electrolytes, Macromol. Res. 14, 404-407 (2006).
5. J. H. Ha, S. J. Yoon, D. Y. Jeong and Y. Cho, Selective poling and characterization of ferroelectric poly(vinylidene fluoridetrifluoroethylene) by scanning nonlinear dielectric microscopy, Macromol. Res. 15, 86-89 (2007).
6. C. C. Liang, Conduction characteristics of the lithium iodide-aluminum oxide solid electrolytes, J. Electrochem. Soc. 120, 1289-1292 (1973).
7. J. E. Weston and B. C. H. Steele, Effects of inert fillers on the mechanical and electrochemical properties of lithium salt-poly(ethylene oxide) polymer electrolytes, Solid State Ionics 7, 75-79 (1982).
8. F. Croce, G. B. Appetecchi, L. Persi and B. Scrosati, Nanocomposite polymer electrolytes for lithium batteries, Nature 394, 456-458 (1998).
9. B. Kumar and L. G. Scanlon, Polymer-ceramic composite electrolytes: conductivity and thermal history effects, Solid State Ionics 124, 239-254 (1999).
10. K. J. Hwang, J. W. Park, I. Kim, C. S. Ha and G. H. Kim, Effect of a compatibilizer on the microstructure and properties of partially biodegradable LDPE/aliphatic polyester/organoclay nanocomposites, Macromol. Res. 14, 179-186 (2006).
11. H. S. Choe, J. Giaccai, M. Alamgir and K. M. Abraham, Preparation and characterization of poly(vinyl sulfone)- and poly(vinylidene fluoride)-based electrolytes, Elecrochimica Acta 40, 2289-2293 (1995).
12. J. Y. Song, Y. Y. Wang and C. C. Wan, Review of gel-type polymer electrolytes for lithium-ion batteries, J. Power Sources 77, 183-197 (1999).
13. B. J. Cha and J. M. Yang, Effect of high-temperature spinning and PVP additive on the properties of PVDF hollow fiber membranes for microfiltration, Macromol. Res. 14, 596-602 (2006).
14. J. H. Park and S. C. Jana, Mechanism of exfoliation of nanoclay particles in epoxy-clay nanocomposites, Macromolecules 36, 2758-2768 (2003).
15. X. Dai, J. Xu, X. Guo, Y. Lu, D. Shen, N. Zhao, X. Luo and X. Zhang, Study on structure and orientation action of polyurethane nanocomposites, Macromolecules 37, 5615-5623 (2004).
16. H. M. Jeong, M. Y. Choi,M. S. Kim, J. H. An, J. S. Jung, J. H. Kim, B. K. Kim and S. Cho, Styrenic polymer/organoclay nanocomposite prepared via in situ polymerization with an azoinitiator linked to an epoxy oligomer, Macromol. Res. 14, 610-616 (2006).
17. C. R. Tseng, J. Y. Wu, H. Y. Lee and F. C. Chang, Preparation and crystallization behavior of syndiotactic polystyrene-clay nanocomposites, Polymer 42, 10063-10070 (2001).
18. W. Huang and R. Frech, Molecular structures and normal vibrations of trifluoromethane sulfonate (CF3SO3 ?) and its lithium ion pairs and aggregates, J. Phys. Chem. 98, 100-110 (1994).
19. D. L. Pavia, G. M. Lampman and G. S. Kriz, Introduction to Spectroscopy, p. 26. Harcourt College Publishers, Fort Worth, USA (2001).