Hydrogenation of sunflower oil over different palladium supported catalysts: Activity and selectivity

Chemical Engineering Journal

Volumn 155, Issue 3, 2009, Pages 941-949

  Fernández, María B ^a   Sánchez M , Jhon F ^a   Tonetto, Gabriela M ^a   Damiani, Daniel E ^a  

^a PLAPIQUI UNS CONICET   (Argentina)

Author keywords

Hydrogenation; Isomerization; Palladium; Sunflower oil; Trans isomers

Indexed keywords

ALUMINA-SUPPORTED; ATOMIC ABSORPTION SPECTROSCOPY; DIFFERENT PRECURSORS; DOUBLE BONDS; METAL LOADINGS; NI CATALYSTS; OPERATING CONDITION; PALLADIUM ACETYLACETONATE; PALLADIUM CATALYST; PALLADIUM NITRATE; PALLADIUM SUPPORTED CATALYSTS; PD CATALYST; SATURATED COMPOUNDS; SPECIFIC ACTIVITY; SUNFLOWER OIL; TEMPERATURE-PROGRAMMED REDUCTION; TRANS-ISOMERS; XRD;

ABSORPTION SPECTROSCOPY; ADSORPTION; ATMOSPHERIC TEMPERATURE; ATOMIC SPECTROSCOPY; CATALYSIS; CATALYST ACTIVITY; CATALYST SELECTIVITY; CHEMISORPTION; ELECTRON TRANSITIONS; FATTY ACIDS; HYDROGENATION; ISOMERIZATION; ISOMERS; NICKEL; PALLADIUM; PLANTS (BOTANY); TRANSMISSION ELECTRON MICROSCOPY; VEGETABLE OILS; ZEOLITES;

CATALYST SUPPORTS;

HELIANTHUS;

EID: 71649094497     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2009.09.037     Document Type: Article

References (30)

1. Coenen J. Hydrogenation of edible oils. J. Am. Oil Chem. Soc. 53 (1976) 382-389
2. Mozaffarian D., Rimm E., King I., Lawler R., McDonald G., and Levy W. Trans fatty acids and systemic inflammation in heart failure. Am. J. Clin. Nut. 80 (2004) 1521-1525
3. Han S., Leka L., Lichtenstein A., Ausman L., Schaefer E., and Meydani S. Effect of hydrogenated and saturated, relative to polyunsaturated, fat on immune and inflammatory responses of adults with moderate hypercholesterolemia. J. Lipid Res. 43 (2002) 445-452
4. Lee K.-W., Mei B., Bo Q., Kim Y.-W., Chung K.-W., and Han Y. Catalytic selective hydrogenation of soybean oil for industrial intermediates. J. Ind. Eng. Chem. 13 (2007) 530-536
5. Nohair B., Especel C., Lafaye G., Marecot P., Hoang L.C., and Barbier J. Palladium supported catalysts for the selective hydrogenation of sunflower oil. J. Mol. Catal. A 229 (2005) 117-126
6. Ray J. Behavior of hydrogenation catalysts. I. Hydrogenation of soybean oil with palladium. J. Am. Oil Chem. Soc. 62 (1985) 1213-1217
7. Santacesaria E., Parrella P., Di Sergio M., and Borrelli G. Role of mass transfer and kinetics in the hydrogenation of rapeseed oil on a supported palladium catalyst. Appl. Catal. A 116 (1994) 269-294
8. Plourde M., Belkacemi K., and Arul J. Hydrogenation of sunflower oil with novel catalysts supported on structured silica. Ind. Eng. Chem. Res. 43 (2004) 2382-2390
9. 3 catalysts (Me = Mo, V and Pb). J. Mol. Catal. A 233 (2005) 133-139
10. Fernández M., Tonetto G., Crapiste G., Ferreira M., and Damiani D. Hydrogenation of edible oil over Pd catalysts: a combined theoretical and experimental study. J. Mol. Catal. A 237 (2005) 67-79
11. Leofanti G., Padovan M., Tozzola G., and Venturelli B. Surface area and pore texture of catalysts. Catal. Today 41 (1998) 207-219
12. Horvath G., and Kawazoe K. Method for the calculation of effective pore size distribution in molecular sieve carbon. J. Chem. Eng. Jpn. 16 (1983) 470-475
13. Cheng L., and Yang R. Improved Horvath-Kawazoe equations including spherical pore models for calculating micropore size distribution. Chem. Eng. Sci. 49 (1994) 2599-2609
14. 3-supported PdMo catalysts. Appl. Catal. B 15 (1998) 115-127
15. 3 catalysts for the selective reduction of NO by methane. J. Mol. Catal. A 202 (2003) 289-303
16. La) in liquid-phase hydrogenation in a slurry reactor. Chem. Eng. Sci. 40 (1985) 2311-2319
17. Weisz P., and Prater D. Interpretation of measurements in experimental catalysis. Adv. Catal. 6 (1954) 143-196
18. Brunauer S., Deming L., Deming E., and Teller E. On a theory of the van der Waals adsorption of gases. J. Am. Chem. Soc. 62 (1940) 1723-1732
19. Lesage-Rosenberg E., Vlaic G., Dexpert H., Lagarde P., and Freund E. Exafs analysis of low-loaded palladium on alumina catalysts. Appl. Catal. 22 (1986) 211
20. 2 and alumina surfaces studied by XAS. Catal. Lett. 85 (2003) 25
21. Treacy M.M.J., Higgins J.B., and von Ballmoos R. Collection of Simulated XRD Powder Patterns for Zeolites. 3rd ed. (1996), Elsevier, Amsterdam
22. Hardenberg T., Mertens L., Mesman P., Muller H.C., and Nicolaides C.P. Zeolites 12 (1992) 685
23. Marques L.S., Monteiro J.L.F., and Pastore H.O. Micropor. Mesopor. Mater. 32 (1999) 131
24. Vasudevan S., Cosyns J., Lesage E., Freund E., and Dexpert H. Preparation of Catalysts III vol. 463 (1983), Jacobs Editors
25. 2. II. Effects of pretreatment on structure. J. Catal. 77 (1982) 421-431
26. Fogler H., and Scott L. Elements of Chemical Reaction Engineering. 3rd ed. (1999), Prentice Hall, New Jersey
27. Andersson K., Hell M., Löwendahl L., and Schöön N.-H. Diffusivities of hydrogen and glyceryl trioleate in cottonseed oil at elevated temperature. J. Am. Oil Chem. Soc. 51 (1974) 171-173
28. In: Swern D. (Ed). Bailey's Industrial Oil and Fat Products. 4th edition vol. 2 (1982)
29. Fernández M., Tonetto G., Crapiste G., and Damiani D. Revisiting the hydrogenation of sunflower oil over a Ni catalyst. J. Food Eng. 82 (2007) 199-208
30. Cook R. Thermally induced isomerism by deodorization. INFORM 13 (2002) 71-76