Catalytic decomposition of hydrogen iodide over pre-treated Ni/CeO2 catalysts for hydrogen production in the sulfur-iodine cycle

International Journal of Hydrogen Energy

Volumn 34, Issue 21, 2009, Pages 8792-8798

  Zhang, Yanwei ^a   Wang, Zhihua ^a   Zhou, Junhu ^a   Liu, Jianzhong ^a   Cen, Kefa ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Hydrogen iodide; Hydrogen production; Ni CeO2; Redox treatment; Sulfur iodine cycle

Indexed keywords

ACTIVE SITE; CATALYTIC ACTIVITY; CATALYTIC DECOMPOSITION; DIFFUSION PROCESS; HYDROGEN IODIDE; OXIDIZATION; REDOX TREATMENTS; STRUCTURE AND PERFORMANCE; SULFUR IODINES; SULFUR-IODINE CYCLES; SURFACE SITES; XPS; XRD , TEM;

CATALYSIS; CATALYSTS; CERIUM; CERIUM COMPOUNDS; GAS PRODUCERS; HYDROGEN PRODUCTION; INDUSTRIAL CHEMICALS; IODINE; NICKEL; OXYGEN; SULFUR; VACANCIES;

OXYGEN VACANCIES;

EID: 71549141671     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2009.08.058     Document Type: Article

References (25)

1. Russell Jr JL, McCorkle KH, Norman JH, Porter II JT, Roemer TS, Schuster JR, et al. Water splitting - a progress report. Proc 1st World Hydrogen Energy Conf, Miami Beach, U.S.A., 1A105-1A124, 1-3 March, 1976.
2. Norman JH, Besenbruch GE, Brown LC. Thermochemical water-splitting cycle, bench-scale investigation and process engineering. GA-A16713, 1982.
3. 2 solution. Int J Hydrogen Energy 14 (1989) 545-549
4. Kubo S., Nakajima H., Kasahara S., Higashi S., Masaki T., Abe H., et al. A demonstration study on a closed-cycle hydrogen production by the thermochemical water-splitting iodine-sulfur process. Nucl Eng Des 233 (2004) 347-354
5. Kubo S., Kasahara S., Okuda H., Erada A., Tanaka N., Inaba Y., et al. A pilot test plan of the thermochemical water-splitting iodine-sulfur process. Nuclear Engineering and Design 233 (2004) 355-362
6. Nomura M., Kasahara S., and Nakao S. Silica membrane reactor for the thermochemical iodine-sulfur process to produce hydrogen. Ind Eng Chem Res 43 18 (2004) 5874-5879
7. Hwang G.J., and Onuki K. Simulation study on the catalytic decomposition of hydrogen iodine in a membrane reactor with a silica membrane for the thermochemical water-splitting IS process. J Membr Sci 194 (2001) 207-215
8. Goldstein S., Borgard J.M., and Vitart X. Upper bound and best estimate of the efficiency of the iodine sulphur cycle. Int J Hydrogen Energy 30 6 (2005) 619-626
9. Zhou J.H., Zhang Y.W., Wang Z.H., Yang W.J., Zhou Z.J., Liu J.Z., et al. Thermal efficiency evaluation of open-loop SI thermochemical cycle for the production of hydrogen, sulfuric acid and electric power. Int J Hydrogen Energy 32 (2007) 567-575
10. Zhang Y.W., Zhou J.H., Wang Z.H., and Cen K.F. Detailed kinetic modeling and sensitivity analysis of hydrogen iodide decomposition in sulfur-iodine cycle for hydrogen production. Int J Hydrogen Energy 33 (2008) 627-632
11. Funk J.E. Thermochemical hydrogen production: past ang present. Int J Hydrogen Energy 26 (2001) 185-190
12. O'Keefe D.R., Norman J.H., and Williamson D.G. Catalysis research in thermochemical water-splitting processes. Catal Rev Sci Eng 22 3 (1980) 325-369
13. Oosawa Y., Kumagai T., Mizuta S., Kondo W., Takemori Y., and Fujii K. Kinetics of the catalytic decomposition of hydrogen iodide in the magnesium-iodine thermochemical cycle. Bull Chem Soc Jpn 54 (1981) 742-748
14. Shindo Y., Ito N., and Haraya K. Kinetics of the catalytic decomposition of hydrogen iodide in the thermochemical hydrogen production. Int J Hydrogen Energy 9 (1984) 695-700
15. Zhang Y.W., Wang Z.H., Zhou J.H., Liu J.Z., and Cen K.F. Effect of preparation method on platinum-ceria catalysts for hydrogen iodide decomposition in sulfur-iodine cycle. Int J Hydrogen Energy 33 (2008) 602-607
16. Favuzza P., Felici C., Lanchi M., Liberatore R., Mazzocchia C.V., Spadoni A., et al. Decomposition of hydrogen iodide in the S-I thermochemical cycle over Ni catalyst systems. Int J Hydrogen Energy (2008) 10.1016/j.ijhydene.2008.07.076
17. Zhang Y.W., Zhou J.H., Chen Y., Wang Z.H., Liu J.Z., and Cen K.F. Hydrogen iodide decomposition over nickel-ceria catalysts for hydrogen production in the sulfur-iodine cycle. Int J Hydrogen Energy 33 (2008) 5477-5483
18. Holmgren A., Azarnoush F., and Fridell E. Influence of pre-treatment on the low-temperature activity of Pt/ceria. Appl Catal B 22 (1999) 49-61
19. 2 catalyst. Appl Surf Sci 245 (2005) 162-171
20. Bozo C., Guilhaume N., and Herrmann J.M. Role of the ceria-zirconia support in the reactivity of platinum and palladium catalysts for methane total oxidation under lean conditions. J Catal 203 (2001) 393-406
21. 2 (NM: noble metal) catalysts. Catal Today 50 (1999) 175-206
22. Ndifor E.N., Garcia T., Solsona B., and Taylor S.H. Influence of preparation conditions of nano-crystalline ceria catalysts on the total oxidation of naphthalene, a model polycyclic aromatic hydrocarbon. Appl Catal B 76 (2007) 248-256
23. 2. J Catal 248 (2007) 258-267
24. 2 catalysts. J Rare Earth 26 (2008) 66-70
25. 2 catalysts: effect of nickel content. Appl Catal A 226 (2002) 63-72