Modelling of transient kinetics in catalytic three-phase reactors: Enantioselective hydrogenation

Chemical Engineering Science

Volumn 65, Issue 3, 2010, Pages 1076-1087

  Toukoniitty, Esa ^a   Wärnå, Johan ^a   Murzin, Dmitry Yu ^a   Salmi, Tapio ^a  

^a LABORATORY OF INDUSTRIAL CHEMISTRY AND REACTION ENGINEERING   (Finland)

Author keywords

Enantioselective hydrogenation; Heterogenous catalysis; Modelling; Three phase; Transient kinetics

Indexed keywords

ADSORPTION DESORPTION; CATALYST STABILITY; CATALYTIC TRANSFORMATION; CHARACTERISATION; DYNAMIC BEHAVIOURS; ENANTIOSELECTIVE; ENANTIOSELECTIVE HYDROGENATION; ETHYL BENZOYLFORMATE; FIXED BED; GAS PHASE PROCESS; HETEROGENOUS CATALYSIS; KINETIC EXPERIMENT; LIQUID PHASE; ORGANIC REACTION; ORGANIC SYSTEMS; PHASE TRANSIENT; SUPPORTED PT; SURFACE SPECIES; THREE PHASE REACTOR; THREE PHASE SYSTEM; TRANSIENT CONDITIONS; TRANSIENT EXPERIMENTS; TRANSIENT KINETICS; TRANSIENT TECHNIQUES;

ADSORPTION; CATALYSIS; CATALYSTS; DESORPTION; EXPERIMENTS; FLOW PATTERNS; HYDROGENATION; PLATINUM; PLATINUM COMPOUNDS;

MATHEMATICAL MODELS;

EID: 71549124326     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.09.062     Document Type: Article

References (29)

1. Bennett C.O. The transient method and elementary steps in heterogeneous catalysis. Catal. Rev. Sci. Eng. 13 (1976) 121-148
2. Bennett C.O. Experiments and processes in the transient regime for heterogeneous catalysis. Adv. Catal. 44 (1999) 329-416
3. Berger R.J., Kapteijn F., Moulijn J.A., Marin G.B., De Wilde J., Olea M., Chen D., Holmen A., Lietti L., Tronconi E., and Schuurman Y. Dynamic methods for catalytic kinetics. Appl. Catal. A. Gen. 342 (2008) 3-28
4. Blaser H.-U., Jalett H.P., Monti D.M., Baiker A., and Wehrli J.T. Enantioselective hydrogenation of ethyl pyruvate: effect of catalyst and modifier structure. Stud. Surf. Sci. Catal. 67 (1991) 147-155
5. 3 hydrogenation catalyst. J. Phys. Chem. C 111 (2007) 9374-9383
6. Busygin I., Toukoniitty E., Leino R., and Murzin D.Yu. Effect of modifier structure in asymmetric 1-phenylpropane-1,2-dione hydrogenation. J. Mol. Catal. A. Chem. 236 (2005) 227-238
7. Caravielhes S., Schweich D., and de Bellefon C. Transient operation of a catalytic liquid-liquid plug flow reactor for kinetic measurements. Chem. Eng. Sci. 57 (2002) 2697-2705
8. Chorkendorff I., and Nimentsverdriet J.W. Concepts of Modern Catalysis and Kinetics (2003), Wiley-VCH, Weinheim
9. Haario, H., 2007. Modest 6.0-a User's guide, ProfMath, Helsinki.
10. Hindmarsh, A. C., 1983. ODEPACK, A Systematized Collection of ODE Solvers. In: Stepleman, R. S., et al. (Eds.), Scientific Computing, North-Holland, Amsterdam (vol. 1 of IMACS Transactions on Scientific Computation), pp. 55-64.
11. Kangas M., Salmi T., and Murzin D. Skeletal isomerization of butene in fixed beds. Part 2. kinetic and flow modeling. Ind. Eng. Chem. Res. 47 (2008) 5413-5426
12. Kobayashi H., and Kobayashi M. Transient response method in heterogeneous catalysis. Catal. Rev. Sci. Eng. 10 (1974) 139-176
13. Kobayashi M. Characterization of transient response curves in heterogeneous catalysis-I classification of the curves. Chem. Eng. Sci. 37 (1982) 393-401
14. Mikkola J.-P., Vainio H., Salmi T., Sjöholm R., Ollonqvist T., and Väyrynen J. Deactivation kinetics of Mo-promoted Raney Ni catalyst in the hydrogenation of xylose to xylitol. Appl. Catal. A. General 196 (2000) 143-155
15. Murzin D., and Salmi T. Catalytic Kinetics (2005), Elsevier
16. Salmi T. Modelling and simulation of transient states of ideal heterogeneous catalytic reactors. Chem. Eng. Sci. 43 (1988) 503-511
17. Salmi T., Murzin D., Mikkola J.-P., Wärnå J., Mäki-Arvela P., Toukoniitty E., and Toppinen S. Advanced kinetic concepts and experimental methods for catalytic three-phase processes. Ind. Eng. Chem. Res. 43 (2004) 4540-4550
18. Sandelin F., Salmi T., and Murzin D.Yu. Dynamic modelling of catalyst deactivation in fixed-bed reactors: skeletal isomerization of 1-pentene on ferrierite. Ind. Eng. Chem. Res. 45 (2006) 558-566
19. Sandelin F., Oinas P., Salmi T., Paloniemi J., and Haario H. Dynamic modelling of catalytic liquid-phase reactions in fixed beds-kinetics and catalyst deactivation. Chem. Eng. Sci. 61 (2006) 4528-4539
20. Schürch M., Schwalm O., Mallat T., Weber J., and Baiker A. Enantioselective hydrogenation of ketopantolactone. J. Catal. 169 (1997) 275-286
21. Silveston P.L., and Hanika J. Periodic operation of three-phase catalytic reactors. Can. J. Chem. Eng. 82 (2004) 1105-1142
22. 3 catalysts in the acetic acid. Catal. Commun. 3 (2002) 125-127
23. Toukoniitty B., Kangas M., Wärnå J., Kuusisto J., Mikkola J.-P., Toukoniitty E., Salmi T., and Murzin D. Suppression of catalyst deactivation by acoustic irradiation-kinetic approach. Chem. Today 24 (2006) 62-65
24. 2 fibers. Appl. Catal. A. General 216 (2001) 73-83
25. Toukoniitty E., Mäki-Arvela P., Kuzma M., Villela A., Kalantar Neyestanaki A., Salmi T., Sj öholm R., Leino R., Laine E., and Murzin D.Yu. Enantio-selective hydrogenation of 1-Phenyl-1,2-propanedione. J. Catal. 204 (2001) 281-291
26. Toukoniitty E., Mäki-Arvela P., Kalantar Neyestanaki A., Salmi T., and Murzin D. Continuous hydrogenation of 1-phenyl-1,2-propanedione under transient and steady-state conditions: regioselectivity, enantioselectivity and catalyst deactivation. Appl. Catal. A. General 235 (2002) 125-138
27. Toukoniitty E., Wärnå J., Salmi T., Mäki-Arvela P., and Murzin D. Application of transient methods in three-phase catalysis: hydrogenation of a dione in a catalytic plate column. Catal. Today 79-80 (2003) 383-389
28. Toukoniitty E., Ševčíkovà B., Mäki-Arvela P., Wärnå J., Salmi T., and Murzin D.Yu. Kinetics and modeling of 1-phenyl-1,2-propanedione hydrogenation. J. Catal. 213 (2003) 7-16
29. 3 catalyst: bed dilution effects and cinchonidine adsorption study. Catal. Lett. 95 (2004) 179-183