From hydrogenases to noble metal-free catalytic nanomaterials for H 2 production and uptake

Science

Volumn 326, Issue 5958, 2009, Pages 1384-1387

  Goff, Alan Le ^a   Artero, Vincent ^b   Jousselme, Bruno ^a   Tran, Phong Dinh ^b   Guillet, Nicolas ^c   Métayé, Romain ^a   Fihri, Aziz ^b   Palacin, Serge ^a   Fontecave, Marc ^b,d  

^a DIF   (France)

^b UNIV GRENOBLE ALPES   (France)

^c CEA GRENOBLE   (France)

^d l'alimentation et l'Environnement   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON NANOTUBE; HYDROGEN; HYDROGENASE; NICKEL BISDIPHOSPHINE; PHOSPHINE DERIVATIVE; PROTON; SULFURIC ACID; UNCLASSIFIED DRUG;

ACIDIFICATION; ACIDOPHILY; CATALYSIS; FUEL CELL; HEAVY METAL; HYDROGEN; OXIDATION; PLATINUM; SOLAR POWER; WIND POWER;

ACIDITY; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; COVALENT BOND; CYCLIC POTENTIOMETRY; DENSITY; ELECTRIC POTENTIAL; ELECTRODE; OXIDATION; PRIORITY JOURNAL;

BIOMIMETIC MATERIALS; CATALYSIS; CATALYTIC DOMAIN; ELECTROCHEMICAL TECHNIQUES; ELECTRODES; HYDROGEN; HYDROGEN-ION CONCENTRATION; HYDROGENASE; LIGANDS; NANOTUBES, CARBON; NICKEL; OXIDATION-REDUCTION; PHOSPHINES; PROTONS; SULFURIC ACIDS;

EID: 71549116117     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1179773     Document Type: Article

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33. This work was supported by the CEA (Nanosciences program, grant Grafthydro), the CNRS ("Materials" program, grant 961 "projets exploratoires; Interface Science des Matériaux/Vivant") and the Agence Nationale de la Recherche (PAN-H 2008, EnzHyd). The authors thank E. Mayousse and P.-A. Jacques for experimental contribution and V. Derycke for assistance in the SEM characterizations. The authors have filed a European patent application (EP-08 290 988.8) for the grafting procedure of catalysts presented here.