Investigation of the State of Bis(2,4,4-Trimethylpentyl)dithiophosphinic Acid in Nonane and Toluene Solutions

Solvent Extraction and Ion Exchange

Volumn 27, Issue 5-6, 2009, Pages 745-760

  Grigorieva, N A ^a   Pavlenko, N I ^a   Pleshkov, M A ^b   Pashkov, G L ^a   Fleitlikh, I Yu ^a  

^a INSTITUTE OF CHEMISTRY AND CHEMICAL TECHNOLOGY   (Russian Federation)

^b Gipronikel Institute   (Russian Federation)

Author keywords

Bis(2,4,4 trimethylpentyl)dithiophosphinic acid; Liquid liquid extraction

Indexed keywords

AROMATIC DILUENTS; AROMATIC RINGS; CONCENTRATION OF; CONCENTRATION RANGES; ELECTRON SYSTEMS; EXTRACTANTS; FORMATION CONSTANTS; IR SPECTROSCOPY; LIQUID-LIQUID EXTRACTION; SELF-ASSOCIATIONS; TETRAMERS; TOLUENE SOLUTION;

AROMATIC COMPOUNDS; ASSOCIATION REACTIONS; BINDING SITES; FLUORINE CONTAINING POLYMERS; HYDROGEN BONDS; LIQUIDS; OLIGOMERS; ORGANIC ACIDS; SPECTROSCOPIC ANALYSIS; TOLUENE;

SOLVENT EXTRACTION;

EID: 70749133260     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290903113983     Document Type: Article

References (25)

1. ® Extractant, 2007, Technical Brochure, CYTEC Industries Inc.
2. ®) in acidic liquid-liquid extraction systems. Solvent extraction in the process industries. Proceedings of the ISEC 993, York, UK, 1993, vol. 1, pp. 557-564.
3. Mihaylov, I.; Krause, E.; Colton, D.F.; Okita, Y.; Duterque, J.-P.; Perraud, J.-J. The development of a novel hydrometallurgical process for nickel and cobalt recovery from Goro laterite ore. CIM Bulletin 2000, 93(1041), 124-130.
4. Rickelton, W.A.; Boyle, R.J. The selective recovery of zinc with new thiophosphinic acids. Solvent Extr. Ion Exch. 1990, 8(6), 783-797.
5. Ionova, G.; Ionov, S.; Rabbe, C.; Hill, C.; Madic, C.; Guillaumont, R.; Krupa, C. Mechanism of trivalent actinide/lanthanide separation using bis(2,4,4-trimethylpentyl) dithiophosphinic acid (Cyanex 301) and neutral o-bearing co-extractant synergistic mixtures. Solvent Extr. Ion Exch. 2001, 19(3), 391-414.
6. Sole, K.C.; Hiskey, J.B. Solvent extraction characteristics of thiosubstituted organophosphinic acid extractants. Hydrometallurgy 1992, 30, 345-365.
7. Tait, B.K. Cobalt-nickel separation the extraction of cobalt (II) and nickel (II) by Cyanex 301, Cyanex 302 and Cyanex 272. Hydrometallurgy 1993, 32, 365-372.
8. Tsakiridis, P.E.; Agatzini, S.L. Simultaneous solvent extraction of cobalt and nickel in the presence of manganese and magnesium from sulfate solutions by Cyanex 301. Hydrometallurgy 2004, 72(3-4), 269-278.
9. Van de Voorde, I.; Pinoy, L.; Courtijn, E.; Verpoort, F. Equilibrium studies of nickel(II), copper(II), and cobalt(II) extraction with Aloxime 800, D2EHPA, and Cyanex reagents. Solvent Extr. Ion Exch. 2006, 24, 893-914.
10. Pashkov, G.L.; Grigorieva, N.A.; Pavlenko, N.I.; Fleitlikh, I.Yu.; Nikiforova, L.K. Nickel(II) extraction from sulfate media with bis(2,4,4-trimethylpentil)dithiophosphinic acid dissolved in nonane. Solvent Extr. Ion Exch. 2008, 26(6), 749-763.
11. ® 301. Proceedings of the ISEC 2002, South Africa, Johannesburg, 2002, 291-298.
12. Almela, A.; Elizalde, M.P. Interactions of metal extractant reagents. Part VIII. Comparative aggregation equilibria of Cyanex 302 and Cyanex 301 in heptane. Analytical Proceedings including Analytical Communications. 1995, 32, 145-147.
13. Chen, J.; Jiao, R. and Zhu, Y. Purification of Cyanex 301 and its property. Chinese J. Applied Chem. 1996, 13(2), 45-48.
14. Jensen, M.P. and Bond, A.H. Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301, and Cyanex 302. Radiochimical. 2002, 90(4), 205-209.
15. Sole, K.C.; Hiskey, J.B. Solvent extraction of copper with Cyanex 272, Cyanex 302, and Cyanex 301. Hydrometallurgy 1995, 37(2), 345-367.
16. Jensen, M.P.; Chiarizia, R.; Urban, V. Investigation of the aggregation of the neodymium complexes of dialkylphosphoric, oxothiophosphinic, and dithiophosphinic acids in toluene. Solvent Extr. Ion Exch. 2001, 19(5), 865-884.
17. Zhu, Y.; Chen, J.; Jiao, R. Extraction of Am (III) and Eu (III) from Nitrate Solution with Purified Cyanex 301. Solvent Extr. Ion Exch. 1996, 14(1), 61-68.
18. Burg, C.; Knowles, A. Technical Invisible and Ultraviolet Spectrometry. Vol. 1 - Standards in Absorption Spectrometry; Chapman and Hall Ltd.: London, 1981.
19. Vilkov L.V.; Pentin Yu. A. Physical Methods of Investigation in Chemistry. Structural Methods and Optical Spectroscopy; Vysshaya Shkola: Moscow, 1987, 367 p.
20. Allen, G.; Colclough, R.O. Hydrogen bonding of the thiol group in phosphinodithioic acids. J. Chem. Soc. 1957, 9, 3912-3915.
21. Shagidullin, R.R.; Lipatova, I.P.; Vachugova, L.I; Cherkasov, R.A.; Khairutdinova, F.Kh. Hydrogen bonding in dithioic acids of V valency phosphorous. Proceedings of the Academy of Sciences of the USSR. Chemical Sciences Series 1972, 4, 847-850.
22. Shagidullin, R.R., Lipatova, I.P.; Rayevskiy, O.A.; Vachugova, L.I.; Cherkasov, R.A. Hydrogen bonding in dithioic acids of V valency phosphorous. Communication 2. Intermolecular H-bonds and conformation of dithioacid molecules. Proceedings of the Academy of Sciences of the USSR. Chemical Sciences Series 1973, 3, 541-545.
23. Pogoreliy, V.K.; Kukhtenko, I.I.; Divnich, T.F. Investigation of selfassociation of dithioacids of phosphorous using NMR method. Theoretical and experimental chemistry. 1975, 11(2), 242-248.
24. Prigozhin, I.; Defey, R. Chemical Thermodynamics; Elsevier "Nauka," Siberian Branch of the RAS, Novosibirsk, 1966, 511 p.
25. Rodina, T.F.; Varentsova, V.I.; Kolyshev, A.N.; Levin, I.S. Determination of the associations distribution and acid dissociation constants of di-2-ethylhexyl-phosphorodithoic acid in some diluent. Proceedings of the Siberian Branch of the Academy of Sciences of the USSR. Chemical Sciences Series 1973, 6(14), 14-18.