The solid-liquid phase diagrams of binary mixtures of even saturated fatty acids differing by six carbon atoms

Thermochimica Acta

Volumn 496, Issue 1-2, 2009, Pages 30-37

  Costa, Mariana C ^a,c   Rolemberg, Marlus P ^b   Meirelles, Antonio J A ^a   Coutinho, João A P ^c   Krahenbuhl M A ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

^b FEDERAL UNIVERSITY OF MARANHÃO   (Brazil)

^c UNIVERSITY OF AVEIRO   (Portugal)

Author keywords

DSC; Phase diagram; Polarized light microscopy; Saturated fatty acids; Solid liquid equilibrium

Indexed keywords

BIOCHEMICAL MOLECULES; CAPRIC ACID; CAPRYLIC ACID; CARBON ATOMS; CARBON CHAINS; EUTECTIC REACTIONS; INDUSTRIAL PRODUCTION; LAURIC ACID; LIQUIDUS LINES; MYRISTIC ACID; PALMITIC ACID; PERITECTIC; POLARIZED LIGHT MICROSCOPY; SATURATED FATTY ACID; SATURATED FATTY ACIDS; SOLID LIQUID EQUILIBRIUM; SOLID-LIQUID PHASE DIAGRAMS; SOLID-SOLID PHASE TRANSITIONS;

ACIDS; BINARY MIXTURES; DIFFERENTIAL SCANNING CALORIMETRY; GRAPHIC METHODS; LIGHT POLARIZATION; LIQUIDS; PHASE TRANSITIONS; STEARIC ACID;

PHASE DIAGRAMS;

EID: 70549106964     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2009.06.018     Document Type: Article

References (30)

1. Karleskind A. Oils & Fats Manual: A Comprehensive Treatise, Properties, Production, Applications (1996), Lavoisier Publishing, Paris
2. Falk O., and Meyer-Pittroff R. The effect of fatty acid composition on biodiesel oxidative stability. Eur. J. Lipid Sci. Technol. 106 12 (2004) 837-843
3. Meher L.C., Sagar D.V., and Naik S.N. Technical aspects of biodiesel production by transesterification-a review. Renew. Sust. Energ. Rev. 10 3 (2006) 248-268
4. Johnson R.W., and Fritz E. Fatty Acids in Industry: Processes, Properties, Derivatives, Applications (1989), Marcel Dekker, Nova York
5. Zhang J.J., Zhang J.L., He S.M., Wu K.Z., and Liu X.D. Thermal studies on the solid-liquid phase transition in binary systems of fatty acids. Thermochim. Acta 369 1-2 (2001) 157-160
6. Shilei L., Neng Z., and Guohui F. Eutectic mixtures of capric acid and lauric acid applied in building wallboards for heat energy storage. Energy Buildings 38 (2006) 708-711
7. Garti N., and Sato K. Crystallization and Polymorphism of Fats and Fatty Acids (1989), Marcel Dekker, New York
8. Vand V., Morley W.M., and Lomer T.R. The crystal structure of lauric acid. Acta Crystallogr. 4 4 (1951) 324-329
9. Holland R.F., and Nielsen J.R. A new crystal form of fatty acids. Acta Crystallogr. 16 9 (1963) 902-906
10. Lomer T.R. Crystal and molecular structure of lauric acid (Form a1). Acta Crystallogr. 16 10 (1963) 984-988
11. Goto M., and Asada E. Crystal-structure of a-super form of lauric acid. Bull. Chem. Soc. Jpn. 51 1 (1978) 70-74
12. Goto M., and Asada E. Crystal-structure of B-form of stearic-acid. Bull. Chem. Soc. Jpn. 51 9 (1978) 2456-2459
13. Kaneko F., Kobayashi M., Kitagawa Y., and Matsuura Y. Structure of stearic-acid E-form. Acta Crystallogr. C 46 (1990) 1490-1492
14. Moreno E., Cordobilla R., Calvet T., Cuevas-Diarte M.A., Gbabode G., Negrier P., Mondieig D., and Oonk H.A.J. Polymorphism of even saturated carboxylic acids from n-decanoic to n-eicosanoic acid. New J. Chem. 31 (2007) 947-957
15. Boodhoo M.V., Kutek T., Filip V., and Narine S.S. The binary phase behavior of 1,3-dimyristoyl-2-stearoyl-sn-glycerol and 1 2-dimyristoyl-3-stearoyl-sn-glycerol. Chem. Phys. Lipids 154 1 (2008) 7-18
16. Boodhoo M.V., Bouzidi L., and Narine S.S. The binary phase behavior of 1,3-dicaproyl-2-stearoyl-sn-glycerol and 1 2-dicaproyl-3-stearoyl-sn-glycerol. Chem. Phys. Lipids 157 1 (2009) 21-39
17. Chapman D. Polymorphism of glycerides. Chem. Rev. 62 5 (1962) 433-456
18. Timms R.E. Phase behaviour of fats and their mixtures. Prog. Lipid Res. 23 (1984) 1-38
19. Sato K., Ueno S., and Yano J. Molecular interactions and kinetic properties of fats. Prog. Lipid Res. 38 1 (1999) 91-116
20. Sato K. Crystallization behaviour of fats and lipids-a review. Chem. Eng. Sci. 56 (2001) 2255-2265
21. Bailey A.E. Melting and Solidification of Fats (1950), Interscience Publishers, New York
22. Small D.M. Physical Chemistry of Lipids: From Alkanes to Phospholipids (1986), Plenum Press, New York and London
23. Inoue T., Hisatsugu Y., Ishikawa R., and Suzuki M. Solid-liquid phase behavior of binary fatty acid mixtures. 2. Mixtures of oleic acid with lauric acid, myristic acid, and palmitic acid. Chem. Phys. Lipids 127 2 (2004) 161-173
24. Inoue T., Hisatsugu Y., Suzuki M., Wang Z., and Zheng L. Solid-liquid phase behavior of binary mixtures 3 Mixtures of oleic acid with capric acid (decanoic acid) and caprylic acid (octanoic acid). Chem. Phys. Lipids 132 (2004) 225-234
25. Inoue T., Hisatsugu Y., Yamamoto R., and Suzuki M. Solid-liquid phase behavior of binary fatty acid mixtures. 1. Oleic acid stearic acid and oleic acid behenic acid mixtures. Chem. Phys. Lipids 127 2 (2004) 143-152
26. Costa M.C., Rolemberg M.P., Boros L.A.D., Krähenbühl M.A., Oliveira M.G., and Meirelles A.J.A. Solid-liquid equilibrium of binary fatty acids mixtures. J. Chem. Eng. Data 52 (2007) 30-36
27. Costa M.C., Sardo M., Rolemberg M.P., Coutinho J.A.P., Meirelles A.J.A., Ribeiro-Claro P., and Krähenbühl M.A. The solid-liquid phase diagrams of binary mixtures of consecutive, even saturated fatty acids. Chem. Phys. Lipids 160 (2009) 85-97
28. Costa M.C., Sardo M., Rolemberg M.P., Coutinho J.A.P., Meirelles A.J.A., Ribeiro-Claro P., and Krähenbühl M.A. The solid-liquid phase diagrams of binary mixtures of consecutive, even saturated fatty acids: differing by four carbon atoms. Chem. Phys. Lipids 157 (2009) 40-50
29. Gbabode G., Negrier P., Mondieig D., Moreno E., Calvet T., and Cuevas-Diarte M.A. Polymorphism and solid-state miscibility in the pentadecanoic acid-heptadecanoic acid binary system. Chem. Phys. Lipids 154 1 (2008) 68-77
30. Gbabode G., Negrier P., Mondieig D., Moreno E., Calvet T., and Cuevas-Diarte M.A. Fatty acids polymorphism and solid-state miscibility pentadecanoic acid-hexadecanoic acid binary system. J. Alloys Compd. 469 1-2 (2009) 539-551