Modeling the effect of species retention on the band broadening in perfectly ordered silica monolithic column mimics with variable external porosity and intra-skeleton diffusivity

Journal of Separation Science

Volumn 32, Issue 15-16, 2009, Pages 2707-2722

  Detobel, Frederik ^a   Gzil, Piotr ^a   Desmet, Gert ^a  

^a VRIJE UNIVERSITEIT BRUSSEL   (Belgium)

Author keywords

Computational fluid dynamics; Geometrical parameters; Mass transfer; Plate height; Van Deemter equation

Indexed keywords

3D MODELS; ANALYTES; BAND-BROADENING; COMPUTATIONAL FLUID DYNAMICS SIMULATIONS; DEGREE OF ORDER; DIFFUSIVITIES; GEOMETRICAL PARAMETERS; MATHEMATICAL EXPRESSIONS; MOBILE-PHASE VELOCITY; MODELING PROBLEMS; PARAMETER FITTING; PARAMETER VALUES; PLATE HEIGHT; PORE DIAMETERS; RETENTION FACTORS; SHAPE FACTOR; SILICA MONOLITHIC COLUMN; SILICA MONOLITHS; TEST CASE; VAN DEEMTER EQUATION;

CHROMATOGRAPHIC ANALYSIS; COMPUTATIONAL FLUID DYNAMICS; DIFFUSION; FLUID DYNAMICS; PARAMETER ESTIMATION; PLATES (STRUCTURAL COMPONENTS); SILICA; SIMULATORS;

THREE DIMENSIONAL;

SILICON DIOXIDE;

ACCURACY; ALGORITHM; ARTICLE; CHROMATOGRAPHY; COMPUTATIONAL FLUID DYNAMICS; COMPUTER PROGRAM; COMPUTER SIMULATION; CONTROLLED STUDY; DIFFUSION; GEOMETRY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MATHEMATICAL ANALYSIS; MATHEMATICAL MODEL; PARAMETER; POROSITY; PRIORITY JOURNAL; SEPARATION TECHNIQUE; THREE DIMENSIONAL IMAGING;

EID: 70549106174     PISSN: 16159306     EISSN: 16159314     Source Type: Journal    
DOI: 10.1002/jssc.200900222     Document Type: Article

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