Characteristics of permanganate oxidation of TCE at low reagent concentrations

Environmental Technology

Volumn 30, Issue 13, 2009, Pages 1337-1342

  Woo, N C ^a   Hyun, S G ^a   Park, W W ^a   Lee, E S ^b   Schwartz, F W ^c  

^a Yonsei University   (South Korea)

^b OHIO UNIVERSITY   (United States)

^c OHIO STATE UNIVERSITY   (United States)

Author keywords

Controlled release system; DNAPL; Groundwater; KMnO4; Remediation

Indexed keywords

GROUNDWATER; HYDROGEOLOGY; ORGANIC COMPOUNDS; OXIDATION; POLLUTION; REMOVAL;

BATCH EXPERIMENTS; CHLORINATED SOLVENT; CONTROLLED RELEASE; CONTROLLED RELEASE SYSTEM; CONTROLLED RELEASE SYSTEMS; CONVERSION RATES; DNAPL; GROUNDWATER PLUMES; INORGANIC IONS; LOW CONCENTRATIONS; LOW LEVEL; MOLAR RATIO; PERCHLOROETHYLENE; PERMANGANATE OXIDATION; POTASSIUM PERMANGANATE; REAGENT CONCENTRATION; REMOVAL EFFICIENCIES; REMOVAL RATE; TCE OXIDATION;

TRICHLOROETHYLENE;

CHLORIDE; GROUND WATER; PERMANGANATE POTASSIUM; REAGENT; SOLVENT; TETRACHLOROETHYLENE; TRICHLOROETHYLENE;

CONCENTRATION (COMPOSITION); EXPERIMENTAL STUDY; GROUNDWATER POLLUTION; OXIDATION; PLUME; POLLUTANT REMOVAL; POTASSIUM;

ARTICLE; BATCH FERMENTATION; CHEMICAL PROCEDURES; CHLORINATION; EXPERIMENT; OXIDATION; PLUME;

EID: 70450233766     PISSN: 09593330     EISSN: 1479487X     Source Type: Journal    
DOI: 10.1080/09593330902840342     Document Type: Article

References (21)

1. R. Stewart, Oxidation by permanganate, in Oxidation in Organic Chemistry, K.B. Wiberg, ed., Academic Press, New York, 1965, pp. 1-68.
2. E.S. Lee, Y. Seol, Y.C. Fang, and F.W. Schwartz, Destruction efficiencies and dynamics of reaction fronts associated with the permanganate oxidation of trichloroethvlene, Environ. Sci. Technol. 37 (2003), pp. 2540-2546.
3. R.L. Siegrist, M.A. Urynowicz, and O.R. West, In situ chemical oxidation for remediation of contaminated soil and ground water, Ground Water Currents 37, EPA 542-N-00-006, US Environmental Protection Agency, Office of Solid Waste and Emergency Response, Washington DC, 2000.
4. P.A. Vella, G. Deshinsky, J.E. Boll, J. Munder, and W.M. Joyce, Treatment of low level phenols with potassium permanganate, J. Water Pollut. Control Fed. 62 (1990), pp. 907-914.
5. P.A. Vella and B. Veronda, Oxidation of trichloroethylene: A comparison of potassium permanganate and Fenton 's reagent, in In Situ Chemical Oxidation For The Nineties, 3, Technomic, Lancaster, PA, 1994, pp. 62 73.
6. D.D. Gates and R.L. Siegrist, In situ chemical oxidation of trichloroethylene using hydrogen peroxide, J. Environ. Eng. 121 (1995), pp. 639-644.
7. D.D. Gates, R.L. Siegrist, and S.R. Cline, Comparison of potassium permanganate and hydrogen peroxide as chemical oxidants for organically contaminated soils, J. Environ. Eng. 127 (2001), pp. 337-347.
8. O.R. West, S.R. Cline, R.L. Siegrist, T.C. Houk, W.L. Holden, F.G. Gardner, and R.M. Schlosser, A fieldscale test of in situ chemical oxidation through recirculation, Proceedings of the Spectrum '98 International Conference on Nuclear and Hazardous Waste Management, Denver, CO, American Nuclear Society, 1998, pp. 1051-1057.
9. M. Schnarr, C. Truax, G. Farquhar, E. Hood, T. Gonully, and B. Stickney, Laboratory and controlled field experiment using potassium permanganate to remediate trichloroethylene and perchloroethylene DNAPLs in porous media, J. Contam. Hydrol. 29 (1998), pp. 205-224.
10. Y.E. Yan and F.W. Schwartz, Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate, J. Contam. Hydrol. 37 (1999), pp. 343-365.
11. R.L. Siegrist, M.A. Urynowiez, O.R. West, M.L. Crimi, and K.S. Lowe, Principles and Practices of In Situ Chemical Oxidation using Permanganate, Battelle Press, Columbus, OH,2001.
12. M.A. Urynowez, Reaction kinetics and mass transfer during in situ oxidation of dissolved and DNAPL trichloroethene with permanganate, Ph.D. diss., Colorado School of Mincs, 2000.
13. S.U. Khan and M. Schnitzer, Soil Organic Matter, Elsevier Scientific, New York, 1978.
14. 4 chemical oxidation and deep soil mixing for soil treatment, Geotech. News, December (1997).
15. F.G. Gardner, N.E. Korte, J. Strong-Gunderson, R.L. Siegrist, O.R. West, S.R. Cline, and J. Baker, Implementation of deep soil mixing at the Kansas City Plant, in Final project report by Oak Ridge National Laboratory for the Environmental Restoration Program at the DOE Kansas City Plant, ORNL/TM-13532, Oak Ridge National Laboratory, Oak Ridge, TN, 1998.
16. A.M. S truse, Mass transport of potassium permanganate in low permeability media and matrix interactions, M.Sc. thesis, Colorado School of Mines, 1999.
17. 4 for groundwater remediation, Chemosphere 66 (2007), pp. 2058-2066.
18. E.S. Lee and F.W. Schwartz, Characterization and optimization of long-term controlled release system for groundwater remediation: A generalized modeling approach, Chemosphere 69 (2007), pp. 247-253.
19. 4 (CRP) barrier system for groundwater remediation: A pilot-scale flow-tank study, Chemosphere 71, (2008), pp. 902-910.
20. E.S. Lee, G. Liu, F.W. Schwartz, Y. Kim, and M. Ibaraki, Model-based evaluation of controlled-release system in the remediation of dissolved plumes in groundwater, Chemosphere 72 (2008), pp. 165-173.
21. Y.E. Yan and F.W. Schwartz, Kinetics and mechanisms for TCE oxidation by permanganate, Environ. Sci. Technol 34 (2000), pp. 2535-2541.