Experimental measurements of vapor-liquid equilibria at low pressure: Systems containing alcohols, esters and organic acids

Fluid Phase Equilibria

Volumn 287, Issue 2, 2010, Pages 141-145

  Navarro Espinosa, Iván R ^a   Cardona, Carlos A ^a   López, Jimmy A ^b  

^a UNIVERSIDAD NACIONAL DE COLOMBIA   (Colombia)

^b PLAPIQUI UNS CONICET   (Argentina)

Author keywords

Low pressure; Parameters optimization; Reactive mixtures; Vapor liquid equilibrium

Indexed keywords

EQUATION OF STATE; ETHYL ACETATES; EXPERIMENTAL MEASUREMENTS; LIQUID VAPOR EQUILIBRIUM; LOW PRESSURES; METHYL ACETATES; PENG-ROBINSON; REACTIVE MIXTURES; RECIRCULATIONS; VAPOR-LIQUID EQUILIBRIUM; WONG-SANDLER MIXING RULES;

ACETIC ACID; CHEMICAL REACTIONS; EQUATIONS OF STATE; ESTERS; ETHANOL; LIQUIDS; METAL ANALYSIS; METHANOL; ORGANIC ACIDS; PH EFFECTS; PHASE EQUILIBRIA; WATER VAPOR;

BINARY MIXTURES;

EID: 70450223886     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fluid.2009.10.002     Document Type: Article

References (22)

1. Pisarenko Y.A., Serafimov L.A., Cardona C.A., Efremov D.L., and Shuwalov A. Reactive distillation design: analysis of the process statics. Rev. Chem. Eng. 17 (2001) 253-326
2. Giessler S., Danilov R.Y., Pisarenko R.Y., Serafimov L.A., Hasebe S., and Hashimoto I. Feasibility study of reactive distillation using the analysis of the statics. Ind. Eng. Chem. Res. 37 (1998) 4375-4382
3. Giessler S., Danilov R.Y., Pisarenko R.Y., Serafimov L.A., Hasebe S., and Hashimoto I. Feasible separation modes for various reactive distillation systems. Ind. Eng. Chem. Res. 38 (1999) 4060-4067
4. Malone M.F., Huss R.S., and Doherty M.F. Green chemical engineering aspects of reactive distillation. Environ. Sci. Technol. 37 (2003) 5325-5329
5. Malone M.F., and Doherty M.F. Reactive distillation. Ind. Eng. Chem. Res. 39 (2000) 3953-3957
6. Hala E., Pick J., Fried V., and Vilim O. Vapor-Liquid Equilibrium (1960), Akademie Verlag, Berlin
7. Alsmeyer F., Marquardt W., and Olf G. A new method for phase equilibrium measurements in reacting mixtures. Fluid Phase Equilib. 203 (2002) 31-51
8. Calvar N., Dominguez A., and Tojo J. Vapor-liquid equilibria for the quaternary reactive systems ethyl acetate + etanol + water + acetic acid and some of the constituent binary systems at 101.3 kPa. Fluid Phase Equilib. 235 (2005) 215-222
9. Bernatová S., Aim K., and Wichterle I. Isothermal vapour-liquid equilibrium with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system, and in five binary subsystems. Fluid Phase Equilib. 247 (2006) 96-101
10. Kurihara K., Nakamichi M., and Kojima K. Isobaric vapor-liquid equilibria for methanol + ethanol + water and three constituent binary systems. J. Chem. Eng. Data 38 (1993) 446-449
11. Xu Z.P., and Chuang K.T. Correlation of vapor-liquid equilibrium data for methyl acetate-methanol-water-acetic acid mixtures. Ind. Eng. Chem. Res. 36 (1997) 2866-2870
12. Horstmann S., Pöpken T., and Gmehling J. Phase equilibria and excess properties for binary systems in reactive distillation processes. Part I. Methyl acetate synthesis. Fluid Phase Equilib. 180 (2001) 221-234
13. C.A. Cardona, Design of Reactive Distillation Processes for Producing Alkyl Acetates from Acetic Anhydride. PhD Dissertation. Moscow State Academy of Chemical Engineering (2001).
14. Stryjek R., and Vera J.H. PRSV: an improved Peng-Robinson equation of state for pure compounds and mixtures. Can. J. Chem. Eng. 64 (1986) 323-333
15. Soave G. Equilibrium constants from a modified Redlich-Kwong equation of state. Chem. Eng. Sci. 27 (1972) 1197-1203
16. Wong D.S.H., and Sandler S.I. Theoretically correct mixing rule for cubic equations of state. AIChE J. 38 (1992) 671-680
17. Renon H., and Prausnitz J.M. Local compositions in thermodynamic excess functions for liquid mixtures. AIChE J. 14 (1967) 135-144
18. Smith J.M., Van Ness H.C., and Abbott M.M. Introduction to Chemical Engineering Thermodynamics. fifth ed. (1996), McGraw-Hill, Inc.
19. Ghosh P., and Taraphdar T. Prediction of vapor-liquid equilibria of binary systems using PRSV equation of state and Wong-Sandler mixing rules. Chem. Eng. J. 70 (1998) 15-24
20. López J.A., and Cardona C.A. Phase equilibrium calculations for carbon dioxide + n-alkanes binary mixtures with the Wong-Sandler mixing rules. Fluid Phase Equilib. 239 (2006) 206-212
21. López J.A., Trejos V.M., and Cardona C.A. Objective functions analysis in the minimization of binary VLE data for asymmetric mixtures at high pressures. Fluid Phase Equilib. 248 (2006) 147-157
22. López J.A., Trejos V.M., and Cardona C.A. Parameters estimation and VLE calculation in asymmetric binary mixtures containing carbon dioxide + n-alkanols. Fluid Phase Equilib. 275 (2009) 1-7