Highly Z-selective metathesis homocoupling of terminal olefins

Journal of the American Chemical Society

Volumn 131, Issue 46, 2009, Pages 16630-16631

  Jiang, Annie J ^a   Zhao, Yu ^a   Schrock, Richard R ^a   Hoveyda, Amir H ^b  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b BOSTON COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1-HEXENE; 1-OCTENE; ALLYLBENZENE; ARYLOXIDE; CHEMICAL EQUATIONS; HIGH YIELD; HOMOCOUPLING; OLEFIN METATHESIS; PINACOLATE; PYRROLIDE; TERMINAL OLEFINS;

CATALYSIS; CATALYSTS;

OLEFINS;

1 HEXENE; ALKENE DERIVATIVE; BENZENE DERIVATIVE; BENZYL DERIVATIVE; CYCLOBUTANE DERIVATIVE; MOLYBDENUM; OCTANE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; PYRROLE DERIVATIVE; SILANE DERIVATIVE; TOLUENESULFONIC ACID DERIVATIVE;

ARTICLE; CATALYST; ISOMERIZATION; MOLECULAR INTERACTION; RING OPENING METATHESIS POLYMERIZATION; STEREOCHEMISTRY; SUBSTITUTION REACTION;

ALKENES; CATALYSIS;

EID: 70450181131     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja908098t     Document Type: Article

References (18)

1. Schrock, R. R. Chem. Rev. 2009, 109, 3211.
2. (a) Hock, A.; Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc. 2006, 128, 16373.
3. (b) Singh, R.; Schrock, R. R.; Müller, P.; Hoveyda, A. H. J. Am. Chem. Soc. 2007, 129, 12654.
4. (a) Malcolmson, S. J.; Meek, S. J.; Sattely, E. S.; Schrock, R. R.; Hoveyda, A. H. Nature 2008, 456, 933.
5. (b) Sattely, E. S.; Meek, S. J.; Malcolmson, S. J.; Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc. 2009, 131, 943.
6. (c) Meek, S. J.; Malcolmson, S. J.; Li, B.; Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc.,online 10/20/09.
7. Ibrahem, I.; Yu, M.; Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc. 2009, 131, 3844.
8. Flook, M. M.; Jiang, A. J.; Schrock, R. R.; Müller, P.; Hoveyda, A. H. J. Am. Chem. Soc. 2009, 131, 7962.
9. (a) Jiang, A. J.; Simpson, J. H.; Müller, P.; Schrock, R. R. J. Am. Chem. Soc. 2009, 131, 7770.
10. (b) Marinescu, S. C.; Schrock, R. R.; Li, B.; Hoveyda, A. H. J. Am. Chem. Soc. 2009, 131, 58.
11. See Supporting Information for other examples and syntheses of all new catalysts (*).
12. Marinescu, S. C.; Schrock, R. R.; Müller, P.; Hoveyda, A. H. J. Am. Chem. Soc. 2009, 131, 10840.
13. Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, 2003; Vols. 1-3.
14. (a) Romero, P. E.; Piers, W. E. J. Am. Chem. Soc. 2005, 127, 5032.
15. (b) Romero, P. E.; Piers, W. E. J. Am. Chem. Soc. 2007, 129, 1698.
16. (c) Webster, C. E. J. Am. Chem. Soc. 2007, 129, 7490.
17. (d) van der Eide, E. F.; Romero, P. E.; Piers, W. E. J. Am. Chem. Soc. 2008, 130, 4485.
18. (e) Wenzel, A. G.; Grubbs, R. H. J. Am. Chem. Soc. 2006, 128, 16048.