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17
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70449721365
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-1): 3442 (vs), 3065 (m), 2970 (w), 2923 (w), 1648 (s), 1552 (s), 1427 (m), 1382 (s), 1103 (m), 1082 (m), 871 (w), 763 (m), 741 (w), 652 (w), 616 (w).
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-1): 3442 (vs), 3065 (m), 2970 (w), 2923 (w), 1648 (s), 1552 (s), 1427 (m), 1382 (s), 1103 (m), 1082 (m), 871 (w), 763 (m), 741 (w), 652 (w), 616 (w).
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18
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70449711616
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The single-crystal X-ray data for 1 was collected on a Bruker SMART CCD diffractometer with graphite-monochromated Mo Kα radiation (λ, 0.71073 Å) at room temperature. Absorption corrections were applied using sadabs. The structure was solved with direct methods and refined with the full-matrix least-squares technique based on F2 using the shelxtl program package [16, Anisotropic thermal parameters were applied to all non-hydrogen atoms. The hydrogen atoms were located at the calculated sites and refined with isotropic temperature factors. Crystal data for 1: crystal dimensions 0.26 × 0.22 × 0.09 mm3, formula C16H24Cu5N6O20, Mr, 938.11, monoclinic, space group P21/n, with a, 10.605(2, b, 11.852(3, c, 12.1133, α, 90.00°, β, 105.02°, γ, 90.00°, Z, 2, ρcalcd, 2.119 g cm-3, μ, 3.654 mm-1, the final R
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2 = 0.1559, and S = 1.010.
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19
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84985648192
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