Studies on electrophilic reaction of tertiary 2,3-allenols with NBS in H2O or aqueous MeCN: An efficient selective synthesis of 2-bromoallylic ketones, 1,2-allenyl ketones, or 3-bromo-2,5-dihydrofurans

Journal of Organic Chemistry

Volumn 74, Issue 22, 2009, Pages 8733-8738

  Li, Jing ^a   Kong, Wangqing ^a   Yu, Yihua ^b   Fu, Chunling ^a   Ma, Shengming ^a  

^a ZHEJIANG UNIVERSITY   (China)

^b EAST CHINA NORMAL UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENALS; ALKENYL; ALKYL GROUPS; ALKYL SUBSTITUENT; ALLENYL; ARYL GROUP; C-C BONDS; CARBON ATOMS; CARBONYL FUNCTIONALITY; DIHYDROFURANS; ELECTRONIC EFFECTS; ELECTROPHILIC REACTION; HYDROXYL GROUPS; PROTON ELIMINATION; REACTION CONDITIONS; REACTION PATHWAYS; RING-EXPANSION REACTION; SELECTIVE SYNTHESIS; STERIC EFFECT; THREE-MEMBERED RINGS;

ALDEHYDES; ALKYLATION; CHROMATOGRAPHIC ANALYSIS; COLUMN CHROMATOGRAPHY; FLUORINE CONTAINING POLYMERS; SILICA; SILICA GEL; SYNTHESIS (CHEMICAL);

KETONES;

3 BROMO 2,5 DIHYDROFURAN DERIVATIVE; ACETONITRILE; ALCOHOL DERIVATIVE; ALDEHYDE DERIVATIVE; ALLENE DERIVATIVE; ALLYL COMPOUND; ELECTROPHILE; FURAN DERIVATIVE; KETONE DERIVATIVE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COLUMN CHROMATOGRAPHY; STEREOCHEMISTRY; SYNTHESIS;

EID: 70449672730     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9018717     Document Type: Article

References (22)

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