Enantioselective aldol reaction of tetrasubstituted ketene silyl acetals with achiral aldehydes for the construction of asymmetric tertiary alcohols: An application for the divergent total syntheses of buergerinins F and G

Synthesis

Volumn , Issue 17, 2009, Pages 2915-2926

  Shiina, Isamu ^a   Iizumi, Takashi ^a   Yamai, Yu Suke ^a   Kawakita, Yo Ichi ^a   Yokoyama, Kazutoshi ^a   Yamada, Yo Ko ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Aldol reaction; Enantioselective; Ketene silyl acetal; Tertiary alcohol; Tin chiral amine catalyst

Indexed keywords

ALDOL REACTION; ALDOL REACTIONS; ASYMMETRIC ALDOL REACTIONS; CHIRAL DIAMINE; CHIRAL TERTIARY ALCOHOLS; CROTONALDEHYDE; ENANTIOSELECTIVE; HETEROATOMS; KETALIZATION; KETENE SILYL ACETAL; MUKAIYAMA ALDOL REACTION; OPTICALLY ACTIVE; TERTIARY ALCOHOL; TERTIARY ALCOHOLS; TOTAL SYNTHESIS; TRIFLATES;

ALDEHYDES; AMINES; CATALYSIS; CATALYSTS; ORGANIC POLYMERS; SILANES; SUGAR (SUCROSE); SYNTHESIS (CHEMICAL); TIN;

COORDINATION REACTIONS;

ALDEHYDE DERIVATIVE; ANTIINFLAMMATORY AGENT; BUERGERININ F; BUERGERININ G; CROTONALDEHYDE; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; DRUG SYNTHESIS; ENANTIOSELECTIVITY; MUKAIYAMA REACTION;

EID: 70449393326     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1216922     Document Type: Article

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