Thermal stability and kinetics of ylide-borane complexes

Thermochimica Acta

Volumn 424, Issue 1-2, 2004, Pages 149-155

  Stoddard, Jonathan M ^a   Shea, Kenneth J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

DSC; Homologation; Kissinger kinetics; Non isothermal

Indexed keywords

ACTIVATION ENERGY; COMPLEXATION; DIFFERENTIAL SCANNING CALORIMETRY; ENTROPY; ISOTHERMS; MATHEMATICAL MODELS; REACTION KINETICS; THERMODYNAMIC STABILITY;

AB INITIO CALCULATIONS; KISSINGER METHODS; NON-ISOTHERMAL KINETIC ANALYSIS;

BORON COMPOUNDS;

BORANE DERIVATIVE; DIMETHYLSULFOXONIUM METHYLIDE; SULFUR DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTALLIZATION; ENTROPY; REACTION ANALYSIS; THERMOSTABILITY;

EID: 7044232140     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2004.05.024     Document Type: Article

References (20)

1. Shea K.J., Busch B.B., Paz M.M., Staiger C.L., Stoddard J.M., Walker J.R., Zhou X., Zhu H. J. Am. Chem. Soc. 124:2002;3636
2. Stoddard J.M., Shea K.J. Organometallics. 22:2003;1124
3. Vyazovkin S. Int. Rev. Phys. Chem. 19:2000;45
4. Sewry J.D., Brown M.E. Thermochim. Acta. 390:2002;217
5. 3-ylide complex has been prepared in 3 g quantities as a white solid substance. The DSC (<1.5 mg) shows a very exothermic transition above 55°C and larger amounts of solid complex should not be heated.
6. M.J. Frisch, et al., GAUSSIAN 98, Revision A.11, Gaussian, Inc., Pittsburgh, PA, 2001.
7. Galwey A.K. Thermochim. Acta. 399:2003;1
8. E. Davydov, A. Vorotnikov, G. Pariyskii, G. Zalkov, Kinetic Peculiarities of Solid Phase Reactions, John Wiley & Sons, New York, 1998.
9. A.K. Galwey, M.E. Brown, Thermal Decomposition of Ionic Solids, Elsevier, Amsterdam, 1999.
10. C.E. Bawn, Chem. Solid State (1955) 254.
11. Flynn J.H., Wall J. Nat. Bur. Stand. 70A:1966;487
12. Ozawa T. Bull. Chem. Soc. Jpn. 38:1965;1881
13. Ozawa T. J. Therm. Anal. 2:1970;301
14. Doyle D. J. Appl. Polym. Sci. 5:1961;285
15. Budrugeac B., Homentcouschi D., Segal E. J. Therm. Anal. Cal. 63:2001;457
16. Vyazovkin S. New J. Chem. 24:2000;913
17. Kissinger H. J. Res. Nat. Bureau Standards. 57:1956;217
18. Vyazovkin S., Wright C.A. Thermochim. Acta. 340/341:1999;53
19. Vyazovkin S.V. J. Comput. Chem. 22:2001;178
20. T.H. Lowry, K.S. Richardson, Mechanism and Theory in Organic Chemistry, 2nd ed., Harper & Row, New York, 1981.