High rates and substrate selectivities in water by polyvinylimidazoles as transaminase enzyme mimics with hydrophobically bound pyridoxamine derivatives as coenzyme mimics

Journal of the American Chemical Society

Volumn 131, Issue 43, 2009, Pages 15604-15605

  Skouta, Rachid ^a   Wei, Sujun ^a   Breslow, Ronald ^a  

^a Och Spine at New York Presbyterian Hospitals   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; ENZYME MIMICS; HIGH RATE; POLYMERIZATION PROCESS; PYRUVIC ACID; RADICAL POLYMERS; RATE RATIOS; SIDE CHAINS; SUBSTRATE SELECTIVITY; VINYLIMIDAZOLE;

AMINO ACIDS; CHEMICAL REACTIONS; FREE RADICAL POLYMERIZATION; ORGANIC ACIDS; POLYMERS;

ENZYMES;

AMINOTRANSFERASE; IMIDAZOLE DERIVATIVE; PYRIDOXAMINE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; PH MEASUREMENT; SYNTHESIS; TEMPERATURE MEASUREMENT;

IMIDAZOLES; MOLECULAR MIMICRY; POLYVINYLS; PYRIDOXAMINE; SPECTROMETRY, MASS, MATRIX-ASSISTED LASER DESORPTION-IONIZATION; SPECTROPHOTOMETRY, ULTRAVIOLET; SUBSTRATE SPECIFICITY; TRANSAMINASES; WATER;

EID: 70350647436     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9072589     Document Type: Article

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