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The compensation is not complete when considering the breathing mode in the model. In heterostructures, the periodicity of the lattice distortions along the z direction is lost so that the total volume of the lattice may not be kept constant due to the existence of the breathing mode.
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In the bulk phase diagrams presented in this paper (Figs. 2 7), we only considered uniform phases that have been confirmed in experiments. However, quasi-2D phases may exist in heterostructures, especially near the interface. In this case, it would be more appropriate to compare with a 2D phase diagram. However, we have found that the 2D phase diagram is qualitatively similar to the three-dimensional (3D) bulk diagram (with the A-AFM phase substituted by an orbital-ordered FM phase). Therefore, only 3D bulk phase diagrams are presented in this paper. It should be noted that given the complexity of the system, even the phase diagram in the bulk limit is not fully clear in the entire parameter space. It would be interesting for future efforts to analyze whether some of the exotic phases in heterostructures may also appear in the bulk phase diagrams in some particular parameter regime.
-
In the bulk phase diagrams presented in this paper (Figs. 2 7), we only considered uniform phases that have been confirmed in experiments. However, quasi-2D phases may exist in heterostructures, especially near the interface. In this case, it would be more appropriate to compare with a 2D phase diagram. However, we have found that the 2D phase diagram is qualitatively similar to the three-dimensional (3D) bulk diagram (with the A-AFM phase substituted by an orbital-ordered FM phase). Therefore, only 3D bulk phase diagrams are presented in this paper. It should be noted that given the complexity of the system, even the phase diagram in the bulk limit is not fully clear in the entire parameter space. It would be interesting for future efforts to analyze whether some of the exotic phases in heterostructures may also appear in the bulk phase diagrams in some particular parameter regime.
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